Search results for " metal"
showing 10 items of 2159 documents
A new approach to the synthesis of intermetallic compounds: mild synthesis of submicrometric CoxMy (M = Mo, W; x∶y = 3∶1 and 7∶6) particles by direct…
2002
A simple processing route to cobalt–molybdenum and cobalt–tungsten intermetallics (CoxMy, where M = Mo and W, and x∶y = 3∶1 and 7∶6) has been developed, on the basis of the use of precursors resulting from freeze-drying of aqueous solutions of the appropriate common metal salts. The influence of the preparative variables on the outcomes of this procedure is examined. These compounds are prepared as single phases by thermal reduction of amorphous freeze-dried powders under a hydrogen–argon atmosphere (8% H2), followed by slow cooling of the samples. The materials have been characterised by X-ray powder diffraction, metal analysis, scanning electron microscopy and thermogravimetry under an ox…
Influence of sample pan on the thermal behaviour of KSCN measured with TG
2003
Abstract In this study, the influence of the sample pan on the thermal behaviour of potassium thiocyanate (KSCN) was investigated. The measurements were performed with thermogravimetry (TG) and the two sample pans used were a platinum pan and a ceramic crucible. The samples were heated to 400–950 °C and the thermal products were identified by powder diffraction. The thermal behaviour of KSCN was found to be dependent on the sample pan used. With the platinum sample pan KSCN reacted in the first step into a mixture of K 2 SO 4 and potassium tetracyanoplatinate (K 2 Pt(CN) 4 ). In the second step, the mixture reacted further to pure K 2 SO 4 . In the ceramic sample crucible, however, the reac…
Experimental Investigation of the Shear Response of Precast Steel-Concrete Trussed Beams
2017
The results of an experimental campaign of three-point bending tests on precast composite beams, named hybrid steel-trussed concrete beams (HSTCBs), are provided. HSTCBs are typically constituted by a precast steel truss embedded in a block of concrete cast in place. Two series of specimens were manufactured, designed such that shear failure would occur, and tested under positive and negative bending moment. The experimental results obtained showed that fragile shear failure occurred in almost all cases, evidencing the crisis of the compressed concrete strut involved in the collapse mechanism. Yielding of the steel members provided ductility to the system, especially in those cases in which…
First-principles simulations of hydrogen peroxide formation catalyzed by small neutral gold clusters.
2009
Energetics and dynamical pathways for hydrogen peroxide formation from H(2) and O(2) bound to neutral gold dimers and tetramers have been investigated by applying several strategies: T = 0 K geometry optimizations, constrained Car-Parrinello molecular dynamics simulations at T = 300 K and metadynamics at T = 300 K. The competing reaction channels for water and hydrogen peroxide formation have been found and characterized. In each case, the reaction barriers for Au cluster catalyzed proton transfer are less than 1 eV. Water formation is a competitive reaction channel, and the relative weight of H(2)O and H(2)O(2) products may depend on the chosen Au cluster size. Dynamic simulations demonstr…
Mathematical model for the adsorption-induced nonlocal frequency shift in adatoms-nanobeam system
2017
Abstract This paper models and investigates the resonance frequency shift induced by the adsorption phenomena for an adatoms-nanobeam system including the small scale effect as well as rotary inertia and shear distortion effects. The Lennard-Jones (6–12) type potential is used to determine the adsorption-induced energy owing van der Waals (vdW) interaction mechanism between adatom-adatom and adatom-substrate. The small scale effect is introduced by using Eringen's nonlocal elasticity theory while the explicit expressions of inertia moment and shear force are derived from the standard Timoshenko beam equations in which the residual stress effect is accounted as an additive axial load. Numeri…
An Automated Visual Inspection System for the Classification of the Phases of Ti-6Al-4V Titanium Alloy
2013
Metallography is the science of studying the physical properties of metal microstructures, by means of microscopes. While traditional approaches involve the direct observation of the acquired images by human experts, Com-puter Vision techniques may help experts in the analysis of the inspected mate-rials. In this paper we present an automated system to classify the phases of a Titanium alloy, Ti-6Al-4V. Our system has been tested to analyze the final products of a Friction Stir Welding process, to study the states of the micro-structures of the welded material.
Geochemical investigation of trace metal pollutants in the Oreto river, Palermo (Italy)
2022
In the past, three main rivers, named Kemonia, Papireto and Oreto, were present in the plain of Palermo, in northwestern Sicily. Today, only the latter one has been preserved from the unregulated urban expansion. Fortunately, over the last ten years, attention and consciousness towardsthe Oreto river and its delicate ecosystem has grown considerably, also thanks to many associations and citizens’ committees involved in protecting, preserving and valorising the precious area. In this context, our study is focused on a hydrogeochemical investigation of its surface water quality. The Oreto river flows for about 20 km within a catchment area of about 130 km2. Over the past three years, numerous…
The contribution of volcanoes to the atmospheric trace metals budget in the Mediterranean basin
2009
Volcanic emissions represent one of the major natural source for several trace metals (Cd, Cu, As, Pb, Hg and Zn) into the atmosphere both as gaseous and aerosol forms. The Mediterranean Sea can be considered a large geochemical sink for these elements whose source are the huge amounts of aerosols of different origin. The industrialised areas located in the northern part of the basin represent a nearly constant source of the anthropogenic-dominated aerosol. By contrast, the arid and desert regions located at the southern and eastern parts of the Mediterranean, are the sources of frequent dust “pulses” perturbing the “steady-state” conditions of the local atmosphere through the input of seve…
Sedimentary record of anthropogenic chemical and organic pollution in a Mediterranean coastal area (Gulf of Palermo, Italy).
2009
The relatively high influx of unregulated industrial and domestic effluents has progressively degraded the Palermo coastal environment in NW Sicily. To evaluate the poorly known effects of these inputs on the Palermo Gulf, three sediment box-cores were collected along a transect perpendicular to the coast, in front of the Oreto river mouth, in water depths of 20—750 m. The samples, dated by 210Pb and 137Cs, were analysed for concentration of major/trace elements, total polycyclic aromatic hydrocarbon (PAH), total organic carbon (TOC) and for organic carbon and nitrogen isotopic compositions. Total organic carbon concentrations show relatively high values (0.4—2.9%), with a decreasing seawar…
Geochemical comparison of natural and anthropogenic metal fluxes in extreme environments: Mt. Etna volcano (Italy) and Šalek Valley (Slovenia)
2009
Geochemical comparison between some metals (As, Cd, Cu, Pb, Se, V, Zn) emissions from an active volcano (Mt. Etna) and a highly industrialized area (Šalek Valley) showed some interesting similarities: in general, most of the elements emitted into the atmosphere do not return to the Earth’s surface and are therefore dispersed into the environment. Exceptions for Šalek Valley are Cd, which probably derives in large part from rock leaching, and in part As and Pb, which fall mostly as ash. Also, Etna’s emissions are richer in Cd and Cu, whereas industrial emissions at Šalek Valley are richer in V and Zn. All other metals have similar fluxes in the two types of emissions.