Search results for " SEP"
showing 10 items of 1106 documents
Correction of the deviations in the retention times with Chromolith columns associated to the flow rate: Implications in the modelling of the retenti…
2011
In a previous work (J. Sep. Sci. 2009, 32, 2793-2803), we reported an interpretive optimisation approach to achieve maximal resolution in minimal analysis time, based on models describing the retention and peak shape as a function of mobile phase composition and flow rate. The method was applied to the separation of a group of basic drugs in a Chromolith column. In that work, we found that the retention factors were sensitive to the flow rate. The reason of the observed deviations in retention times is the increase in the column volume at the applied pressure, which decreases the linear velocity inside the column. This behaviour forced to include a correction term in the model that describe…
Generalization of a finite-difference numerical method for the steady-state and transient solutions of the nernst—planck flux equations
1985
Abstract A generalization of the numerical method of Brumleve and Buck for the solution of Nernst—Planck equations when convective flux and electric current are involved has been developed. The simulation procedure was applied to a specific case: transport of strong electrolytes in a wide-pore membrane with simultaneous diffusion, convection and electric current. Good agreement was found between experimental data and computed results.
Quantifying brain tumor tissue abundance in HR-MAS spectra using non-negative blind source separation techniques
2012
Given high-resolution magic angle spinning (HR-MAS) spectra from several glial tumor subjects, our goal is to differentiate between tumor tissue types by separating the different sources that contribute to the profile of each spectrum. Blind source separation techniques are applied for obtaining characteristic profiles for necrosis, highly cellular tumor and border tumor tissue and providing the contribution (abundance) of each of these tumor tissue types to the profile of each spectrum. The problem is formulated as a non-negative source separation problem. Non-negative matrix factorization, convex analysis of non-negative sources and non-negative independent component analysis methods are …
Trace detection of plutonium by three-step photoionization with a laser system pumped by a copper vapor laser
1985
Laser photoionization has been used to detect trace amounts of plutonium. A high sensitivity and selectivity has been achieved by applying three-step excitation and ionization of the plutonium atoms with high pulse-repetition rates and additional mass determination by time-of-flight measurements. A laser system was developed which consists of a copper vapor laser pumping three dye lasers simultaneously. Samples containing between 1010 and 1012 atoms of239Pu on Re filaments were measured yielding strong resonance signals with maximum ion count rates of several kHz at a vanishingly low background. A detection efficiency of 10−7 was determined allowing the detection of about 108 plutonium atom…
MeCP2 haplodeficiency and early-life stress interaction on anxiety-like behavior in adolescent female mice
2021
Abstract Background Early-life stress can leave persistent epigenetic marks that may modulate vulnerability to psychiatric conditions later in life, including anxiety, depression and stress-related disorders. These are complex disorders with both environmental and genetic influences contributing to their etiology. Methyl-CpG Binding Protein 2 (MeCP2) has been attributed a key role in the control of neuronal activity-dependent gene expression and is a master regulator of experience-dependent epigenetic programming. Moreover, mutations in the MECP2 gene are the primary cause of Rett syndrome and, to a lesser extent, of a range of other major neurodevelopmental disorders. Here, we aim to study…
Non-analog decay of 74Rb
2001
The magnitude of the Coulomb mixing parameter δ1 IM has been experimentally deduced, for the first time, for the β decay of 74Rb. The estimated magnitude is derived from the feeding of the non-analog first excited 0+ state in 74Kr. The inferred upper limit of 0.07% is small compared to theoretical predictions. The half-life was measured to be 64.90(9) ms. peerReviewed
Ray-Space-Based Multichannel Nonnegative Matrix Factorization for Audio Source Separation
2021
Nonnegative matrix factorization (NMF) has been traditionally considered a promising approach for audio source separation. While standard NMF is only suited for single-channel mixtures, extensions to consider multi-channel data have been also proposed. Among the most popular alternatives, multichannel NMF (MNMF) and further derivations based on constrained spatial covariance models have been successfully employed to separate multi-microphone convolutive mixtures. This letter proposes a MNMF extension by considering a mixture model with Ray-Space-transformed signals, where magnitude data successfully encodes source locations as frequency-independent linear patterns. We show that the MNMF alg…
Sustainable recovery of critical elements from seawater saltworks bitterns by integration of high selective sorbents and reactive precipitation and c…
2023
The availability of raw mineral resources containing elements included in the Critical Raw Materials (CRMs) list is a growing concern for the European Union. Sea mining has been identified as a promising secondary source. In particular, brines obtained in solar saltworks (bitterns) contain relevant amounts of valuable CRMs such as Mg(II), B(III), other alkaline/alkaline earth metals (Rb(I), Cs(I), Sr(II)) and transition/post-transition elements (Co(II), Ga(III), Ge(IV)). However, the low concentration of some of these elements (µg/L) requires an effort to develop recovery routes that are sustainable and economically feasible where the required chemicals and energy are produced on-site from …
ICU-acquired infections: It is not only about the number of patients per room
2016
LETTER TO EDITOR
No-touch methods of terminal cleaning in the intensive care unit: results from the first large randomized trial with patient-centred outcomes
2017
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