Search results for " Volcano"

Rapid oxidation of mercury (Hg) at volcanic vents: Insights from high temperature thermodynamic models of Mt Etna's emissions

2011

A major uncertainty regarding the environmental impacts of volcanic Hg is the extent to which Hg is deposited locally or transported globally. An important control on dispersion and deposition is the oxidation state of Hg compounds: Hg(0) is an inert, insoluble gas, while Hg(II) occurs as reactive gases or in particles, which deposit rapidly and proximally, near the volcanic vent. Using a new high temperature thermodynamic model, we show that although Hg in Etna's magmatic gases is almost entirely Hg(0) (i.e., gaseous elemental mercury), significant quantities of Hg(II) are likely formed at Etna's vents as gaseous HgCl2, when magmatic gases are cooled and oxidised by atmospheric gases. Thes…

Mobility of plume-derived volcanogenic elements in meteoric water at Nyiragongo volcano (Congo) inferred from the chemical composition of single rain…

2017

The chemical composition of single rainfall events was investigated at Nyiragongo volcano (Democratic Republic of Congo) with the aim of determining the relative contributions of plume-derived elements. The different locations of the sampling sites allowed both plume-affected samples (hereafter referred to as “fumigated samples”) and samples representative of the local background to be collected. The chemical composition of the local background reflects the peculiar geographic features of the area, being influenced by biomass burning, geogenic dust, and biological activity. Conversely, fumigated samples contain large amounts of volcanogenic elements that can be clearly distinguished from th…

First 13C/12C isotopic characterisation of volcanic plume CO2

2010

We describe analytical details and uncertainty evaluation of a simple technique for the measurement of the carbon isotopic composition of CO2 in volcanic plumes. Data collected at Solfatara and Vulcano, where plumes are fed by fumaroles which are accessible for direct sampling, were first used to validate the technique. For both volcanoes, the plume-derived carbon isotopic compositions are in good agreement with the fumarolic compositions, thus providing confidence on the method, and allowing its application at volcanoes where the volcanic component is inaccessible to direct sampling. As a notable example, we applied the same method to Mount Etna where we derived a δ13C of volcanic CO2 betw…

Mantle-derived fluids in Central Mediterranean: Geochemical and geophysical constrains on sources of fluids and migration

2013

The geodynamics of the central Mediterranean is characterized by the interaction between the European plate and the African’s. In this setting Sicily is a sector of the Appenine-Maghrebide accretionary prism, which is located between two areas affected by extensional tectonics (Sicily Channel to the south and the Thyrrenian back arc basin to the north). Significant mantle-derived helium (0.4<R/Ra<2.8; R=3He/4He in the sample, Ra in atmosphere) is found in the CH4 and N2-CO2 rich fluids released in central western Sicily, a region without evidence of recent magmatism. CH4- dominated gases are released from mud volcanoes localized in an area of both low heat flow and seismicity. On the contra…

The Coupled Magmatic and Hydrothermal Systems of the Restless Aluto Caldera, Ethiopia

2020

Seismicity can be used to better understand interactions between magma bodies, hydrothermal systems and their host rocks—key factors influencing volcanic unrest. Here, we use earthquake data to image, for the first time, the seismic velocity structure beneath Aluto, a deforming volcano in the Main Ethiopian Rift. Traveltime tomography is used to jointly relocate seismicity and image 3D P- and S-wave velocity structures and the ratio between them (V P/V S). At depths of 4–9 km, the seismicity maps the top of a large low velocity zone with high V P/V S, which we interpret as a more ductile and melt-bearing region. A shallow (&lt;3 km) hydrothermal system exhibits low seismic velocities and ve…

Elevated CO2 emissions during magmatic-hydrothermal degassing at Awu Volcano, Sangihe Arc, Indonesia

2020

Awu is a remote and little known active volcano of Indonesia located in the northern part of Molucca Sea. It is the northernmost active volcano of the Sangihe arc with 18 eruptions in less than 4 centuries, causing a cumulative death toll of 11,048. Two of these eruptions were classified with a Volcanic Explosivity Index (VEI) of 4. Since 2004, a lava dome has occupied the centre of Awu crater, channelling the fumarolic gas output along the crater wall. A combined Differential Optical Absorption Spectroscopy (DOAS) and Multi-component Gas Analyzer System (Multi-GAS) study highlight a relatively small SO2 flux (13 t/d) sustained by mixed magmatic&ndash

Tunable diode laser measurements of hydrothermal/volcanic CO2 and implications for the global CO2 budget

2014

Quantifying the CO2 flux sustained by low-temperature fumarolic fields in hydrothermal/volcanic environments has remained a challenge, to date. Here, we explored the potential of a commercial infrared tunable laser unit for quantifying such fumarolic volcanic/hydrothermal CO2 fluxes. Our field tests were conducted between April 2013 and March 2014 at Nea Kameni (Santorini, Greece), Hekla and Krýsuvík (Iceland) and Vulcano (Aeolian Islands, Italy). At these sites, the tunable laser was used to measure the path-integrated CO2 mixing ratios along cross sections of the fumaroles' atmospheric plumes. By using a tomographic post-processing routine, we then obtained, for each manifestation, the co…

Micro-thermometry and minerochemical composition of ultramafic xenoliths and minerals from Mt. Vulture volcano (southern Italy)

2022

Here minerochemical composition and micro-thermometric data of ultramafic xenoliths (wehrlite) and loose xenocrysts (olivine and Cr-diopside) from the last melilitite-carbonatite explosive volcanic activity of Mt. Vulture volcano. In addition, some geometrical parameters of pelletal lapilli are reported.

New evidences on mercury emissions from Earth volcanism

2010

New Inferences on Magma Dynamics in Melilitite-Carbonatite Volcanoes: The Case Study of Mt. Vulture (Southern Italy)

2022

This study provides the first micro-thermometric data of fluid inclusions (FIs) in mafic loose (disaggregated) xenocrysts and ultramafic xenoliths in explosive products of the melilitite-carbonatite Mt. Vulture volcano (southern Italy). Pure CO2 late stage FIs hosted in rock-forming minerals of wehrlite xenoliths and clinopyroxene xenocrysts were trapped at the local crust-mantle boundary (32 km). In contrast, trapping pressures within the loose olivine xenocrysts are from 3.2 to 4.5 kbar (8–13 km). Considering the ongoing degassing of mantle-derived CO2 rich gases, together with seismic evidences of the presence of low amount of melts at depth, and the tectonic control of the past volcanic…