Search results for " Nanotube"

Impact of non-functionalized and ionic liquid modified carbon nanotubes on mechanical and thermal properties of ethylene- octene copolymer nanocompos…

2016

In this article the development and characterization of composites made from metallocene based ethylene-octene copolymer (EOC) with 38% octene content, non-modified or modified multi walled carbon nanotubes (MWCNTs), covalently functionalised with long chain hexadecyl moiety imidazolium ionic liquid (IL-f-MWCNTs), is presented. The procedure of MWCNTs functionalization is discussed. In order to obtain a good dispersion of the filler, composites with MWCNTs and IL-f-MWCNTs in the concentration range of 0.5-12 wt.% were made by ultrasonication / thermoplastic mixing method. The results indicated improvement in mechanical properties with increase of the filler content. The methodology of the d…

Ethylene-vinyl Acetate Thermoplastic Copolymers Filled with Multiwall Carbon Nanotubes: Effect of Hydrothermal Ageing on Mechanical, Thermal, and Ele…

2013

A range of properties of two commercial thermoplastic ethylene-vinyl acetate (EVA) copolymers, Elvax 420 and Elvax 450, neat and as melt-mixed composite filled with 15 wt.-% of multi-wall carbon nanotubes (MWCNTs), are studied in the “as produced” state and after hydrothermal ageing. Addition of MWCNTs into the neat copolymers introduces the functionality of electrical conductivity and significantly improves their mechanical properties, while thermal characteristics are slightly affected by the presence of carbon nanotubes. A remarkable increase of the elastic modulus (150%) and stress at failure (50%) in stress–strain experiments as well as creep resistance (40%) of the nanocomposites in c…

Numerical–Analytical Model for Nanotube‐Reinforced Nanocomposites

2013

Nanotube Friendly Poly(N-isopropylacrylamide).

2010

Poly(N-ispropylacrylamide) [PNIPAM] is a widely studied polymer for use in biological applications due to its lower critical solution temperature (LCST) being so close to the human body temperature. Unfortunately, attempts to combine carbon nanotubes (CNTs) with PNIPAM have been unsuccessful due to poor interactions between these two materials. In this work, a PNIPAM copolymer with 1 mol-% pyrene side group [p-PNIPAM] was used to produce a thermoresponsive polymer capable of stabilizing both single and multi-walled carbon nanotubes (MWNTs) in water. The presence of pyrene in the polymer chain lowers the LCST less than 4 °C and the interaction with nanotubes does not show any influence on LC…

Tailoring Properties of Carbon Nanotube Dispersions and Nanocomposites Using Temperature-Responsive Copolymers of Pyrene-Modified Poly(N-cyclopropyla…

2010

Despite their immense potential, the ability to control the dispersion and microstructure of carbon nanotubes remains a hurdle for their widespread use. Stimuli-responsive polymers show conformational changes with an applied external stimulus (pH, temperature, light, etc.). The dispersion of carbon nanotubes by thermoresponsive polymers is shown to enable the macroscopic properties of aqueous suspensions to be tailored as a function of temperature. This work presents the synthesis, characterization, and use of temperature-responsive poly(N-cyclopropylacrylamide) (PNCPA) polymers containing 1, 3, and 5 mol % pyrene-bearing repeat units to tailor the dispersion state of single-walled carbon n…

Grafting of polymer chains on the surface of carbon nanotubes via nitroxide radical coupling reaction

2015

Poly(butylene succinate) (PBS) was grafted on the surface of TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) modified multi-walled carbon nanotubes (MWCNTs) via a nitroxide radical coupling reaction. TEMPO functionalized MWCNTs (MWCNTs-g-TEMPO) were synthesized using the Cu(I)-catalyzed azide/alkyne click chemistry approach and the covalent bond of the nitroxide moieties onto the MWCNTs was confirmed via electron paramagnetic resonance (EPR) spectroscopy. The PBS grafting on the sidewalls of MWCNTs was carried out in solution via peroxide-induced formation of macroradicals and it was confirmed by EPR and attenuated total reflectance Fourier transform infrared analysis. Preliminary rheological …

α ,ω n -Heterotelechelic Hyperbranched Polyethers Solubilize Carbon Nanotubes

2010

The synthesis of novel linear-hyperbranched (linhb) polyether block copolymers based on poly(ethylene oxide) and branched poly(glycerol), bearing a single pyrene or myristyl moiety at the α-position of the linear chain is described. The polymers exhibit low polydispersity (M w /M n < 1.3) and controlled molecular weights (M n = 5 000 g·mol -1 ). The mainly hydrophilic block copolymers with multiple hydroxyl end groups readily dissolve multiwalled carbon nanotubes (MWCNTs) in water by mixing and subsequent sonification, resulting in noncovalent attachment of the linhb hybrid structure to the carbon nanotubes (CNTs). Transmission electron microscopy (TEM) was employed to visualize the solubil…

Mode I interlaminar fracture toughness of thin-ply laminates with CNT webs at the crack interface

2019

Abstract Pristine and functionalized carbon nanotube (CNT) webs were introduced at the interlaminar region of two different thin-ply carbon fibre reinforced polymer systems (NTPT 402 prepreg, and TeXtreme/SE84LV). The Mode I interlaminar fracture toughness (ILFT) for the NTPT 402 material was substantially lower. In contrast when SE84LV resin was used, the resistance curves were virtually unchanged and with no depreciation in the steady state value of the ILFT. This demonstrates that a careful choice of the resin is essential to permit the embedding of CNT webs in thin-ply laminates without compromising structural performance and opens a new way towards the development of multifunctional th…

Biocompatible Poly(N-isopropylacrylamide)-halloysite Nanotubes for Thermoresponsive Curcumin Release

2015

The grafting of poly(N-isopropylacrylamide) (PNIPAAM) onto the halloysite external surface is proposed in order to obtain a novel thermoresponsive drug carrier for curcumin delivery. The new nanomaterial is characterized by means of FT-IR spectroscopy, thermogravimetric analysis, and SEM investigations. A high density of polymer chain was achieved at the nanoparticle surface. The PNIPAAM dehydration phenomenon was observed in water above 32 °C that is nearly coincident with the lower critical solution temperature for the polymer. The colloidal stability as well as the wettability of the obtained nanomaterial may be triggered by temperature stimuli. In vitro tests simulating the gastro-intes…

Carbon nanostructures incorporated on methacrylate monoliths for separation of small molecules by nano-liquid chromatography

2018

Abstract Carbon nanostructures have been incorporated to polymethacrylate monoliths to develop novel stationary phases with enhanced separation performance in nano-liquid chromatography (nano-LC). Two incorporation approaches of these nanomaterials in monoliths were investigated. Single-walled carbon nanohorns (SWNHs) were first incorporated to the polymerization mixture, followed by UV initiation. The resulting stationary phases with embedded SWNHs led to an increase in the separation performance of analytes compared to the parent monolith. Alternatively, a two-step photo-grafting approach was also adopted to attach the carbon nanoparticles onto the polymer monolith surface. The effect of …