Search results for " Geometry."
showing 10 items of 2189 documents
[Cu(P^P)(N^N)][PF6] compounds with bis(phosphane) and 6-alkoxy, 6-alkylthio, 6-phenyloxy and 6-phenylthio-substituted 2,2'-bipyridine ligands for lig…
2018
We report a series of [Cu(P^P)(N^N)][PF6] complexes with P^P = bis(2-(diphenylphosphino)phenyl)ether (POP) or 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (xantphos) and N^N = 6-methoxy-2,2′-bipyridine (MeObpy), 6-ethoxy-2,2′-bipyridine (EtObpy), 6-phenyloxy-2,2′-bipyridine (PhObpy), 6-methylthio-2,2′-bipyridine (MeSbpy), 6-ethylthio-2,2′-bipyridine (EtSbpy) and 6-phenylthio-2,2′-bipyridine (PhSbpy). The single crystal structures of all twelve compounds have been determined and confirm chelating modes for each N^N and P^P ligand, and a distorted tetrahedral geometry for copper(I). For the xantphos-containing complexes, the asymmetrical bpy ligand is arranged with the 6-substituent lying …
Complexes of titanium and zirconium containing a tridentate linked amido–cyclopentadienyl ligand with a soft donor group: synthesis, structure, and e…
1999
Abstract Group 4 metal complexes M(η5:η1-C5R4SiMe2NCH2CH2SMe)Cl2 (R=H, M=Ti; R=Me, M=Ti, Zr) containing the thioether-functionalized linked amido–cyclopentadienyl ligand were synthesized and characterized by 1H- and 13C-NMR spectroscopy, mass spectrometry, and elemental analysis. The crystal structures of the complexes Ti(η5:η1-C5H4SiMe2NCH2CH2SMe)Cl2 and Zr(η5:η1:η1-C5Me4SiMe2NCH2CH2SMe)Cl2 were determined by single-crystal X-ray diffraction studies. The titanium complex is a conventional three-legged piano-stool molecule without an intramolecular interaction between the sulfur donor group and the titanium center, whereas the zirconium complex adopts a trigonal bipyramidal structure, with …
Zirconium and hafnium complexes of the thio(bisphenolato) ligand: synthesis, structural characterization and testing as 1-hexenepolymerizationcatalys…
2009
Thio(bisphenolato) complexes of the type [M2(mu-tbop-kappa3O,S,O)2Cl4] [M = Zr 1, Hf 2 and tbop = 2,2-thiobis{4-(1,1,3,3-tetramethyl-butyl)phenolate}] were prepared by HCl elimination from tbopH2 and MCl4. Substitution of the chlorides in 1 and 2 by 2,6-diisopropylphenolato groups (dipp) generates new compounds [M2(mu-tbop-kappa3O,S,O)2(dipp)4] (M = Zr 3, Hf 4). The structures of 1-4 were confirmed by NMR spectroscopy; complexes 3 and 4 were further investigated by X-ray crystallography. These studies showed 1-4 to be dimers either in the solid state or in solution and to have metal centers adopting distorted octahedral geometry. However treatment of MCl4 with [Al2(mu-OEt)2(tbop-kappa3O,S,O…
Extending CSG with projections: Towards formally certified geometric modeling
2015
We extend traditional Constructive Solid Geometry (CSG) trees to support the projection operator. Existing algorithms in the literature prove various topological properties of CSG sets. Our extension readily allows these algorithms to work on a greater variety of sets, in particular parametric sets, which are extensively used in CAD/CAM systems. Constructive Solid Geometry allows for algebraic representation which makes it easy for certification tools to apply. A geometric primitive may be defined in terms of a characteristic function, which can be seen as the zero-set of a corresponding system along with inequality constraints. To handle projections, we exploit the Disjunctive Normal Form,…
Bords d'une surface médiane : Identifications et applications
2014
National audience; Un squelette d'une forme fermée est une structure mince, centrée dans cette forme, décrivant sa topologie et sa géométrie. Les squelettes permettent de développer des applications interactives en synthèse d'images~: l'utilisateur peut manipuler intuitivement des formes en modifiant leurs squelettes. Parmi toutes les formulations de squelettes, nous nous intéressons en particulier à la surface médiane. Ses éléments, nommés atomes, sont les sphères maximales intérieures à la forme décrite. Les positions des atomes sont organisées en courbes et surfaces, qui composent la structure squelettale. Cette structure peut être d'une grande aide pour manipuler une forme. Cependant, e…
Fractional half-tangent of a curve described by Iterated Function Systems.
2009
International audience; The deterministic fractal curves and surfaces find many applications in modeling of rough objects. However, these curves and surfaces are nowhere differentiable. Without notion of tangent, we can not determine the relative orientation of two fractal shapes, to join them with a "natural" aspect. Various works proposed a generalization of the concept of derivative by introducing the fractional derivative. In this paper we apply this concept of fractional derivative to the curves described by Iterated Function Systems. We show that if the fractional derivative exists at boundary points of the curve, the direction of the fractional half-tangent is necessarily the eigenve…
Tangentes à une courbe fractale
2007
http://www.irit.fr/REFIG/index.php/refig/article/view/10; National audience; Nous nous intéressons au calcul des tangentes à une courbe fractale définie à l'aide d'un IFS. Généralement, les courbes fractales sont nulle part dérivables, mais sous certaines conditions on peut montrer qu'elles admettent, en un ensemble de points, des demi-tangentes à droite et à gauche. Nous proposons une méthode permettant de déterminer ces demi-tangentes.
Needle-shape quality control by shadowgraphic image processing
2011
International audience; We propose a needle-shape quality-control method. To this end, we have devised a new acquisition system that combines a camera and a backlight. Needle measurements are carried out at a micrometric scale using shadowgraphic image processing. Our method not only distinguishes good needles from bad ones, but also allows classifying flawed needles into various categories of defects. This classification is important because some categories of defects can affect the entire production, whereas others do not. The results of our needle-shape quality-control method are validated using real samples directly off the manufacturing line. Needles are correctly classified at >97%, a…
Reaction-Diffusion Network For Geometric Multiscale High Speed Image Processing
2010
International audience; In the framework of heavy mid-level processing for high speed imaging, a nonlinear bi-dimensional network is proposed, allowing the implementation of active curve algorithms. Usually this efficient type of algorithm is prohibitive for real-time image processing due to its calculus charge and the inadequate structure for the use of serial or parallel architectures. Another kind of implementation philosophy is proposed here, by considering the active curve generated by a propagation phenomenon inspired from biological modeling. A programmable nonlinear reaction-diffusion system is proposed under front control and technological constraints. Geometric multiscale processin…
AN APPROACH TO CORRECTING IMAGE DISTORTION BY SELF CALIBRATION STEREOSCOPIC SCENE FROM MULTIPLE VIEWS
2012
International audience; An important step in the analysis and interpretation of video scenes for recognizing scenario is the aberration corrections introduced during the image acquisition in order to provide and correct real image data. This paper presents an approach on distortion correction based on stereoscopic self calibration from images sequences by using a multi-camera system of vision (network cameras). This approach for correcting image distortion brings an elegant and robust technique with good accuracy. Without any knowledge of shooting conditions, the camera's parameters will be estimated. For this, the image key points of interest are extracted from different overlapping views …