Search results for "SUSCEPTIBILITY"
showing 10 items of 912 documents
Exporting a Google Earth™ aided earthflow susceptibility model: a test in central Sicily
2012
Abstract In the framework of a regional landslide susceptibility study in southern Sicily, a test has been carried out in the Tumarrano river basin (about 80 km2) aimed at characterizing its landslide susceptibility conditions by exporting a ‘‘source model’’, defined and trained inside a limited (about 20 km2) representative sector (the ‘‘source area’’). Also, the possibility of exploiting Google Earth TM software and photo-images databank to produce the landslide archives has been checked. The susceptibility model was defined, according to a multivariate geostatistic approach based on the conditional analysis, using unique condition units (UCUs), which were obtained by combining four selec…
Modeling landslide susceptibility by using GIS-analysis and multivariate adaptive regression splines
2015
Landslide susceptibility may be evaluated by defining statistical relationships between the spatial distribution of past slope failures and the variability of landslide triggering factors. In this research, susceptibility to landsliding was assessed by employing multivariate adaptive regression splines (MARS), a statistical model that has been rarely used to this aim. The experiment was carried out in an area of central Sicily (Italy), which is severely affected by shallow landslides mainly occurring during the wet autumn- winter semester. Bedrock lithology and a set of primary and secondary topographic attributes were exploited as proxies of main landslide driving factors. The robustness o…
Stochastic assessment of landslide susceptibility by using five different instability datasets: a case study from the southern sector of the “Via al …
In this study, the ability of stochastic models to predict landslide susceptibility in the southern sector of the “Via al Llano” highway (Colombia) was assessed. To this aim, an inventory of landslides occurred in the area was prepared by analyzing images available in Google Earth. Multivariate Adaptive Regression Splines (MARS) was employed to model the spatial distribution of the following five data sets of unstable cells selected within each landslide: i) the highest cell (data set MAX), ii) the highest 10% of cells (data set SUP), iii) the lowest cell (data set MIN), iv) the lowest 10% of cells (data set INF), and v) the entire landslide area (data set BODY). The goal of our experiment …
Predicting depositional areas of landslide susceptibility comparing four datasets extracted from landslide area: a case of study after rainfall-induc…
Hurricane Ida and low-pressure system 96E crossed Central American countries in 2009. However, in El Salvador, the torrential rainfalls caused many flooding and landslides. As a result, over 200 causalities and the destruction of several villages, and bridges occurred along the mountain slopes. The remote analysis allowed us to prepare an inventory of landslides that occurred after the Hurricane in a basin located in the northern part of Ilopango Caldera. Five groups of data sets were created using selected pixels of each landslide area in order to evaluate the capacity to predict the lowest and the entire landslide area. Multivariate Adaptive Regression Splines (MARS) were employed to mode…
Metal–Organic Frameworks as Playgrounds for Reticulate Single-Molecule Magnets
2019
Achieving an accurate control on the final structure of Metal-Organic Frameworks (MOFs) is mandatory to obtain target physical properties. Here we describe how the combination of a metalloligand design strategy and a post-synthetic method is a versatile and powerful approach to success on this extremely difficult task. In a first stage, a novel oxamato-based tetranuclear cobalt(III) complex with a tetrahedron-shape geometry is used, for the first time, as metalloligand toward cal-cium(II) cations to lead a diamagnetic Ca(II)-Co(III) three-dimensional (3D) MOF (1). In a second stage, in a single-crystal to single-crystal manner the calcium(II) ions are replaced by terbium (III), dysprosium(I…
Magnetic properties of AgLnSe2 compounds (Ln=Ho, Er, Tm and Yb)
2001
Abstract The heavy lanthanide selenides AgLnSe2 (Ln=Ho–Yb) crystallize in the orthorhombic AgErSe2 type structure (P212121). The lanthanide ions are placed in the centres of slightly distorted octahedra, whereas each of the silver ions is surrounded by four selenide ions forming a strongly distorted tetrahedron. The high field magnetization (up to 14 T) and the magnetic susceptibility were measured on the polycrystalline samples. The crystal field parameters were estimated from the field dependences of the magnetizations, assuming a rhombic distortion of LnSe6 octahedra. The magnetic susceptibilities were also calculated using the same set of the crystal field parameters. None of the compou…
Design of 3d–4f molecular squares through the [Fe{(HB(pz)3)}(CN)3]− metalloligand
2018
A new series of {FeIII2LnIII2} heterobimetallic squares of general formula [FeIII{HB(pz)3}(CN)(μ-CN)2Ln(pyim)x(NO3)2(H2O)y]2·zH2O [Ln = La (1), Gd (2), Tb (3) and Dy (4); {HB(pz)3}− = hydrotris(pyrazolyl)borate and pyim = 2-(1H-imidazol-2-yl)pyridine; x = 2, y = 0 (1), x = y = 1 (2–4) and z = 10 (1), 6 (2), 2.76 (3), 4 (4)] were synthesized by reacting the low-spin [FeIII{HB(pz)3}(CN)3]− complex anion with the preformed [LnIII(pyim)x(NO3)2(H2O)y]+ complex cation [formed in situ by mixing the lanthanide(III) salt and the pyim ligand]. Single-crystal X-ray diffraction shows that 1–4 crystallize in the P triclinic space group, 2–4 being isomorphous. In all cases, the structure comprises neutra…
Syntheses, characterisation, magnetism and photoluminescence of a homodinuclear Ln(III)-Schiff base family.
2009
A novel family of homodinuclear complexes of the general formula [Ln(2)L(2)(X)(2)] (where Ln = Nd(3+), Pr(3+), Sm(3+) and Tb(3+) for 1, 2, 3 and 4, respectively and X, the coordinated NO(3)(-) or Cl(-) anion) has been synthesised from the corresponding lanthanide(III) salts with the pentadentate dianionic Schiff base ligand, H(2)L [N(1),N(3)-bis(salicylideneimino)diethylenetriamine], that exhibits a N(3)O(2) donor set. Single crystal X-ray diffraction studies evidenced the isostructurality of this family of centrosymmetric neutral dinuclear entities where the Ln(III) metal centres are coupled together by two phenolato oxygen atoms belonging to two units of ligand (H(2)L). Interestingly, the…
Thermal expansion and magnetic properties of benzoquinone-bridged dinuclear rare-earth complexes.
2017
The synthesis and structural characterization of two benzoquinone-bridged dinuclear rare-earth complexes [BQ(MCl2·THF3)2] (BQ = 2,5-bisoxide-1,4-benzoquinone; M = Y (1), Dy (2)) are described. Of these reported metal complexes, the dysprosium analogue 2 is the first discrete bridged dinuclear lanthanide complex in which both metal centres reside in pentagonal bipyramidal environments. Interestingly, both complexes undergo significant thermal expansion upon heating from 120 K to 293 K as illustrated by single-crystal X-ray and powder diffraction experiments. AC magnetic susceptibility measurements reveal that 2 does not show the slow relation of magnetization in zero dc field. The absent of …