Search results for "UBO"

[Ag67(SPhMe2)32(PPh3)8]3+: Synthesis, Total Structure, and Optical Properties of a Large Box-Shaped Silver Nanocluster

2016

Engineering the surface ligands of metal nanoparticles is critical in designing unique arrangements of metal atoms. Here, we report the synthesis and total structure determination of a large box-shaped Ag67 nanocluster (NC) protected by a mixed shell of thiolate (2,4-dimethylbenzenethiolate, SPhMe2) and phosphine (triphenylphosphine, PPh3) ligands. Single crystal X-ray diffraction (SCXRD) and electrospray ionization mass spectrometry (ESI-MS) revealed the cluster formula to be [Ag67(SPhMe2)32(PPh3)8]3+. The crystal structure shows an Ag23 metal core covered by a layer of Ag44S32P8 arranged in the shape of a box. The Ag23 core was formed through an unprecedented centered cuboctahedron, i.e.,…

Synthesis of Cuboctahedral CeO2 Nanoclusters and Their Assembly into Cuboid Nanoparticles by Oriented Attachment

2017

Here, we describe a simple approach to control the oriented attachment process through selective ligand scavenging from the {100} facets of CeO2 nanoclusters. Aggregates of these nanoclusters smaller than 10 nm with controlled shapes and exposed facets were obtained. For the synthesis of the cuboctahedral CeO2 nanoclusters, we developed a solvent-controlled synthesis approach based on a non-hydrolytic sol–gel process and used an ester aminolysis reaction to control ligand scavenging from the {100} facets. First-principle calculations allowed us to understand and interpret, at the atomic level, the effects of shape control on the synthesis. Fine-tuning of the desired morphologies can be achi…

Perpetuating Anti-Muslim Discrimination through the Interpretation of Religious Equality in the European Court of Human Rights

2018

AbstractFaced with widespread prejudice and discrimination, European Muslims are increasingly resorting to the European Court of Human Rights as a last-ditch strategy to transform state policies toward minority faiths. While the Court has a mandate to protect religious freedom and equality, the conservative and sometimes biased way in which it has interpreted these concepts has enabled the persistence of stark asymmetries in the legal and social statuses of different religions. Using an analysis of relevant cases, this article seeks to highlight the judicial processes that currently sustain Muslim subordination and pinpoint specific reforms that could reverse the trend.

ChatOps paradigmas izmantošana darba vidē

2018

Līdz ar tehnoloģijas attīstību un ikdienā darbā izmantoto rīku skaita palielināšanos, ir nepieciešams veids, kā vieglāk kontrolēt izstrādes procesus, izsekot serveru un kompilāciju statusus un kā uzlabot komunikāciju starp izstrādes komandām. Galvenaie darba uzdevumi ir novērtēt ChatOps lietojamību, kā izstrādes procesu metodoloģiju, kā šī paradigma tiek īstenota darba vidē un kādi ir šīs paradigmas lietošanas ieguvumi un izaicinājumi. Kā arī svarīgi ir noskaidrot, kādi ChatOps risinājumi eksistē un kā tie atšķiras viens no otra. Bakalaura darbā ir izpētīts, kas ir ChatOps programmēšanas paradigma, kā šī paradgima radusies, kādi ir izaicinājumi, ar ko var sastapties, ieviešot ChatOps darba …

takotsubo cardiomiopathy after acute diarrhea

2010

Takotsubo cardiomyopaty is a recently described syndrome characterized by transient left ventricular dysfunction, mimicking an acute coronary syndrome and usually precipitated by a physical or emotional stress. We report the first case of Takotsubo cardiomyopathy after acute diarrhea in a man. It may be argued that severe diarrhea in predisposed individuals may cause an acute stress resulting in increased sympathetic activity leading to this syndrome. Probably the relationship between the adrenergic system and the heart is more complex than general thought and the stimuli which favor an autonomic imbalance and precipitate the syndrome are very disparate in clinical practice.

Paleoclimate and bubonic plague: a forewarning of future risk?

2010

Background Human cases of plague (Yersinia pestis) infection originate, ultimately, in the bacterium's wildlife host populations. The epidemiological dynamics of the wildlife reservoir therefore determine the abundance, distribution and evolution of the pathogen, which in turn shape the frequency, distribution and virulence of human cases. Earlier studies have shown clear evidence of climatic forcing on contemporary plague abundance in rodents and humans. Results We find that high-resolution palaeoclimatic indices correlate with plague prevalence and population density in a major plague host species, the great gerbil (Rhombomys opimus), over 1949-1995. Climate-driven models trained on these…

Il danno psichico da Disturbo Post-Traumatico da Stress (DPTS): aspetti clinici e testologici

2002

The red tooth hypothesis: A computational model of predator-prey relations, protean escape behavior and sexual reproduction

2009

This paper presents an extension of the Red Queen Hypothesis (hereafter, RQH) that we call the Red Tooth Hypothesis (RTH). This hypothesis suggests that predator-prey relations may play a role in the maintenance of sexual reproduction in many higher animals. RTH is based on an interaction between learning on the part of predators and evolution on the part of prey. We present a simple predator-prey computer simulation that illustrates the effects of this interaction. This simulation suggests that the optimal escape strategy from the prey's standpoint would be to have a small number of highly reflexive, largely innate (and, therefore, very fast) escape patterns, but that would also be unlearn…

Biogenic amine levels, reproduction and social dominance in the queenless ant Streblognathus peetersi

2006

Social harmony often relies on ritualized dominance interactions between society members, particularly in queenless ant societies, where colony members do not have developmentally predetermined castes but have to fight for their status in the reproductive and work hierarchy. In this behavioural plasticity, their social organisation resembles more that of vertebrates than that of the "classic" social insects. The present study investigates the neurochemistry of the queenless ant species, Streblognathus peetersi, to better understand the neural basis of the high behavioural plasticity observed in queenless ants. We report measurements of brain biogenic amines [octopamine, dopamine, serotonin]…

Effects of several degrees of chronic social defeat stress on emotional and spatial memory in CD1 mice

2015

In the present study, the effects of several degrees of CSDS (Chronic Social Defeat Stress) on emotional and spatial memory in mice were evaluated in separate experiments. Male CD1 mice were randomly assigned to four experimental groups (n=10-12) for each experiment: NS (non-stressed), S5, S10 and S20 (5, 10 and 20 sessions of CSDS, respectively). The S groups underwent the corresponding number of agonistic encounters (10min each) over a 20-day period. 24h after the last session of CSDS, mice performed the inhibitory avoidance (Experiment 1) or the Morris water maze test (Experiment 2). In both experiments, animals were also evaluated in the elevated plus maze for 5min to obtain complementa…