Search results for "Tram"

Cross-Metathesis/Intramolecular (Hetero-)Michael Addition: A Convenient Sequence for the Generation of Carbo- and Heterocycles

2017

The high stability and functional group compatibility of ruthenium carbene complexes confer them a great ability to catalyze domino processes. For this reason, the combination of metathesis reactions with additional transformations in a domino fashion has been exploited extensively, with the result of expanding the utility of ruthenium carbene complexes beyond that of just olefin metathesis. Among those domino processes, it is worth mentioning the sequence of cross-metathesis/intramolecular Michael addition, which allows for the generation of a wide variety of carbo- and heterocycles in a very simple manner, taking advantage of the benefits of domino reactions. Carbon-, oxygen- and nitrogen…

Molybdenum Pentachloride Mediated Synthesis of Spirocyclic Compounds by Intramolecular Oxidative Coupling

2015

The oxidative treatment of (m)ethyl 2-aryl cinnamates equipped with methoxy groups in position 4 of the phenyl moiety promote the formation of cyclohexadienone substructures. This dealkylative oxidative C–C coupling gives access to spirocyclic compounds and avoids the construction of the corresponding phenanthrenes. Furthermore, the transformation can be expanded to other spirocyclic systems.

Bowl-shape electron donors with absorptions in the visible range of the solar spectrum and their supramolecular assemblies with C 60

2012

We describe the synthesis, electronic, optical and photophysical properties of a family of three electron-donor bowl-shaped organic molecules that absorb light in the whole range of the visible spectrum (up to 800 nm in one case), and associate C60 in solution with binding constants in the range of 104–102 M−1 as measured from both UV-vis and fluorescence titrations in several solvents. These molecules are π-extended derivatives of tetrathiafulvalene, based on a truxene core to which two or three units of dithiole are covalently attached. The inclusion of the bulky dithiole groups is responsible for their bowl-shape geometry, which allows them to associate with C60, and their electron-donor…

A Ferrocenyl Amino Substituted Stannylene as an Intramolecular Fe→Sn Lewis Adduct

2018

Subduction or sagduction? Ambiguity in constraining the origin of ultramafic–mafic bodies in the Archean crust of NW Scotland

2016

Abstract The Lewisian Complex of NW Scotland is a fragment of the North Atlantic Craton. It comprises mostly Archean tonalite–trondhjemite–granodiorite (TTG) orthogneisses that were variably metamorphosed and reworked in the late Neoarchean to Paleoproterozoic. Within the granulite facies central region of the mainland Lewisian Complex, discontinuous belts composed of ultramafic–mafic rocks and structurally overlying garnet–biotite gneiss (brown gneiss) are spatially associated with steeply-inclined amphibolite facies shear zones that have been interpreted as terrane boundaries. Interpretation of the primary chemical composition of these rocks is complicated by partial melting and melt loss…

Sulfide enrichment at an oceanic crust-mantle transition zone: Kane Megamullion (23°N, MAR)

2018

Abstract The Kane Megamullion oceanic core complex located along the Mid-Atlantic Ridge (23°30′N, 45°20′W) exposes lower crust and upper mantle directly on the ocean floor. We studied chalcophile elements and sulfides in the ultramafic and mafic rocks of the crust-mantle transition and the mantle underneath. We determined mineralogical and elemental composition and the Cu isotope composition of the respective sulfides along with the mineralogical and elemental composition of the respective serpentines. The rocks of the crust-mantle transition zone (i.e., plagioclase harzburgite, peridotite-gabbro contacts, and dunite) overlaid by troctolites are by one order of magnitude enriched in several…

Carbon isotope composition of CO2-rich inclusions in cumulate-forming mantle minerals from Stromboli volcano (Italy)

2017

We report on measurements of concentration and carbon isotope composition (δ13CCO2) of CO2 trapped in fluid inclusions of olivine and clinopyroxene crystals separated from San Bartolo ultramafic cumulate Xenoliths (SBX) formed at mantle depth (i.e., beneath a shallow Moho supposed to be at 14.8 km). These cumulates, erupted about 2 ka ago at Stromboli volcano (Italy), have been already investigated by Martelli et al. (2014) mainly for Sr-Nd isotopes and for their noble gases geochemistry. The concentration of CO2 varies of one order of magnitude from 3.8·10− 8 mol g− 1 to 4.8·10− 7 mol g− 1, with δ13C values between − 2.8‰ and − 1.5‰ vs V-PDB. These values overlap the range of measurements …

Geochemistry of ultramafic and mafic rocks from the northern Central Asian Orogenic Belt (Tuva, Central Asia) - constraints on lower and middle arc c…

2021

Abstract The Agardagh Tes-Chem complex (ATCC) in Tuva, Central Asia (50.5°N, 95°E) exposes a rare mafic to ultramafic crust-mantle fragment that developed within a late Neoproterozoic (~570 Ma) intra-oceanic island arc system that was accreted to the Tuva-Mongolian microcontinent during the formation of the Central Asian Orogenic Belt. Residual mantle rocks (harzburgites and dunites) are highly refractory with high Cr# (0.59–0.83) and intermediate Mg# (0.46–0.52) in spinel and experienced high degrees of total melt extraction (up to 25%). In ultramafic cumulate rocks (wehrlites and pyroxenites), Cr# and Mg# in spinel are distinctly lower (0.22–0.45 and 0.34–0.37), and rare earth element (RE…

Phlogopite-pargasite coexistence in an oxygen reduced spinel-peridotite ambient

2021

AbstractThe occurrence of phlogopite and amphibole in mantle ultramafic rocks is widely accepted as the modal effect of metasomatism in the upper mantle. However, their simultaneous formation during metasomatic events and the related sub-solidus equilibrium with the peridotite has not been extensively studied. In this work, we discuss the geochemical conditions at which the pargasite-phlogopite assemblage becomes stable, through the investigation of two mantle xenoliths from Mount Leura (Victoria State, Australia) that bear phlogopite and the phlogopite + amphibole (pargasite) pair disseminated in a harzburgite matrix. Combining a mineralogical study and thermodynamic modelling, we predict …

An experimental study of the role of partial melts of sediments versus mantle melts in the sources of potassic magmatism

2019

Abstract Potassium-rich lavas with K/Na of >2 are common in orogenic and anorogenic intraplate magmatic provinces. However, in the primitive mantle, the concentration of Na exceeds that of K by 10 times. The source of K-rich lavas thus needs to be either K-enriched or Na-depleted to account for high K/Na ratios. The geochemical and isotopic compositions of high 87Sr/86Sr post-collisional lavas show that their mantle source contains a recycled crustal component. These highly K-enriched lavas with crustal like trace element patterns are termed “orogenic lamproites” and are compositionally distinct from K-rich “anorogenic lamproites” that show lower 87Sr/86Sr and a trace element pattern that r…