Search results for "BOX"

showing 10 items of 2676 documents

Polyamines and ripening of photoreceptor outer segments in chicken embryos.

1995

Abstract Polyamines and their related monoacetyl derivatives were studied in rod outer segment (ROS) and cone outer segment (COS) of photoreceptor cells from chick embryo retina during eye development (7th–18th days). Putrescine was found to be necessary, in the second phase of retinogenesis, to sustain both ROS and COS differentiation and, after acetylation, γ-aminobutyric acid synthesis. On the other hand, spermidine and even more spermine intervene in the third phase of development when photoreceptors mature. Moreover, the presence of N1-acetylspermidine already at the 7th day indicates that in the outer segment of photoreceptor cells too, as in the whole retina, putrescine synthesis com…

genetic structuresSpermineChick EmbryoBiologyOrnithine DecarboxylaseRetinaOrnithine decarboxylasechemistry.chemical_compoundDevelopmental NeuroscienceAcetyltransferasesCadaverinemedicinePutrescineAnimalsPhotoreceptor Cellsgamma-Aminobutyric AcidRetinaBiogenic PolyaminesCell DifferentiationRod Cell Outer SegmentSpermidinemedicine.anatomical_structurechemistryBiochemistrySpermine synthasebiology.proteinPutrescineSperminesense organsSpermidine synthasePolyamine oxidaseDevelopmental BiologyInternational journal of developmental neuroscience : the official journal of the International Society for Developmental Neuroscience
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Resonance properties of GABAergic interneurons in immature GAD67-GFP mouse neocortex.

2014

Subthreshold resonance is a characteristic membrane property of different neuronal classes, is critically involved in the generation of network oscillations, and tunes the integration of synaptic inputs to particular frequency ranges. In order to investigate whether neocortical GABAergic interneurons show resonant behavior already during early postnatal development, we performed whole-cell patch-clamp recordings from visually identified interneurons in supragranular layers of parietal regions in coronal neocortical slices from postnatal day (P) P6-P13 GAD67-GFP knock-in mice. Subthreshold resonance was analyzed by injection of sinusoidal current with varying frequency. About 50% of the inve…

genetic structuresSubthreshold membrane potential oscillationsGlutamate decarboxylaseGreen Fluorescent ProteinsNeocortexSodium ChannelsMembrane PotentialsCalcium Channels T-TypeMiceInterneuronsParietal LobemedicineAnimalsGene Knock-In TechniquesGABAergic NeuronsMolecular BiologyMembrane potentialNeocortexSubthreshold conductionChemistryGlutamate Decarboxylasemusculoskeletal neural and ocular physiologyGeneral NeuroscienceResonanceMembrane hyperpolarizationmedicine.anatomical_structurenervous systemGABAergicNeurology (clinical)NeuroscienceDevelopmental BiologyBrain research
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Diorganotin(IV) complexes ofD-galacturonic acid: solid-state and solution-phase structural study

2003

Three diorganotin(IV) complexes of D-galacturonic acid (H2GalA; R = Me, n-Bu, Ph), two of which are new derivatives (R = Me, Ph), have been synthesized and their solid-state and solution-phase investigated by IR, Mossbauer, 1H, 13C and 119Sn NMR spectroscopy. The FTIR data suggest that H2GalA, in the dialkyltin derivatives, behaves as a dianionic ligand, coordinating the tin(IV) atom through an ester-type carboxylate and deprotonated alcoholic hydroxo groups, whereas a bridging carboxylate occurs in the diphenyltin(IV) complex. Octahedral and trigonal bipyramidal local geometries on tin(IV) atoms are proposed for dialkyltin(IV)GalA and diphenyltin(IV)GalA complexes respectively on the basis…

geometryalpha pyranosidesynthesisStereochemistryMossbauer spectroscopychemistry.chemical_elementproton nuclear magnetic resonanceMedicinal chemistrystructure analysiInorganic Chemistrychemistry.chemical_compoundDeprotonationcomplex formationMoleculegalacturonic acidorganotin compoundCarboxylateDiorganotininfrared spectroscopybeta furanosidic acidbeta pyranosidedecompositiondiphenyltin galacturonic acid complexLigandarticlecarboxyl groupsolid stateGeneral ChemistryNuclear magnetic resonance spectroscopycarbon nuclear magnetic resonanceNMRdiphenyltin complexunclassified drugTrigonal bipyramidal molecular geometrychemistryOctahedronChemistry (miscellaneous)Settore CHIM/03 - Chimica Generale E InorganicaMössbauerTinApplied Organometallic Chemistry
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Imidazolium-2-carboxylate as an afficient, expeditious and eco-friendly organocatalyst for glycerol carbonate synthesis

2009

An improved and greener approach towards the synthesis of glycerol carbonate, via transesterification, using 1-n-butyl-3-methylimidazolium-2-carboxylate as catalyst is described. The catalyst loading as low as 1% was sufficient to yield quantitative conversions. A plausible mechanism is proposed for the catalytic cycle leading to product formation.

glycerol carbonate010405 organic chemistryChemistry[CHIM.CATA]Chemical Sciences/CatalysisGeneral ChemistryTransesterification010402 general chemistry01 natural sciencesEnvironmentally friendly0104 chemical sciencesCatalysistransesterificationchemistry.chemical_compoundimidazolium-2-carboxylates[ CHIM.CATA ] Chemical Sciences/CatalysisCatalytic cycleorganic catalysisdimethyl carbonateGlycerolOrganic chemistryCarbonateCarboxylateDimethyl carbonateComputingMilieux_MISCELLANEOUS
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Hbox12: an old gene with a new function.

2013

hbox12 embryo development sea urchin.Settore BIO/11 - Biologia Molecolare
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Advanced biorefinery concepts related to non-wood feedstocks

2018

Agricultural residues, such as wheat straw (Triticum aestivum), okra stalk (Abelmoschus esculentus), and giant miscanthus (Miscanthus × giganteus, a hybrid of M. sinensis and M. sacchariflorus) were investigated to assess their possible consumption for integrated lignocellulosic biorefining. The efficient fractionation and recovery of all important chemical components (cellulose, hemicelluloses, and lignin) of such feedstocks are a prerequisite for realistic biorefinery concepts. Water is one of the most eco-friendly solvents with the highest potential for industrial use, and it is also suitable for full-scale biorefinery purposes. For example, under pressure at elevated temperatures over 1…

hemiselluloosakarboksyylihapotbiomassaaliphatic carboxylic acidsselluloosafood and beveragesalkaline pulpingligninligniinihot-water extractionesikäsittelynon-wood feedstockkasvimateriaalitbiojalostamotuuttomassanvalmistusbiorefining
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CCDC 1508045: Experimental Crystal Structure Determination

2021

Related Article: Raminder S. Mulla, Javier Pitarch-Jarque, Enrique García-España, Tanya Desa, Elena Lurie-Luke, J. A. Gareth Williams|2017|Chem. Sel.|2|5045|doi:10.1002/slct.201700995

hexa-sodium bis(mu-22'-({2-[(carboxylatomethyl){2-[(carboxylatomethyl)amino]-2-oxoethyl}amino]ethyl}azanediyl)diacetato)-diaqua-di-calcium(ii) bis(chloride) hydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 732637: Experimental Crystal Structure Determination

2010

Related Article: E.Colacio, H.Aouryaghal, A.J.Mota, J.Cano, R.Sillanpaa, A.Rodriguez-Dieguez|2009|CrystEngComm|11|2054|doi:10.1039/b906382j

hexakis((mu~2~-Pyrimidine-2-carboxylato)-(NNN'N'-tetramethyl-ethylene-12-diamine))-hexa-cobalt hexaperchlorate tetrahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 725441: Experimental Crystal Structure Determination

2010

Related Article: E.Colacio, H.Aouryaghal, A.J.Mota, J.Cano, R.Sillanpaa, A.Rodriguez-Dieguez|2009|CrystEngComm|11|2054|doi:10.1039/b906382j

hexakis((mu~2~-Pyrimidine-2-carboxylato)-(NNN'N'-tetramethyl-ethylene-12-diamine))-hexa-nickel hexakis(tetrafluoroborate) tetrahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 725440: Experimental Crystal Structure Determination

2010

Related Article: E.Colacio, H.Aouryaghal, A.J.Mota, J.Cano, R.Sillanpaa, A.Rodriguez-Dieguez|2009|CrystEngComm|11|2054|doi:10.1039/b906382j

hexakis((mu~2~-Pyrimidine-2-carboxylato)-(NNN'N'-tetramethyl-ethylene-12-diamine))-hexa-nickel hexaperchlorate tetrahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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