Search results for "Precipitation"

Study of nucleation and growth processes of ettringite in diluted conditions

2020

Abstract Ettringite is a key compound of cementitious materials, formed during hydration that influences the rheological behavior of the cement paste. Despite its importance, ettringite formation has been poorly studied. In this work, nucleation and growth processes of ettringite were separately investigated. Ettringite nucleation was described using the Classical Nucleation Theory and an interfacial crystal-solution energy was determined. After the initial primary homogeneous nucleation, when the surface of already formed crystals was still low, the precipitation rate was shown to depend almost exclusively on the solution supersaturation. When the surface of crystals in suspension was gett…

Incorporation of trace metals Cu, Zn, and Cd into gypsum: Implication on their mobility and fate in natural and anthropogenic environments

2020

Abstract The coexistence of calcium (Ca2+), sulfate (SO42−) with trace metal cations (M(II)) can possibly lead to M(II)-gypsum coprecipitation and solid solution formation. However, gypsum's role in the fixation of M(II) is still largely unknown. This study investigated the precipitation of Ca2+ and SO42− in the presence of M(II) (i.e., Cu2+, Zn2+, or Cd2+) and the incorporation of the metal cations into the gypsum structure at different environmental conditions. Trace metals in two natural gypsum samples (Yunnan and Neimeng, China) and one hydrometallurgical byproduct gypsum sample from a Cu refinery were also assessed. X-ray diffraction, scanning electron microscopy-energy dispersive X-ra…

2013

Abstract. As part of the CLACE-6 campaign we performed size-resolved CCN measurements for a~supersaturation range of S = 0.079 % to 0.66% at the high-alpine research station Jungfraujoch, Switzerland, in March~2007. The derived effective hygroscopicity parameter κ describing the influence of particle composition on CCN activity was on average 0.23–0.30 for Aitken (50–100 nm) and 0.32–0.43 for accumulation mode particles (100–200 nm). The campaign average value of κ = 0.3 is similar to the average value of κ for other continental locations. When air masses came from southeasterly directions crossing the Po Valley in Italy, particles were much more hygroscopic (κ ≈ 0.42) due to…

Electronic structure and thermodynamic stability of double-layeredSrTiO3(001)surfaces:Ab initiosimulations

2007

Using the B3PW hybrid exchange-correlation functional within density-functional theory and employing Gaussian-type basis sets, we calculated the atomic and electronic structures and thermodynamic stability of three double-layered (DL) SrTiO3(001) surfaces: (i) SrO-terminated, (ii) TiO2-terminated, and (iii) (2×1) reconstruction of TiO2-terminated SrTiO3(001) recently suggested by Erdman et al. [Nature (London) 419, 55 (2002)]. A thermodynamic stability diagram obtained from first-principles calculations shows that regular TiO2- and SrO-terminated surfaces are the most stable. The stability regions of (2×1) DL TiO2- and DL SrO-terminated surfaces lie beyond the precipitation lines of SrO and…

ATTEMPTS TO ISOLATE C'3 ACTIVITY FROM PIG SERUM.

1965

Gli autori descrivono un metodo per l'isolamento del terzo componente del complemento dal siero di maiale, basato sulla possibilita di provocare, per aggiunta di lisozima, passaggio in soluzione del C′3 precipitato insieme ad altre proteine in seguito all'aggiunta di opportune quantita di « Liquoid » al siero.

Variabilité basse-fréquence des précipitations au Sahel et des températures de surface de l'océan Atlantique au cours du dernier siècle.

2012

6 pages; International audience; Cette étude examine les téléconnexions entre les températures de surface de la mer (TSM) de l'océan Atlantique et la distribution zonale des précipitations au Sahel au cours du dernier siècle. Depuis la fin des années 60, les précipitations d'Afrique de l'Ouest présentent une tendance négative sur l'ensemble de la bande sahélienne. Pourtant, trois types de variabilité basse-fréquence des précipitations sahélienne sont observés : la côte atlantique (Dakar), le Sahel central (Nioro du Sahel et Mopti) et le Sahel oriental (Niamey, Maradi, Maïné-Soroa). Au cours du XXème siècle, les précipitations sont rarement reliées simultanément avec les TSM de l'Atlantique …

A 5500-year oxygen isotope record of high arctic environmental change from southern Spitsbergen

2017

The oxygen isotope composition of chironomid head capsules in a sediment core spanning the past 5500 years from Lake Svartvatnet in southern Spitsbergen was used to reconstruct the oxygen isotope composition of lake water (δ18Olw) and local precipitation. The δ18Olw values display shifts from the baseline variability consistent with the timing of recognized historical climatic episodes, such as the Roman Warm Period, the Dark Ages Cold Period and the ‘Little Ice Age’. The highest values of the record, ca. 3‰ above modern δ18Olw values, occur at ca. 1900–1800 cal. yr BP. Three negative excursions increasing in intensity toward the present, at 3400–3200, 1250–1100, and 350–50 cal. yr BP, are…

Metals Recovery from Waste Pickling Solutions by Reactive Precipitation

2021

Pickling is one of the most important steps in steel manufacturing industry. During the process, an acid reacts with the surface oxides causing metal ions accumulation in the pickling solution. Disposal of the waste acid represents a critical issue for the hot-dip galvanizing industry in terms of environmental damage and high costs. Recovering of the main products by using an integrated process, with the perspective of a circular approach, could minimize the wastewater production, leading to reinvigorate this industrial sector economy. In this context, recovery of the metal ions mainly present in the pickling solution, such as Fe and Zn, becomes a critical issue. In this work, the reactive …

Epigenetic Regulation of Early- and Late-Response Genes in Acute Pancreatitis

2015

Abstract Chromatin remodeling seems to regulate the patterns of proinflammatory genes. Our aim was to provide new insights into the epigenetic mechanisms that control transcriptional activation of early- and late-response genes in initiation and development of severe acute pancreatitis as a model of acute inflammation. Chromatin changes were studied by chromatin immunoprecipitation analysis, nucleosome positioning, and determination of histone modifications in promoters of proinflammatory genes in vivo in the course of taurocholate-induced necrotizing pancreatitis in rats and in vitro in rat pancreatic AR42J acinar cells stimulated with taurocholate or TNF-α. Here we show that the upregulat…

Grain Boundary Wetting Phenomena in High Entropy Alloys Containing Nitrides, Carbides, Borides, Silicides, and Hydrogen: A Review

2021

This review was written during the preparation of M-era.Net full proposal “Grain boundaries in multicomponent alloys without principal component” (A.Ko., A.Ku., G.L., and E.R., application No 9345). We also acknowledge the support of the KIT-Publication Fund of the Karlsruhe Institute of Technology. The Institute of Solid State Physics, University of Latvia, as a center of excellence, has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement no. 739508, project CAMART2.