Search results for "Base"
showing 10 items of 8362 documents
Tuning the Electrochemistry of Free-Base Porphyrins in Acidic Nonaqueous Media: Influence of Solvent, Supporting Electrolyte, and Ring Substituents
2016
International audience; A detailed study of reduction potentials, electroreduction mechanisms and acid-base chemistry was carried out on two series of free-base porphyrins in nonaqueous media. The first series is represented by four-pyrrole substituted tetraphenylporphyrin (TPP) derivatives, two of which are planar and two of which are nonplanar in their non-protonated form. The second comprises porphyrins with 0-4 meso-phenyl groups on the macrocycle. Equilibrium constants for conversion of each neutral porphyrin to its diprotic [H4P] 2+ form were determined and the electrochemistry was then elucidated as a function of: (i) type of nonaqueous solvent, (ii) anion of supporting electrolyte, …
Theoretical space-time modelling of the diffusion of raw materials and manufactured objects
2013
International audience; Workgroup 3 of ArchaeDyn II programme focuses its study on the diffusion systems of ancient products. In order to be able to structure data in GIS in an appropriate way, we propose a general theoretical modelling integrating the different components of the diffusion systems, and identifying their interactions and the factors affecting the location of products and their transfers. Three dimensions are considered: the Time, the Space and the Function of places. A product's pathway can be apprehended efficiently by distinguishing spatial entities as well as functional entities. This modelling highlights the fact that the approach through the simple notion of "site" is n…
Estimating finite mixtures of semi-Markov chains: an application to the segmentation of temporal sensory data
2019
Summary In food science, it is of great interest to obtain information about the temporal perception of aliments to create new products, to modify existing products or more generally to understand the mechanisms of perception. Temporal dominance of sensations is a technique to measure temporal perception which consists in choosing sequentially attributes describing a food product over tasting. This work introduces new statistical models based on finite mixtures of semi-Markov chains to describe data collected with the temporal dominance of sensations protocol, allowing different temporal perceptions for a same product within a population. The identifiability of the parameters of such mixtur…
Bimodal sill emplacement from an inhomogeneous source: a case study of olivine-gabbronorite and diabase with Ni-Cu sulphides in a sill within Permian…
2009
A small outcrop of mafic rocks, located between the Permian-Triassic sediments of the Cenozoic tectonic unit of the Maghrebian chain in Western Sicily, is an olistolith made up of olivine gabbronorite within diabase. Textures, microprobe analyses, and major and trace element geochemistry confirm the co-genetic nature of the various rocks: the gabbronorite is the result of olivine and orthopyroxene accumulation, with interstitial clinopyroxene and plagioclase, in a framework of a gabbrodioritic diabase. At least two stages of magmatic crystallisation during ascent in the continental crust are described, on the basis of reconstructed conditions of T, P and XH2O. The primitive magma was recons…
Pinpointing the SMBH in NGC1052
2016
Supermassive black holes (SMBH) are essential for the production of jets in radio-loud active galactic nuclei (AGN). Theoretical models based on Blandford & Znajek (1977MNRAS.179..433B) extract the rotational energy from a Kerr black hole, which could be the case for NGC1052, to launch these jets. This requires magnetic fields on the order of 1000G to 10000G. We imaged the vicinity of the SMBH of the AGN NGC1052 with the Global Millimetre VLBI Array and found a bright and compact central feature that is smaller than 1.9 light days (100 Schwarzschild radii) in radius. Interpreting this as a blend of the unresolved jet bases, we derive the magnetic field at 1 Schwarzschild radius to lie betwe…
Sub-milliarcsecond imaging of 3C111
2020
Flares in radio-loud active galactic nuclei (AGNs) are thought to be associated with the injection of fresh plasma into the compact jet base. Such flares are usually strongest and appear earlier at shorter radio wavelengths. Hence, very long baseline interferometry (VLBI) at millimeter (mm)-wavelengths is the best-suited technique for studying the earliest structural changes of compact jets associated with emission flares. Aims. We study the morphological changes of the parsec-scale jet in the nearby (z=0.049) gamma-ray bright radio galaxy 3C 111 following a flare that developed into a major radio outburst in 2007. We analyse three successive observations of 3C 111 at 86 GHz with the Global…
S5 0836+710 Ground and Space VLBI images
2020
Detailed studies of relativistic jets in active galactic nuclei (AGN) require high-fidelity imaging at the highest possible resolution. This can be achieved using very long baseline interferometry (VLBI) at radio frequencies, combining worldwide (global) VLBI arrays of radio telescopes with a space-borne antenna on board a satellite. We present multiwavelength images made of the radio emission in the powerful quasar S5 0836+710, obtained using a global VLBI array and the antenna Spektr-R of the RadioAstron mission of the Russian Space Agency, with the goal of studying the internal structure and physics of the relativistic jet in this object. The RadioAstron observations at wavelengths of 18…
Distributed n-player approachability via time and space average consensus
2012
Abstract In this paper we consider repeated coalitional games with transferable utilities (TU) over networks. Namely, we consider a set of n players that have to distribute among themselves a vector of rewards (one for each player). In our network version there is no coordinator allocating the rewards, but the agents have to agree on a common time-averaged vector by updating the local estimates of the reward vector. The common time-averaged reward vector has to approach a suitable constraint set, called core of the game, that guarantees that no agents benefit from quitting the grand coalition. We propose a doubly (over time and space) averaging distributed algorithm. At every iteration, eac…
Service Provisioning and User Association for Heterogeneous Wireless Railway Networks
2017
In addition to comforting passengers' journey, the modern railway system is responsible to support a variety of on-board Internet services to meet the passenger's demands on seamless service provisioning. In order to provide wireless access to the train, one idea attracting increasing attention is to deploy a series of track-side access points (TAPs) with high-speed data rates along the rail lines dedicated to the broadband mobile service provisioning on board. Due to the heavy data traffic flushing into the base stations (BSs) of the cellular networks, TAPs act as a complement to the BSs in data delivery. In this paper, we focus on the TAP association problem for service provisioning in a …
Service Provisioning with Multiple Service Providers in 5G Ultra-dense Small Cell Networks
2015
In this work, a game theoretical approach for addressing the virtual network service providers (NSPs), small cell provider (SCP) and user interaction in heterogenous small cell networks is presented. In particular, we consider the users can select the services of different NSPs based on their prices. The NSPs have no dedicated hardware and need to rent from the SCP in term of radio resources, e.g., small cell base stations (SBSs) in order to provide satisfied services to the users. Due to the fact that the selfish parties involved aim at maximizing their own profits, a hierarchical dynamic game framework is presented to address interactive decision problem. In the lower-level, a Stackelberg…