Search results for " geochimica"
showing 10 items of 446 documents
Passive vs. active degassing modes at an open-vent volcano (Stromboli, Italy)
2012
Abstract We report here on a UV-camera based field experiment performed on Stromboli volcano during 7 days in 2010 and 2011, aimed at obtaining the very first simultaneous assessment of all the different forms (passive and active) of SO 2 release from an open-vent volcano. Using the unprecedented spatial and temporal resolution of the UV camera, we obtained a 0.8 Hz record of the total SO 2 flux from Stromboli over a timeframe of ∼14 h, which ranged between 0.4 and 1.9 kg s −1 around a mean value of 0.7 kg s −1 and we concurrently derived SO 2 masses for more than 130 Strombolian explosions and 50 gas puffs. From this, we show erupted SO 2 masses have a variability of up to one order of mag…
Gas geochemistry and CO2 output estimation at the island of Milos, Greece
2018
Abstract Twenty gas samples have been collected from the natural gas manifestations of Milos Island, the majority of which is found underwater along its coast. Furthermore, three anomalous degassing fumarolic areas (Kalamos, Paleochori and Adamas) have been recognized on-land. Almost all the gases are CO2-dominated with CO2 ranging from 88 to 99% vol for the samples taken underwater, while the on-land manifestations show a wider range (15–98%) due to air contamination. Methane reaches up to 1.0% vol, H2 up to 3.2% vol and H2S up to 3.5% vol indicating a hydrothermal origin of the gases. The isotope composition of He points out to mantle contributions up to 45%, while the C-isotope compositi…
Pathways and fate of REE in the shallow hydrothermal aquifer of Vulcano island (Italy)
2019
Abstract We investigated the geochemical behaviour of major and Rare Earth Elements (REE), together with oxygen and deuterium isotopic composition in the aquifer of Vulcano, the southernmost island of the Aeolian archipelago (Italy). Studied wells, located at different distances from the crater, are characterised by different contributions of the rising volcanic fluids. In particular, those located in the proximity of La Fossa crater are affected by a strong interaction with volcanic-hydrothermal fluids and show REE behaviour similar to that of fresh rocks, suggesting a congruent dissolution of the solid matrix. Samples from the other wells, located in an area where the volcanic deposits ar…
Mercury gas emissions from La Soufrière Volcano, Guadeloupe Island (Lesser Antilles)
2009
Abstract Quantifying mercury (Hg) emissions from active volcanoes is of particular interest for better constraining the global cycle and environmental impact of this highly toxic element. Here we report on the abundance of total gaseous (TGM = Hg 0 (g) + Hg II (g) ) and particulate (Hg (p) ) mercury in the summit gas emissions of La Soufriere andesitic volcano (Guadeloupe island, Lesser Antilles), where enhanced degassing of mixed hydrothermal-magmatic volatiles has been occurring since 1992 from the Southern summit crater. We demonstrate that Hg in volcanic plume occurs predominantly as gaseous mercury, with a mean TGM/Hg (p) mass ratio of ~ 63. Combining the mean TGM/H 2 S mass ratio of …
A New Web-Based Catalog of Earth Degassing Sites in Italy
2008
Italy is a region characterized by intense and widespread processes of Earth degassing. High-temperature gases are released by crater plumes and fumaroles in volcanic environments throughout Italy. Also prevalent are numerous low-temperature gas emissions rich in carbon dioxide (CO2). These low-temperature emissions are located in a large area, mainly in the western sector of central and southern Italy (Figure 1).
Application and evaluation of biomagnetic and biochemical monitoring of the dispersion and deposition of volcanically-derived particles at Mt. Etna, …
2010
article i nfo Article history: Received 6 August 2009 Accepted 4 January 2010 Available online xxxx Biomagnetic monitoring, using tree leaves as passive surfaces for particle collection, has been shown to be a promising technique for assessing the dispersion and deposition of particles in the context of anthropogenic pollution. By comparing leaves' magnetic properties with trace metal levels measured in the leaves, we here assess the utility of the biomagnetic technique as a sensitive, fast and inexpensive method for assessment of volcanic plume deposition. Samples of sweet chestnut leaves (Castanea sativa) were collected from the area surrounding Mt. Etna volcano in Sicily during the 2008 …
A christmas gift: Signature of the 24th December 2018 eruption of Mt. Etna on the chemical composition of bulk deposition in eastern sicily
2020
The eruption of Mt. Etna which occurred on December 24th 2018 was characterized by strombolian activity and fire fountains, emitted by the New South-East Crater and along a fissure that propagated towards the SE. The influence of volcanic emissions on atmospheric deposition was clearly detectable at several kilometres from the source. Wet and dry (bulk) deposition samples were collected each month, through a network of eleven collectors, in the areas of Milazzo, and Priolo between June 2018 and June 2019. They were analysed for major ions and trace elements concentrations. The pH values range from 3.9 to 8.3, while the EC values range from 7 to 396 μS cm-1. An extensive neutralization of th…
Continuous monitoring of hydrogen and carbon dioxide at Mt Etna
2013
article i nfo This study assessed the use of an H2 fuel cell as an H2-selective sensor for volcano monitoring. The resolution, repeatability, and cross-sensitivity of the sensor were investigated and evaluated under known laboratory conditions. A tailor-made device was developed and used for continuously monitoring H2 and CO2 at Mt Etna throughout 2009 and 2010. The temporal variations of both parameters were strongly correlated with the evolution of the volcanic activity during the monitoring period. In particular, the CO2 flux exhibited long-term variations, while H2 exhibited pulses immediately before the explosive activity that occurred at Mt Etna during 2010.
Geochemical characterisation of the alkaline and hyperalkaline groundwater in the Othrys Ophiolite Massif, central Greece
2021
The complex geology of Greece includes two important parallel running ophiolitic belts. The Othrys Massif in central Greece belongs to the westernmost of them. In the current study, 33 water samples from cold hyperalkaline and hypothermal (T < 40°C) alkaline springs and 30 gas samples (either dissolved or free) were collected at 17 different sites in and around this wide ophiolite outcrop, aiming to determine the origin of fluids and evidence gas-water-rock interaction processes taking place in the area. Water samples were analysed for their chemical (major ions and trace elements) and isotope (d18O-H2O, d2H-H2O) composition. They can be subdivided into alkaline (pH <11) of both Mg-Ca…
Intercomparison of SO2 camera systems for imaging volcanic gas plumes
2015
Abstract SO 2 camera systems are increasingly being used to image volcanic gas plumes. The ability to derive SO 2 emission rates directly from the acquired imagery at high time resolution allows volcanic process studies that incorporate other high time-resolution datasets. Though the general principles behind the SO 2 camera have remained the same for a number of years, recent advances in CCD technology and an improved understanding of the physics behind the measurements have driven a continuous evolution of the camera systems. Here we present an intercomparison of seven different SO 2 cameras. In the first part of the experiment, the various technical designs are compared and the advantage…