Search results for "ESOL"
showing 10 items of 2444 documents
On-line measurements of RuO$_4$ during a PWR severe accident
2015
International audience; After the Fukushima accident, it became essential to have a way to monitor in real time the evolution of a nuclear reactor during a severe accident, in order to react efficiently and minimize the industrial, ecological and health consequences of the accident. Among gaseous fission products, the tetroxide of ruthenium RuO$_4$ is of prime importance since it has a significant radiological impact. Ruthenium is a low volatile fission product but in case of the rupture of the lower head by the molten corium, the air entering into the vessel oxidizes Ru into gaseous RuO$_4$, which is not trapped by the Filtered Containment Venting Systems. To monitor the presence of RuO$_4…
Multi-Resolution error analysis of predicted absorption coefficients. Method and computer implementation. Application to the infrared spectrum of met…
2009
A general method for the estimation of the confidence interval of molecular absorption coefficients is presented. It combines statistical numerical experiments with analytical calculations. The method uses line parameter predictions (position and intensity) with known estimated uncertainties. The propagation of errors from line parameters to absorption coefficients or cross-sections are analyzed in detail as a function of the resolution. This work is especially intended to provide expert information for applications requiring theoretical predictions for which the present state of the art of line by line high-resolution modeling is not accurate enough to meet the experimental precision. As a…
Theoretical principles of near-field optical microscopies and spectroscopies
2000
International audience; This paper deals with the principles of detection of optical signals near a surface in a manner permitting the mapping of the distribution of the fields close to various kinds of illuminated samples. We begin with a discussion of the main physical properties of the optical fields near a surface in the absence of any probe tip. This mainly concerns phenomena involving evanescent waves for which the local decay lengths are governed not only by the sizes but also by the intrinsic properties of the surface structures. The interpretation of the detection process is reviewed on the basis of a discussion about the possibility of establishing direct comparisons between exper…
Femtosecond Raman time-resolved molecular spectroscopy
2004
International audience; The applicability of several femtosecond time resolved non-linear coherent techniques such as Raman induced polarization spectroscopy (RIPS), degenerate four-wave mixing (DFWM) and coherent anti-Stokes Raman spectroscopy (CARS) for molecular spectroscopy is presented. All methods rely on the initial coherent excitation of molecular states producing wavepackets, whose time evolution is then measured. In the case of RIPS and DFWM only pure rotational transitions are involved, whereas in CARS vibrational states can be excited. First the methodology of concentration and temperature measurements using RIPS in gas mixtures involving N2, CO2, O2, and N2O is shown. In additi…
Spatio-Temporal Beam Mapping for Studying Nonlinear Dynamics in Graded Index Multimode Fiber
2020
We experimentally demonstrate high-resolution mapping of the spatio-temporal dynamics of the beam cleaning process in graded index multimode fibers. This high-resolution characterization reveals the time-dependent nature of the beam self-cleaning process.
Negatively Curved Nanographene with Heptagonal and [5]Helicene Units
2020
Negatively curved nanographene (NG) 4, having two heptagons and a [5]helicene, was unexpectedly obtained by aryl rearrangement and stepwise cyclodehydrogenations. X-ray crystallography confirmed the saddle-shaped structures of intermediate 3 and NG 4. The favorability of rearrangement over helicene formation following radical cation or arenium cation mechanisms is supported by theoretical calculations. NG 4 demonstrates a reversible mechanochromic color change and solid-state emission, presumably benefiting from its loose crystal packing. After resolution by chiral high-performance liquid chromatography, the circular dichroism spectra of enantiomers 4-(P) and 4-(M) were measured and showed …
High resolution study of the SO2 infrared spectra: calculation scheme for assignment of transitions in very weak ro-vibrational bands.
2009
Neolithic Human Societies and Woodlands in the North-Western Mediterranean Region: Wood and Charcoal Analysis
2017
An overview of woodland history in the north-western Mediterranean region, based on charcoal analysis (Anthracology) from Mesolithic and Neolithic sites, is proposed for the Mediterranean areas of France, Spain and Portugal. The taxonomic identification of charcoal fragments and the diachronic variations of taxa frequencies provide, for each settlement, an accurate image of the local vegetal cover. During the end of the last glaciation, beginning of the Holocene, vegetation dynamics reflects the evolution of climatic and geographic conditions. Any potential ecological impact by hunter-fisher-gatherer communities (Mesolithic) remains invisible; the same comment applies to the farming-herding…
Système de prise d'images haute résolution pour l'analyse de projection de particules : application à l'épandage centrifuge d'engrais
2002
This paper describes the design of a high resolution low cost imaging system for the analysis of high speed particle projection. This system, based on a camera and a set of flashes, is used to characterize the centrifugal spreading of fertilizer particles ejected at speeds of environ 30 m s. Multiexposure images collected with the camera installed perpendicular to the output flow of granules are analysed to estimate the trajectories of the fertilizer granules. Very good results are obtained with the Markov random fields method, in comparison with others.
Mapping intra-plot topsoil diversity of Burgundy vineyards (Aloxe- Corton, France) from very high spatial resolution (VHSR) images
2012
International audience; In this work, we present a method based on very high spatial resolution (VHSR) aerial images acquired in the visible domain and that map soil surface diversity at the hillslope scale with a spatial resolution of a few centimeters. This method combines aerial VHSR image classification with local soil sampling. Principal component analysis (PCA) and non-supervised classification was performed on image characteristics to define soil surface characteristic classes (SSC). Then soil surface mapping was combined with soil surface descriptions and soil profiles to define soil types by physical and chemical characteristics.