Search results for "HAP"
showing 10 items of 2767 documents
Depicting signs and different text genres : Preliminary observations in the corpus of Finnish sign language
2018
In this article we first discuss the different kinds of signs occurring in sign languages and then concentrate on depicting signs, especially on their classification in Finnish Sign Language. Then we briefly describe the corpora of Finland's sign languages (CFINSL). The actual study concerns the occurrences of depicting signs in CFINSL in different text genres, introductions, narratives and free discussions. Depicting signs occurred most frequently in narratives, second most frequently in discussions and least frequently in introductions. The most frequent depicting signs in all genres were those that depicted the whole entity moving or being located. The second most frequent were those sig…
Oxidation-Induced Changes in the ALD-Al2O3/InAs(100) Interface and Control of the Changes for Device Processing
2018
InAs crystals are emerging materials for various devices like radio frequency transistors and infrared sensors. Control of oxidation-induced changes is essential for decreasing amounts of the harmful InAs surface (or interface) defects because it is hard to avoid the energetically favored oxidation of InAs surface parts in device processing. We have characterized atomic-layer-deposition (ALD) grown Al2O3/InAs interfaces, preoxidized differently, with synchrotron hard X-ray photoelectron spectroscopy (HAXPES), low-energy electron diffraction, scanning tunneling microscopy, and time-of-flight elastic recoil detection analysis. The chemical environment and core-level shifts are clarified for w…
Reduction-oxidation dynamics of oxidized graphene: Functional group composition dependent path to reduction
2018
Micrometer-sized oxidation patterns containing varying composition of functional groups including epoxy, ether, hydroxyl, carbonyl, carboxyl, were created in chemical vapor deposition grown graphene through scanning probe lithography and pulsed laser two-photon oxidation. The oxidized graphene films were then reduced by a focused x-ray beam. Through in-situ x-ray photoelectron spectroscopy measurement, we found that the path to complete reduction depends critically on the total oxygen coverage and concentration of epoxy and ether groups. Over the threshold concentrations, a complex reduction-oxidation process involving conversion of functional groups of lower binding energy to higher bindin…
Revealing lattice disorder, oxygen incorporation and pore formation in laser induced two-photon oxidized graphene
2019
Abstract Laser induced two-photon oxidation has proven to be a reliable method to pattern and control the level of oxidation of single layer graphene, which in turn allows the development of graphene-based electronic and optoelectronic devices with an all-optical method. Here we provide a full structural and chemical description of modifications of air-suspended graphene during the oxidation process. By using different laser irradiation doses, we were able to show via transmission electron microscopy, electron energy loss spectroscopy, electron diffraction and Raman spectroscopy how graphene develops from its pristine form up to a completely oxidized, porous and amorphous carbon layer. Furt…
Mechanistic Origins of the pH Dependency in Au-Catalyzed Glycerol Electro-oxidation: Insight from First-Principles Calculations
2021
Electrocatalytic oxidation of glycerol (EOG) is an attractive approach to convert surplus glycerol to value-added products. Experiments have shown that EOG activity and selectivity depend not only on the electrocatalyst but also on the electrode potential, the pH, and the electrolyte. For broadly employed gold (Au) electrocatalysts, experiments have demonstrated high EOG activity under alkaline conditions with glyceric acid as a primary product, whereas under acidic and neutral conditions Au is almost inactive producing only small amounts of dihydroxyacetone. In the present computational work, we have performed an extensive mechanistic study to understand the pH and potential dependency of …
Effect of ozone and hydrogen peroxide on off-flavor compounds and water quality in a recirculating aquaculture system
2022
The recirculating aquaculture system (RAS) is an ever-developing technology for producing fish with a low environmental impact. However, off-flavors can be a major problem in RAS fish production. Off-flavor compounds are of microbial origin and are accumulated in fish flesh. They typically cause a musty and earthy taste and odor, which consumers find unacceptable. Here we hypothesized that oxidizing compounds such as ozone (O3), hydrogen peroxide (H2O2), and their combinations, referred to as advanced oxidation processes (AOP)s, can remove or decrease these compounds in water and prevent their accumulation in fish. In this study, four different oxidative treatments (O3 low (0.4 mg O3 L−1), …
Puumateriaalin kemiallinen käyttäytyminen sulfaattikeiton alkalisessa etanoliesikäsittelyssä
2002
Puun alkalisessa kuidutuksessa hiilihydraatit, pääasiassa hemiselluloosat, päätepilkkoutuvat ns. peeling-reaktion mukaisesti, jolloin reaktiotuotteina syntyy ensisijaisesti alifaattisia karboksyylihappoja. Kyseinen reaktio aiheuttaa huomattavia saantotappioita ja heikentää tuotettavan massan laatua. Hiilihydraattiketjun peeling-reaktio voidaan estää muuntamalla ketjun pelkistävä pääteryhmä kemiallisesti esimerkiksi hapettamalla. Tässä tutkimuksessa hiilihydraattien pelkistävän pääteryhmän hapettaminen tehtiin hapella, jonka imeytymistä alkaliseen esikäsittelyliuokseen tehostettiin etanolilisäyksen avulla. Vertailun vuoksi esikäsittelyjä tehtiin myös pelkällä natriumhydroksidillä typpiilmake…
Alusveden hapetuksen vaikutukset Vesijärven pohjaeläimistöön - vuoden 2012 tulokset
2013
[Johdanto] Tämän Lahden Vesijärveä koskevan pohjaeläinselvityksen tavoitteena oli selvittää vuonna 2010 aloitetun laajamittaisen alusveden hapetuksen vaikutuksia järven syvännepohjaeläimistön tilaan. Hapetuksen vaikutusten esiin saamiseksi hapetusvuosien tilaa verrattiin vuonna 2009 tehtyyn esiselvitykseen (Hynynen & Salmelin 2010), jossa selvitettiin Lahden Vesijärven pohjaeläimistöä ennen järven syvänteiden hapetusta sekä kahden ensim-mäisen hapetusvuoden tuloksiin (Hynynen 2011, Tolonen & Hynynen 2012). Lahden edustalla sijaitsevaa Enonselän syvännealuetta hapetetaan yhdeksällä päällysvettä alusveteen pumppaavalla hapettimella (Salmi et al. 2010). Hankkeista vastaa Lahden kaupungin tekni…
Alusveden hapetuksen ja PHOSLOCK-käsittelyn vaikutukset Kymijärven syvännepohjaeläimistöön - vuoden 2012 tulokset.
2013
[Johdanto] Tämä toinen Kymijärven syvännepohjaeläimistöä koskeva tutkimus toteutettiin syksyllä 2012. Tutkimuksen tarkoituksena oli selvittää järven kunnostustoimena toteutetun hapetuksen sekä kesällä 2012 suoritetun PHOSLOCK-käsittelyn vaikutuksia Kymijärven syvänteiden pohjaeläimistöön ja ekologiseen tilaan. Järven pohjoista Myllypohjan syvännettä on hapetettu kesästä 2008 alkaen hapekasta päällysvettä alusveteen pumppaavalla Mixox-hapettimella (Kukkonen 2011). Alkukesästä 2012 eteläisessä Lapinkiven syvänteessä on järven kunnostustoimena lisäksi toteutettu PHOSLOCK-käsittely, jossa bentoniittisaveen liitetyt lantaani kationit (La³⁺) sitovat pohjaan laskeutuessaan valtaosan veden reaktiiv…
Experimental and Theoretical Investigations of the Redox Behavior of the Heterodichalcogenido Ligands [(EPiPr2)(TePiPr2)N]− (E = S, Se): Cyclic Catio…
2008
The two-electron oxidation of the lithium salts of the heterodichalcogenidoimidodiphosphinate anions [(EPiPr2)(TePiPr2)N]− (1a, E = S; 1b, E = Se) with iodine yields cyclic cations [(EPiPr2)(TePiPr2)N]+ as their iodide salts [(SPiPr2)(TePiPr2)N]I (2a) and [(SePiPr2)(TePiPr2)N]I (2b). The five-membered rings in 2a and 2b both display an elongated E−Te bond as a consequence of an interaction between tellurium and the iodide anion. One-electron reduction of 2a and 2b with cobaltocene produces the neutral dimers (EPiPr2NPiPr2Te−)2 (3a, E = S; 3b, E = Se), which are connected exclusively through a Te−Te bond. Two-electron reduction of 2a and 2b with 2 equiv of cobaltocene regenerates the corresp…