Search results for "Step"

Primary and secondary distributions after a small-amplitude potential step at disk electrode coated with conducting film

2011

Abstract The set of equations and boundary conditions for the “primary potential/current distribution” after a small-amplitude potential step has been analyzed for a film-coated disk electrode in contact with an electrolyte. The solution of these equations provides the overall short-time resistance of this system, Rtot, which is determined by the short-time resistance of the electrolyte solution in contact with the bare disk electrode, Rs, and the short-time film resistance to the current passage in the normal direction, R f = L f / κ f π r o 2 (ro, disk radius; Lf, film thickness; κf, its specific conductivity). The deviation of Rtot from the sum of these resistances, Rs + Rf, originates f…

Acid versus base peptization of mesoporous nanocrystalline TiO2 films: functional studies in dye sensitized solar cells

2005

We report an analysis of the influence of acid/base conditions employed in the synthesis of TiO2 nanoparticles upon the performance of dye sensitised photoelectrochemical solar cells fabricated from these particles. The functional properties of the TiO2 nanoparticles in these devices are investigated by potential step chronoamperometry, transient laser spectroscopy, and photovoltaic device characterisation. We find that base peptization conditions employed in the sol–gel fabrication of the TiO2 nanoparticles result in a reduction in film electron density under negative applied bias, correlated with slower interfacial recombination losses and a higher device open circuit voltage.

ON THE ONE-DIMENSIONAL SCHRÖDINGER EQUATION WITH A QUASI-PERIODIC POTENTIAL

1980

Some efficient algorithms for the solution of a single nonlinear equation

1981

High order methods for the numerical solution of nonlinear scalar equations are proposed which are more efficient than known procedures, and a unified approach to various methods suggested in literature is given.

Stepping molecular motor amid Lévy white noise

2015

We consider a model of a stepping molecular motor consisting of two connected heads. Directional motion of the stepper takes place along a one-dimensional track. Each head is subject to a periodic potential without spatial reflection symmetry. When the potential for one head is switched on, it is switched off for the other head. Additionally, the system is subject to the influence of symmetric, white Lévy noise that mimics the action of external random forcing. The stepper exhibits motion with a preferred direction which is examined by analyzing the median of the displacement of a midpoint between the positions of the two heads. We study the modified dynamics of the stepper by numerical sim…

Simulation of BSDEs with jumps by Wiener Chaos Expansion

2016

International audience; We present an algorithm to solve BSDEs with jumps based on Wiener Chaos Expansion and Picard's iterations. This paper extends the results given in Briand-Labart (2014) to the case of BSDEs with jumps. We get a forward scheme where the conditional expectations are easily computed thanks to chaos decomposition formulas. Concerning the error, we derive explicit bounds with respect to the number of chaos, the discretization time step and the number of Monte Carlo simulations. We also present numerical experiments. We obtain very encouraging results in terms of speed and accuracy.

J. Lautenbacha kritika par Raiņa lugu "Pusidealists"

1905

Manuskripts rokrakstā, datējums nav precīzi zināms.

Stephanotis floribunda infetta da TSWV in Liguria.

2010

Il genere Stephanotis (famiglia delle Asclepiadaceae ) comprende cinque specie di piante rampicanti, sempreverdi, originarie del Madagascar. La più nota ed apprezzata è la specie S. floribunda Brongn., i cui fiori tubulosi, bianchi, leggermente carnosi, riuniti in ombrelle ascellari, sbocciano da maggio ad ottobre emanando un intenso e gradevole profumo. Questi fiori ricordano molto quelli del gelsomino, pur essendo più grandi e cerosi, ma questa somiglianza è bastata ad attribuire alla pianta l’appellativo “gelsomino del Madagascar”. S. floribunda costituisce una coltura di recente introduzione nella Piana di Albenga (Savona): la sua coltivazione è per ora limitata a poche aziende che prod…

Deconstructing Stereotypes Through Reading Children’s Literature as Intergenerational Play: The Case of the Stepmother

2021

One of the key roles within stepfamilies, the role of stepmother has been and still is stigmatized with an aura of wickedness, produced by folk and fairy tales as well as by the media. As a review of theoretical frameworks of children’s literature indicates, there is a shortage of methodological proposals for handling such controversial topics in literary education. Thus, the objective of this chapter is to present and test a methodology for analyzing the capacity of children’s literature to shape social understanding of such intergenerational topics. This study was based on the exploration of the picture book by Gonzalez and Alberdi entitled La novia de papa tambien me quiere (My Dad’s Gir…

Increased dynamic effects in a catalytically compromised variant of Escherichia coli dihydrofolate reductase

2013

Isotopic substitution (15N, 13C, 2H) of a catalytically compromised variant of Escherichia coli dihydrofolate reductase, EcDHFR-N23PP/S148A, has been used to investigate the effect of these mutations on catalysis. The reduction of the rate constant of the chemical step in the EcDHFR-N23PP/S148A catalyzed reaction is essentially a consequence of an increase of the quasi-classical free energy barrier and to a minor extent of an increased number of recrossing trajectories on the transition state dividing surface. Since the variant enzyme is less well set up to catalyze the reaction, a higher degree of active site reorganization is needed to reach the TS. Although millisecond active site motion…