Search results for " Nanotube"
showing 10 items of 560 documents
ChemInform Abstract: Covalently Supported Ionic Liquid Phases: An Advanced Class of Recyclable Catalytic Systems
2016
In this review, the most recent advances in the synthesis and catalytic applications of covalently supported ionic liquid (IL) phases will be discussed. This class of recyclable catalytic materials is based on the covalent attachment of several types of ammonium salts, usually imidazolium, but also thiazolium, triazolium, and pyrrolidinium salts, on the surface of different supports, for example, silica, periodic mesoporous organosilica, polystyrene, magnetic-based materials, carbon nanotubes (NTs), halloysite NTs, polyhedral oligomeric silsesquioxane (POSS), and fullerenes. Moreover, poly(ionic liquid) materials, in which the IL-based structure also acts as a support, will be considered. T…
3 He NMR: from free gas to its encapsulation in fullerene
2013
The (3)He nuclear magnetic shieldings were calculated for single helium atom, its dimer, simple models of fullerene cages (He@Cn), and single wall carbon nanotubes. The performances of several levels of theory (HF, MP2, DFT-VSXC, CCSD, CCSD(T), and CCSDT) were tested. Two sets of polarization-consistent basis sets were used (pcS-n and aug-pcS-n), and an estimate of (3)He nuclear magnetic shieldings in the complete basis set limit using a two-parameter fit was established. Theoretical (3)He results reproduced accurately previously reported theoretical values for helium gas, dimer, and helium probe inside several fullerene cages. Excellent agreement with experimental values was achieved. (3)H…
Effect of packing on the cluster nature of C nanotubes: An information entropy analysis
2007
The possibility of the existence of single-wall carbon nanotubes (SWNTs) in organic solvents in the form of clusters is discussed. A theory is developed based on a bundlet model for clusters, which enables describing the distribution function of clusters by size. Comparison of the calculated values of solubility with experiments would permit obtaining energetic parameters characterizing the interaction of an SWNT with its surrounding, in a solid or solution. Fullerenes and SWNTs are unique objects, whose behaviour in many physical situations is characterized by remarkable peculiarities. Peculiarities in solutions show up first in that fullerenes and SWNTs represent the only soluble forms of…
Probing Laser Plasma Dynamics Using High-Order Harmonics Generation in Carbon-Containing Nanomaterials
2021
We study high-order harmonics generation from plasmas generated from graphite, fullerenes, carbon nanotubes, carbon nanofibers, diamond nanoparticles, and graphene. Our approach utilizes a heating nanosecond laser pulse to produce plasmas that serve as the media for high harmonic generation from a subsequent driven femtosecond laser pulse. High harmonics are generated at different time delays following the plasma formation, which allows us to analyze the spreading of species with different masses. We analyze the harmonic yields from species of single carbon atom, 60 atoms (fullerene), 106 atoms (diamond nanoparticles), 109 atoms (CNTs and CNFs), and even much larger species of graphene shee…
Formation and transformation of carbon nanoparticles under electron irradiation.
2004
This article reviews the phenomena occurring during irradiation of graphitic nanoparticles with high–energy electrons. A brief introduction to the physics of the interaction between energetic electrons and solids is given with particular emphasis on graphitic materials. Irradiation effects are discussed, starting from microscopic mechanisms that lead to structural alterations of the graphite lattice. It is shown how random displacements of the atoms and their subsequent rearrangements eventually lead to topological changes of the nanoparticles. Examples are the formation of carbon onions, morphological changes of carbon nanotubes, or the coalescence of fullerenes or nanotubes under electron…
Cluster Origin of the Solubility of Single-Wall Carbon Nanotubes
2005
The possibility of the existence of single-wall carbon nanotubes (SWNT) in organic solvents, in the form of clusters containing a number of SWNTs, is discussed. A theory is developed based on a bundletmodel for clusters, which enables describing the distribution function of clusters by size. Comparison of the calculated values of solubility with experimental data would permit obtaining energetic parameters characterizing the interaction of an SWNT with its surrounding in a solid phase or solution. Fullerenes and SWNTs are unique objects, whose behavior in many physical situations is characterized by remarkable peculiarities. Peculiarities in solutions show up in that fullerenes and SWNTs re…
Experimental studies on the detachment of multi-walled carbon nanotubes by a mobile liquid interface
2017
International audience; Retention and detachment of colloidal particles from surfaces is often considered only in terms of spontaneous chemical dispersion when the surface is already fully submerged. Nevertheless, interfacial processes, where the particles are caught on a mobile liquid contact line by capillary effects are ubiquitous. Theoretical description of such interfacial processes exist for spherical microcolloids, while for anisotropic shapes the literature is limited. Arc-discharge synthesized multiwalled carbon nanotube (MWNT) material contains besides the very anisotropic tubes also irregular amorphous carbon particles (ACP) that both are strongly hydrophobic. As a water–air–soli…
Synthesis of carbon nanotubes on FexOy doped Al2O3-ZrO2 nanopowder
2014
Carbon nanotubes (CNTs) were synthesized on liquid flame sprayed (LFS) powder substrate of iron oxide doped Al2O3-ZrO2. Iron oxide doped Al2O3-ZrO2 nanopowder was produced by injecting the liquid precursor of aluminium-isopropoxide, zirconium-n-propoxide, ferrocene and p-xylene into a high temperature (similar to 3000 K) flame. The precursor solution was atomized by high-velocity H-2 flow and injected into the flame where nanopartides were formed. The collected sample was used as a substrate material for the synthesis of CNTs. The CNTs were formed on the surfaces of the substrate powder by catalyzed decomposition of CH4. The particle morphology, size, phase composition and the nature of CNT…
Determination of Young’s modulus of Sb2S3 nanowires by in situ resonance and bending methods
2016
In this study we address the mechanical properties of Sb2S3 nanowires and determine their Young’s modulus using in situ electric-field-induced mechanical resonance and static bending tests on individual Sb2S3 nanowires with cross-sectional areas ranging from 1.1·104 nm2 to 7.8·104 nm2. Mutually orthogonal resonances are observed and their origin explained by asymmetric cross section of nanowires. The results obtained from the two methods are consistent and show that nanowires exhibit Young’s moduli comparable to the value for macroscopic material. An increasing trend of measured values of Young’s modulus is observed for smaller thickness samples.
The diffusion of carbon atoms inside carbon nanotubes
2008
We combine electron irradiation experiments in a transmission electron microscope with kinetic Monte Carlo simulations to determine the mobility of interstitial carbon atoms in single-walled carbon nanotubes. We measure the irradiation dose necessary to cut nanotubes repeatedly with a focused electron beam as a function of the separation between the cuts and at different temperatures. As the cutting speed is related to the migration of displaced carbon atoms trapped inside the tube and to their recombination with vacancies, we obtain information about the mobility of the trapped atoms and estimate their migration barrier to be about 0.25 eV. This is an experimental confirmation of the remar…