Search results for " materia"

showing 10 items of 18071 documents

Polypropylene/polyhedral oligomeric silsesquioxane nanocomposites – study of free volumes, crystallinity degree and mass flow rate

2016

Nanokompozyty polipropylen/poliedryczne oligomeryczne silseskwioksany (PP/POSS) przygotowano metodą mieszania w stanie stopionym polimeru. Wpływ struktury oraz ilości zastosowanych nanonapełniaczy POSS na objętości swobodne w polipropylenie określono z zastosowaniem spektroskopii czasów życia pozytonów (PALS). Ustalono zależności pomiędzy parametrami PALS: czasem życia o-Ps (τ3) i natężeniem (I3) składowej o-Ps oraz wartościami stopnia krystaliczności (Xc ) i masowego wskaźnika szybkości płynięcia (MFR) badanych materiałów. Obecność nanonapełniaczy POSS wpłynęła na liczbę i rozmiary objętości swobodnych w polimerze, co spowodowało zmianę mikrostruktury osnowy polipropylenowej. Wraz ze zwięk…

poliedryczne oligomeryczne silseskwioksany (POSS)Materials sciencePolymers and PlasticsGeneral Chemical Engineering02 engineering and technology010402 general chemistry01 natural sciencesDegree (temperature)chemistry.chemical_compoundCrystallinitymass flow ratenanocompositesMaterials ChemistryMass flow rateComposite materialnanokompozytyPolypropyleneNanocompositepositron annihilation lifetime spectroscopy (PALS)masowy wskaźnik szybkości płynięciacrystallinity degreestopień krystaliczności021001 nanoscience & nanotechnologySilsesquioxane0104 chemical scienceschemistryspektroskopia czasów życia pozytonów (PALS)polipropylen0210 nano-technologypolypropylenepolyhedral oligomeric silsesquioxanes (POSS)Polimery
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Silseskwioksany i ich zastosowanie w syntezie materiałów polimerowych

2015

Artykuł stanowi przegląd literatury dotyczącej syntezy oraz charakterystyki materiałów polimerowych zawierających silseskwioksany (POSS). Przedstawiono metody otrzymywania hybrydowych materiałów polimerowych z udziałem funkcjonalizowanych POSS na drodze click chemistry, polikondensacji, poliaddycji, metatezy z otwarciem pierścienia ipolimeryzacji rodnikowej zarówno konwencjonalnej, jak i kontrolowanej (ATRP).

poliedryczne oligomeryczne silseskwioksany (POSS)ring opening metathesis polymerizationpolimeryzacja wolnorodnikowamateriały hybrydoweATRPpoliaddycjapolikondensacjametateza z otwarciem pierścieniaclick chemistryhybrid materialspolycondensationpolyadditionfree-radical polymerizationpolyhedral oligomeric silsesquioxane (POSS)Polimery
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Ecocompositi MaterBi (R)/Farina di legno: ottimizzazione delle proprietà attraverso analisi statistica

2009

polimeri biodegradabili analisi statistica ecocompositi farina di legnoSettore ING-IND/22 - Scienza E Tecnologia Dei Materiali
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Polacy na Krymie w latach dwudziestych i trzydziestych XX wieku

2015

Obecnie Krym zamieszkuje około stu dwudziestu pięciu narodów, wśród których Polacy stanowią dość niewielką grupę. Część współczesnych krymskich Polaków to potomkowie polskich uchodźców, którzy przybyli na półwysep w pierwszej połowie XX wieku. Artykuł prezentuje analizę znajdujących się w krymskich archiwach informacji dotyczących tej tematyki. Omawia historię działalności społeczno-kulturalnej polskiej społeczności w tym okresie. Opublikowane materiały mogą nie tylko zainteresować badaczy, lecz także być pomocne w odnawianiu zerwanych więzi rodzinnych, a również w rozwiązywaniu problemów napływających do Polski uchodźców, których liczba stale rośnie.

polscy uchodźcyKrymarchival materialspierwsza połowa XX wiekuCrimeaPolish refugeesmateriały archiwalnethe first half of the 20th centuryOblicza Komunikacji
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Compatibilization of Polylactide/Poly(ethylene 2,5-furanoate) (PLA/PEF) Blends for Sustainable and Bioderived Packaging.

2022

Despite the advantages of polylactide (PLA), its inadequate UV-shielding and gas-barrier properties undermine its wide application as a flexible packaging film for perishable items. These issues are addressed in this work by investigating the properties of melt-mixed, fully bioderived blends of polylactide (PLA) and poly(ethylene furanoate) (PEF), as a function of the PEF weight fraction (1–30 wt %) and the amount of the commercial compatibilizer/chain extender Joncryl ADR 4468 (J, 0.25–1 phr). J mitigates the immiscibility of the two polymer phases by decreasing and homogenizing the PEF domain size; for the blend containing 10 wt % of PEF, the PEF domain size drops from 0.67 &p…

poly(ethylene furanoate)compatibilizationPolymersPolyestersOrganic ChemistryPharmaceutical ScienceEthylenesfuranoatesAnalytical ChemistryOxygenSettore ING-IND/22 - Scienza E Tecnologia Dei MaterialiBlendsgas-permeabilityChemistry (miscellaneous)PolyethylenepolylactideDrug DiscoveryblendsMolecular Medicinepolylactide; furanoates; poly(ethylene furanoate); blends; compatibilization; gas-permeability; UV-shieldingUV-shieldingPhysical and Theoretical ChemistryMolecules (Basel, Switzerland)
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Effects of Polyacrylic Acid Pre-Treatment on Bonded-Dentine Interfaces Created with a Modern Bioactive Resin-Modified Glass Ionomer Cement and Subjec…

2018

Objectives: Resin-modified glass ionomer cements (RMGIC) are considered excellent restorative materials with unique therapeutic and anti-cariogenic activity. However, concerns exist regarding the use of polyacrylic acid as a dentine conditioner as it may influence the bonding performance of RMGIC. The aim of this study was to evaluate the effect of different protocols for cycling mechanical stress on the bond durability and interfacial ultramorphology of a modern RMGIC applied to dentine pre-treated with/without polyacrylic acid conditioner (PAA). Methods: The RMGIC was applied onto human dentine specimens prepared with silicon-carbide (SiC) abrasive paper with or without the use of a PAA c…

polyacrylic acid treatmentGlass ionomer cement02 engineering and technologyCementos dentales.lcsh:TechnologyAdhesivos dentales.Dental adhesives.dentinechemistry.chemical_compound0302 clinical medicineDentinGeneral Materials ScienceComposite materiallcsh:QC120-168.85bioactiveBond strengthPolyacrylic acidAbrasive021001 nanoscience & nanotechnologyDentin.adhesionmedicine.anatomical_structureDental materials.0210 nano-technologylcsh:TK1-9971cycling mechanical stressresin-modified glass ionomer cementsPolyacrylic acid - Therapeutic use.Materials scienceArticle03 medical and health sciencesstomatognathic systemlongevityDental cementmedicineMateriales dentales.Odontología restauradora.lcsh:MicroscopyDentina.CementRemineralisationDental cements.lcsh:QH201-278.5lcsh:T030206 dentistrychemistrylcsh:TA1-2040lcsh:Descriptive and experimental mechanicslcsh:Electrical engineering. Electronics. Nuclear engineeringlcsh:Engineering (General). Civil engineering (General)Ácido poliacrílico - Uso terapéutico.Dentistry Operative.Materials
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Design of New Polyaspartamide Copolymers for siRNA Delivery in Antiasthmatic Therapy

2020

Here, a novel protonable copolymer was realized for the production of polyplexes with a siRNA (inhibitor of STAT6 expression in asthma), with the aim of a pulmonary administration. The polycation was synthesized by derivatization of &alpha

polyaspartamidelcsh:RS1-441Pharmaceutical Science02 engineering and technologyArticlelcsh:Pharmacy and materia medica03 medical and health scienceschemistry.chemical_compoundpolyaminePEG ratioCopolymerpegylationDerivatization030304 developmental biologySTAT6polyplexechemistry.chemical_classification0303 health sciencesintegumentary systemMucinpolyplexesBiological membranePolymerasthma021001 nanoscience & nanotechnologychemistrysiRNABiophysicsPEGylationAmine gas treating0210 nano-technology
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A Cohesive-frictional Grain-boundary Technique for Microstructural Analysis of Polycrystalline Materials

2018

The development of a 3D microstructural model for the analysis of degradation and failure in polycrystalline materials is reviewed in the present chapter. The material is explicitly modelled at the grain level, using integral equations in conjunction with a phenomenological crystal plasticity framework for the bulk grains, and with cohesive-frictional laws to represent inter-granular micro-cracking processes. The method allows to capture the initiation, development and coalescence of damage or plasticity at the aggregate scale. The formulation’s key feature is the representation of the mechanical problem in terms of inter-granular variables only, which allows to reduce the computational cos…

polycrystalline materialsComputational micro-mechanicMaterials scienceGrain boundaryCrystalliteComposite materialSettore ING-IND/04 - Costruzioni E Strutture Aerospaziali
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Halogen-Bonded Co-Crystals of Aromatic N-oxides : Polydentate Acceptors for Halogen and Hydrogen Bonds

2017

The C-ethyl-2-methylresorcinarene (1) forms 1:1 in-cavity complexes with aromatic N,N′-dioxides, only if each of the aromatic rings has an N−O group. The structurally different C-shaped 2,2′-bipyridine N,N′-dioxide (2,2′-BiPyNO) and the linear rod-shaped 4,4′-bipyridine N,N′-dioxide (4,4′-BiPyNO) both form 1:1 in-cavity complexes with the host resorcinarene in C4v crown and C2v conformations, respectively. In the solid state, the host–guest interactions between the 1,3-bis(4-pyridyl)propane N,N′-dioxide (BiPyPNO) and the host 1 stabilize the unfavorable anti-gauche conformation. Contrary to the N,N′-dioxide guests, the mono-N-oxide guest, 4-phenylpyridine N-oxide (4PhPyNO), does not form an…

polydentateDenticityGeneral Chemical EngineeringcooperativityInorganic chemistryCooperativity010402 general chemistry01 natural sciencesInorganic Chemistrychemistry.chemical_compounddiiodoperfluoroalkanesPyridinelcsh:QD901-999General Materials ScienceC−H···O interactionsta116hydrogen bondN−O groupHalogen bondvetysidokset010405 organic chemistryChemistryHydrogen bondH···O interactionsperfluoroalkylCondensed Matter Physicshalogen bond; hydrogen bond; aromatic N-oxides; perfluoroalkyl; diiodoperfluoroalkanes; polydentate; N−O group; cooperativity; C−H···O interactionsAcceptor0104 chemical sciencesaromatic N-oxidesCrystallographyHalogenorgaaninen kemiahalogen bondlcsh:CrystallographySingle crystalC−röntgenkristallografia
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Raman Investigations to Identify Corallium rubrum in Iron Age Jewelry and Ornaments

2016

International audience; During the Central European Iron Age, more specifically between 600 and 100 BC, red precious corals (Corallium rubrum) became very popular in many regions, often associated with the so-called (early) Celts. Red corals are ideally suited to investigate several key questions of Iron Age research, like trade patterns or social and economic structures. While it is fairly easy to distinguish modern C. rubrum from bone, ivory or shells, archaeologists are confronted with ancient, hence altered, artifacts. Due to ageing processes, archaeological corals lose their intensive red color and shiny surface and can easily be confused with these other light colored materials. We pr…

polyeneslcsh:QE351-399.2[SHS.ARCHEO]Humanities and Social Sciences/Archaeology and PrehistoryDistribution networks02 engineering and technologyBiology010502 geochemistry & geophysics01 natural sciencescorals; shells; Raman spectroscopy; biogenic carbonates; carotenoids; polyenes; color fading; material degradation; archaeology[CHIM.ANAL]Chemical Sciences/Analytical chemistryArchaeological researchMaterial DegradationCorallium rubrumcoral0105 earth and related environmental sciencesmaterial degradationlcsh:MineralogyEcologycarotenoidscolor fadingGeologyOrnamentsarchaeology021001 nanoscience & nanotechnologyGeotechnical Engineering and Engineering Geologybiogenic carbonatesshellscoralsIron AgeRaman spectroscopy0210 nano-technology[SDU.STU.MI]Sciences of the Universe [physics]/Earth Sciences/MineralogyMinerals
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