Search results for "LIMIT"
showing 10 items of 2826 documents
An examination of the views of young people in the Romanian residential care system regarding their relationship with biological family members and t…
2017
ABSTRACTThis paper reports findings from research conducted in six Romanian residential care homes. The aim of the paper is to examine the views held by young people, currently living in residential care, about the importance of their biological families and the option and challenge of reintegration. The data reflect the ideas and perspectives of 44 young people captured through a narrative interview approach using social mapping activities. The results indicate that most children and young people know at least one birth parent and maintain contact on their own initiative; most do not place a high level of importance on such relationships which are generally characterised by lack of confide…
LC of high to moderately polar basic drugs in urine with water and detergent, and direct injection
2016
Background: Micellar LC was first proposed as a ‘green’ mode using mobile phases of water and surfactant. However, in most procedures a small amount of organic solvent is required to decrease the retention to convenient values. Results & methodology: Mixed micellar mobile phases prepared with both cationic (sodium dodecyl sulphate) and nonionic surfactant (Brij-35) modulate the retention of high to moderately polar basic drugs to practical times, eliminating the need of organic solvent. While the mobile phase is continuously recycled through the system, the stationary phase performance is maintained after repetitive injection of the samples. Discussion & conclusion: Through an exte…
Determination of benzomercaptans in environmental complex samples by combining zeolitic imidazolate framework-8-based solid-phase extraction and high…
2020
[EN] In this work, the synthesis of zeolitic imidazolate framework-8 (ZIF-8) crystals and their subsequent application as effective sorbents for extraction and preconcentration of several benzomercaptans from environmental complex samples is described. These materials were prepared by solvothermal approach varying the concentration of n-butylamine modulator to modify the surface of the metal-organic framework. The resulting materials were characterized by scanning and transmission electron microscopy, powder X-ray diffraction and Fourier transform infrared spectroscopy. The ZIF-8 material that gave the best features was selected as extractive phase and the influence of various parameters (s…
Establishing soil loss tolerance: an overview
2016
Soil loss tolerance is a criterion for establishing if a soil is potentially subjected to erosion risk, productivity loss and if a river presents downstream over-sedimentation or other off-site effects are present at basin scale. At first this paper reviews the concept of tolerable soil loss and summarises the available definitions and the knowledge on the recommended values and evaluating criteria. Then a threshold soil loss value, at the annual temporal scale, established for limiting riling was used for defining the classical soil loss tolerance. Finally, some research needs on tolerable soil loss are listed.
Determination of organophosphate flame retardants in soil and fish using ultrasound-assisted extraction, solid-phase clean-up, and liquid chromatogra…
2017
A solid–liquid extraction method in combination with high‐performance liquid chromatography and tandem mass spectrometry was developed and optimized for extraction and analysis of organophosphorus flame retardants in soil and fish. Methanol was chosen as the optimum extraction solvent, not only in terms of extraction efficiency, but also for its broader analyte coverage. The subsequent clean‐up by solid‐phase extraction is required to eliminate matrix coextractives and reduce matrix effects. Recoveries of the optimized method were 50–121% for soil and 47–123% for biota, both with high precision (RSDs <12% in soil and <23% in biota). The method limits of detection ranged from 0.06 to 0.20 ng…
Numerical study of blow-up and stability of line solitons for the Novikov-Veselov equation
2017
International audience; We study numerically the evolution of perturbed Korteweg-de Vries solitons and of well localized initial data by the Novikov-Veselov (NV) equation at different levels of the 'energy' parameter E. We show that as |E| -> infinity, NV behaves, as expected, similarly to its formal limit, the Kadomtsev-Petviashvili equation. However at intermediate regimes, i.e. when |E| is not very large, more varied scenarios are possible, in particular, blow-ups are observed. The mechanism of the blow-up is studied.
Zero viscosity limit of the Oseen equations in a channel
2001
Oseen equations in the channel are considered. We give an explicit solution formula in terms of the inverse heat operators and of projection operators. This solution formula is used for the analysis of the behavior of the Oseen equations in the zero viscosity limit. We prove that the solution of Oseen equations converges in W1,2 to the solution of the linearized Euler equations outside the boundary layer and to the solution of the linearized Prandtl equations inside the boundary layer. © 2001 Society for Industrial and Applied Mathematics.
Determination of lidocaine in urine at low ppm levels using dispersive microextraction and attenuated total reflectance–Fourier transform infrared me…
2015
Abstract IR spectra provide valuable information about biological systems and can be obtained with compactable and affordable instruments, but the lack of sensitivity of this technique hampers its use in the determination of drugs in clinical fluids. Taking lidocaine as a target molecule, in this paper we introduced a methodology for determining drugs in urine samples using infrared spectroscopy. The lack of sensitivity of the IR was compensated with the combination of an effective and straightforward dispersive liquid–liquid microextraction and the measurement of the dry film of the organic extracts through attenuated total reflectance (ATR). The method developed improves the sensitivity b…
Dispersive liquid–liquid microextraction followed by gas chromatography–mass spectrometry for the determination of nitro musks in surface water and w…
2011
A new, simple, fast and high sensitive analytical method based on dispersive liquid-liquid microextraction (DLLME) followed by gas chromatography-mass spectrometry (GC-MS) for the simultaneous determination of nitro musks in surface water and wastewater samples is presented. Different parameters, such as the nature and volume of both the extraction and disperser solvents and the ionic strength and pH of the aqueous donor phase, were optimized. Under the selected conditions (injection of a mixture of 1 mL of acetone as disperser solvent and 50 μL of chloroform as extraction solvent, no salt addition and no pH adjustment) the figures of merit of the proposed DLLME-GC-MS method were evaluated.…
Enhancing extraction performance of organophosphorus flame retardants in water samples using titanium hierarchical porous silica materials as sorbent…
2021
Abstract A sorbent for the extraction of organophosphorus flame retardants has been proposed, based on UVM-7 (University of Valencia Materials) mesoporous silica doped with titanium. Designed cartridges have been applied to the extraction and preconcentration of flame retardants in water samples, followed by gas chromatography coupled to a mass spectrometry detector. Firstly, UVM-7 materials with different contents of titanium were synthesized and characterized by several techniques, thus confirming the proper mesoporous architecture. The potential of these materials was assessed in comparison with their morphological properties, resulting Ti50-UVM-7 the best solid phase. Several extraction…