Search results for "Ratio"
showing 10 items of 33258 documents
Line parameters and shapes of high clusters: R-branch of the nu3 band of CH4 in He mixtures
2002
International audience; The IR absorption spectra of CH4 in pure gas and in mixture with helium were studied in the region of nu3 band at higher J line clusters R(17)-R(22). The frequencies and intensities of rotation-vibration lines were estimated from the experimental spectra at Doppler shape conditions. The line frequencies and intensities were calculated and used for the attribution of overlapped lines in clusters. The calculated line intensities are close to the experimental values. The calculated frequency structure of the higher J manifolds are somewhat wider than the observed one. The shapes of helium-broadened line clusters were compared with those calculated accounting for line mi…
Long-term annual burning of grassland increases CO2 emissions from soils.
2016
7 pages; International audience; Grasslands have potential to mitigate against climate change because of their large capacity to store soil organic carbon (SOC). However, the long-term impact of grassland management such as burning, which is still common in many areas of the world, on SOC is still a matter of debate. The objective of this study was to quantify the long-term effects of annual burning on CO2 output from soils and SOC stocks. The study was performed on a 62 years old field trial comparing annual burning (AB) to no burning associated with tree encroachment (NB), and to annual mowing (AM) with all treatments laid out in randomized block design with three replicates per treatment…
Simulating future trends in hydrological regime of a large Sudano-Sahelian catchment under climate change
2012
Summary This paper assesses the future variability of water resources in the short, medium and long terms over a large Sudano-Sahelian catchment in West Africa. Flow simulations were performed with a daily conceptual model. A period of nearly 50 years (1952–2000) was chosen to capture long-term hydro-climatic variability. Calibration and validation were performed on the basis of a multi-objective function that aggregates a variety of goodness-of-fit indices. The climate models HadCM3 and MPI-M under SRES-A2 were used to provide future climate scenarios over the catchment. Outputs from these models were used to generate daily rainfall and temperature series for the 21st century according to:…
Hydrostratigraphic characterization of glaciofluvial deposits underlying an infiltration basin using ground penetrating radar.
2008
14 pages; International audience; An understanding of the heterogeneity of quaternary gravelly deposits is required to predict flow and contaminant transfer through these formations. In such deposits, preferential flow paths can lead to contamination at depths greater than predicted under the assumption of a homogeneous medium. The difficulties in characterizing their complex structure with conventional methods represent an obstacle for this prediction. In this study, we developed an approach relying on the use of ground penetrating radar (GPR) for the detection of sedimentary depositional units. A genetic interpretation of the radar stratigraphy allowed us to construct a distribution model…
Implementation of a comprehensive ice crystal formation parameterization for cirrus and mixed-phase clouds in the EMAC model (based on MESSy 2.53)
2018
A comprehensive ice nucleation parameterization has been implemented in the global chemistry-climate model EMAC to improve the representation of ice crystal number concentrations (ICNCs). The parameterization of Barahona and Nenes (2009, hereafter BN09) allows for the treatment of ice nucleation taking into account the competition for water vapour between homogeneous and heterogeneous nucleation in cirrus clouds. Furthermore, the influence of chemically heterogeneous, polydisperse aerosols is considered by applying one of the multiple ice nucleating particle parameterizations which are included in BN09 to compute the heterogeneously formed ice crystals. BN09 has been modified in order to co…
High-resolution spectroscopy and analysis of the V2 + V3 combination band of SF6 in a supersonic jet expansion
2013
International audience; Sulphur hexafluoride is a very strong greenhouse gas whose concentration is increasing in the atmosphere. It is detected through infrared absorption spectroscopy in the strong ν3 fundamental region. Due to the existence of low-lying vibrational states of this molecule, however, many hot bands arise at room temperature and those are still not known. We present here a contribution to the elucidation of this hot band structure, by analysing the ν2 + ν3 combination band. We use a supersonic jet expansion high-resolution spectrum at a rotational temperature of ca. 25 K that was recorded thanks to the Jet-AILES setup at the Source Optimisée de Lumière d'Energie Intermédiai…
Identification of processes that control the stable isotope composition of rainwater in the humid tropical West-Central Africa.
2020
12 pages; International audience; This study interprets 11 years (2006 to 2016) and 6 months (March to August in 2017) of respectively monthly and daily isotopic (δD and δ18O) monitoring of rain at Douala (Cameroon), a humid tropical station in Western Africa. The main scope is to analyze the climate controls on precipitation isotopes at different timescales. Firstly, we examine the annual cycles of δ18O. Over the 11 years of survey, the annual cycle exhibits a W shape that is quite reproducible from year to year, with two minima in spring and autumn periods. Based on back trajectory calculations and remote sensing observations of water vapor isotopic composition, we show that the observed …
Simulating speleothem growth in the laboratory: Determination of the stable isotope fractionation (δ13C and δ18O) between H2O, DIC and CaCO3
2019
Abstract Here we present novel cave-analogue experiments directly investigating stable carbon and oxygen isotope fractionation between the major involved species of the carbonate system (HCO3−, CO2, CaCO3 and H2O). In these experiments, which were performed under controlled conditions inside a climate box, a thin film of solution flew down an inclined marble or glass plate. After different distances of flow and, thus, residence times on the plate, pH, electrical conductivity, supersaturation with respect to calcite, precipitation rate as well as the δ18O and δ13C values of the dissolved inorganic carbon (DIC) and the precipitated CaCO3 were obtained. Progressive precipitation of CaCO3 along…
Oxygen isotope compositions of phosphate from arvicoline teeth and Quaternary climatic changes, Gigny, French Jura
2004
Oxygen isotope compositions of biogenic phosphates from mammals are widely used as proxies of the isotopic compositions of meteoric waters that are roughly linearly related to the air temperature at high- and mid-latitudes. An oxygen isotope fractionation equation was determined by using present-day European arvicoline (rodents) tooth phosphate: δ18Op = 20.98(±0.59) + 0.572(±0.065) δ18Ow. This fractionation equation was applied to the Late Pleistocene karstic sequence of Gigny, French Jura. Comparison between the oxygen isotope compositions of arvicoline tooth phosphate and Greenland ice core records suggests to reconsider the previously established hypothetical chronology of the sequence. …
Carbon and oxygen stable isotope compositions of late Pleistocene mammal teeth from dolines of Ajoie (Northwestern Switzerland)
2014
AbstractFossils of megaherbivores from eight late Pleistocene 14C- and OSL-dated doline infillings of Ajoie (NW Switzerland) were discovered along the Transjurane highway in the Swiss Jura. Carbon and oxygen analyses of enamel were performed on forty-six teeth of large mammals (Equus germanicus, Mammuthus primigenius, Coelodonta antiquitatis, and Bison priscus), coming from one doline in Boncourt (~ 80 ka, marine oxygen isotope stage MIS5a) and seven in Courtedoux (51–27 ka, late MIS3), in order to reconstruct the paleoclimatic and paleoenvironmental conditions of the region. Similar enamel δ13C values for both periods, ranging from − 14.5 to − 9.2‰, indicate that the megaherbivores lived i…