Search results for " fisica"

showing 10 items of 4804 documents

Induced Chirality in Confined Space on Halogen Gold Complexes

2015

The solubilization of HAuCl4 in toluene within optically active reverse micelles and lamellar structures formed by (1R,2S)-Dodecyl(2-hydroxy-1-methyl-2-phenylethyl)- dimethylammonium bromide (DMEB) has allowed us to evidence the complex phenomenology accompanying the confinement of Au salt within these nanostructures. Together with a chloride/bromide exchange process occurring in the first coordination sphere of an Au ion, UV−vis and electronic circular dichroism (ECD) spectra reveal the appearance of an induced dichroic signal attributable to Au complexes entrapped in the hydrophilic domain of the DMEB chiral nanostructures. Interestingly, change of the effective oxidation state and coordi…

Circular dichroismSupramolecular chiralityCoordination spherechirality confined space DMEBPhotochemistrySurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundGeneral EnergychemistryBromideRAY-ABSORPTION SPECTROSCOPY; BODY DISTRIBUTION-FUNCTIONS; NEAR-EDGE STRUCTURE; STABILIZED MICROEMULSIONS; SUPRAMOLECULAR CHIRALITY; CINCHONIDINE ADSORPTION; ELECTRONIC-STRUCTURES; CHIROPTICAL ACTIVITY; UNDECAGOLD CLUSTERS; CONDENSED MATTERPhysical and Theoretical ChemistryAbsorption (chemistry)SpectroscopyChirality (chemistry)Settore CHIM/02 - Chimica FisicaCoordination geometryThe Journal of Physical Chemistry C
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Two Latent and Two Hyperstable Polymeric Forms of Human Neuroserpin

2010

AbstractHuman neuroserpin (hNS) is a serine protease inhibitor that belongs to the serpin superfamily and is expressed in nervous tissues. The serpin fold is generally characterized by a long exposed loop, termed the reactive center loop, that acts as bait for the target protease. Intramolecular insertion of the reactive center loop into the main serpin β-sheet leads to the serpin latent form. As with other known serpins, hNS pathological mutants have been shown to accumulate as polymers composed of quasi-native protein molecules. Although hNS polymerization has been intensely studied, a general agreement about serpin polymer organization is still lacking. Here we report a biophysical chara…

Circular dichroismanimal structuresLightmedicine.medical_treatmenthuman neuroserpinBiophysicsContext (language use)SerpinProtein Structure SecondaryserpinopathiePolymerizationNeuroserpinSpectroscopy Fourier Transform InfraredmedicineHumansProtein IsoformsScattering Radiationpathological serpin aggregationReactive centerSerpinsProtein UnfoldingSerine proteaseProteasebiologyProtein StabilityChemistryCircular DichroismProteinNeuropeptidesTemperatureserpinlatent neuroserpinSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)PolymerizationBiochemistryFENIBembryonic structuresbiology.proteinBiophysicsBiophysical Journal
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LIFE CYCLE ASSESSMENT OF ITALIAN CITRUS BASED PRODUCTS. SENSITIVITY ANALYSIS AND IMPROVMENT SCENARIOS

2010

Though many studies concern the agro-food sector in the EU and Italy, and its environmental impacts, literature is quite lacking in works regarding LCA application on citrus products. This paper represents one of the first studies on the environmental impacts of citrus products in order to suggest feasible strategies and actions to improve their environmental performance. In particular, it is part of a research aimed to estimate environmental burdens associated with the production of the following citrus-based products: essential oil, natural juice and concentrated juice from oranges and lemons. The life cycle assessment of these products, published in a previous paper, had highlighted sign…

Citrus Life cycle assessment Water Energy Improvement scenarios Sensitivity analysisSettore ING-IND/11 - Fisica Tecnica Ambientale
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Stochastic models for wind speed forecasting

2011

Abstract This paper is concerned with the problem of developing a general class of stochastic models for hourly average wind speed time series. The proposed approach has been applied to the time series recorded during 4 years in two sites of Sicily, a region of Italy, and it has attained valuable results in terms both of modelling and forecasting. Moreover, the 24 h predictions obtained employing only 1-month time series are quite similar to those provided by a feed-forward artificial neural network trained on 2 years data.

Class (computer programming)EngineeringSeries (mathematics)Artificial neural networkMeteorologyRenewable Energy Sustainability and the EnvironmentStochastic modellingbusiness.industryModel selectionSettore FIS/01 - Fisica SperimentaleEnergy Engineering and Power TechnologySettore FIS/03 - Fisica Della MateriaSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)Wind speedFuel TechnologyNuclear Energy and EngineeringSpectral analysisbusinessstochastic models time series model selection spectral analysis artificial neural networks wind forecastingAlgorithmEnergy Conversion and Management
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On deformation of Poisson manifolds of hydrodynamic type

2001

We study a class of deformations of infinite-dimensional Poisson manifolds of hydrodynamic type which are of interest in the theory of Frobenius manifolds. We prove two results. First, we show that the second cohomology group of these manifolds, in the Poisson-Lichnerowicz cohomology, is ``essentially'' trivial. Then, we prove a conjecture of B. Dubrovin about the triviality of homogeneous formal deformations of the above manifolds.

Class (set theory)Pure mathematicsConjectureDeformation (mechanics)Nonlinear Sciences - Exactly Solvable and Integrable SystemsGroup (mathematics)FOS: Physical sciencesStatistical and Nonlinear PhysicsType (model theory)Poisson distributionMAT/07 - FISICA MATEMATICATrivialityMathematics::Geometric TopologyCohomologysymbols.namesakeDeformation of Poisson manifoldsPoisson-Lichnerowicz cohomologysymbolsPoisson manifolds Poisson-Lichnerowicz cohomology Infinite-dimensional manifolds Frobenius manifoldsMathematics::Differential GeometryExactly Solvable and Integrable Systems (nlin.SI)Mathematics::Symplectic GeometryMathematical PhysicsMathematics
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Morphisms of certain banach C*-modules

2000

Morphisms and representations of a class of Banach C*-modules, called CQ*algebras, are considered. Together with a general method for constructing CQ*-algebras, two different ways of extending the GNS-representation are presented.

Class (set theory)Pure mathematicsMorphismGeneral methodSettore MAT/05 - Analisi MatematicaGeneral MathematicsFOS: Physical sciencesMathematics (all)Mathematical Physics (math-ph)ArithmeticSettore MAT/07 - Fisica MatematicaMathematical PhysicsMathematics
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Multiplications of Distributions in One Dimension and a First Application to Quantum Field Theory

2002

In a previous paper we introduced a class of multiplications of distributions in one dimension. Here we furnish different generalizations of the original definition and we discuss some applications of these procedures to the multiplication of delta functions and to quantum field theory. © 2002 Elsevier Science (USA).

Class (set theory)Pure mathematicsThermal quantum field theoryApplied MathematicsFOS: Physical sciencesAnalysiMathematical Physics (math-ph)Scaling dimensionAlgebraDimension (vector space)Beta function (physics)MultiplicationQuantum field theorySettore MAT/07 - Fisica MatematicaMathematical PhysicsAnalysisMathematicsJournal of Mathematical Analysis and Applications
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Tirocinio Formativo Attivo nell'Ateneo di Palermo: Classe di Abilitazione A049 - Matematica e Fisica

2013

Sarà descritta l'organizzazione del primo ciclo del Corso di Tirocinio Formativo Attivo, Classe A049 - Matematica e Fisica, nell'Ateneo di Palermo, sia per quanto riguarda le attività psico-pedagogiche, sia per le attività disciplinari. In particolare, sarà descritta l'organizzazione del tirocinio svolto a scuola sotto la guida dei tutor accoglienti e sotto la guida del tutor coordinatore. Saranno evidenziati punti di forza, punti di debolezza e aspetti di criticità delle varie attività svolte e verranno proposti miglioramenti per i cicli successivi.

Classe di Abilitazione A049Matematica e FisicaTirocinio Formativo Attivo
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Noise influence on electron dynamics in semiconductors driven by a periodic electric field

2008

Studies about the constructive aspects of noise and fluctuations in different non-linear systems have shown that the addition of external noise to systems with an intrinsic noise may result in a less noisy response. Recently, the possibility to reduce the diffusion noise in semiconductor bulk materials by adding a random fluctuating contribution to the driving static electric field has been tested. The present work extends the previous theories by considering the noise-induced effects on the electron transport dynamics in low-doped n-type GaAs samples driven by a high-frequency periodic electric field (cyclostationary conditions). By means of Monte Carlo simulations, we calculate the change…

Classical Monte Carlo simulations fluctuations (theory) transport properties (theory)Condensed Matter - Materials ScienceMaterials Science (cond-mat.mtrl-sci)FOS: Physical sciencesSettore FIS/03 - Fisica Della MateriaSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)
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A Study on Engineering Freshman Conceptual Understanding of Newtonian Mechanics

2021

Force concept inventory is a multiple-choice questionnaire commonly used to assess students’ conceptual understanding of Newtonian mechanics. We here show that a cluster analysis method can be used to study student answers to the force concept inventory to investigate their understanding of Newtonian mechanics and provide new insights into the use of the force concept inventory. We identi- fied groups of students characterized by similar correct answers as well as by non- correct answers to the questionnaire, whose analysis allowed us to highlight student misconceptions/non-normative conceptions. Such an analysis of student answers gave us insights into the relationships between the student…

Classical mechanicsComputer scienceCluster analysis · Engineering freshmen · Force concept inventory · Newtonian mechanicsSettore FIS/08 - Didattica E Storia Della FisicaForce Concept InventoryAnalysis method
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