Search results for "bonding"
showing 10 items of 996 documents
Mechanical behaviour and failure modes of metal to composite adhesive joints for nautical applications
2010
In this paper, the influence of several parameters on the mechanical behaviour and failure modes of hybrid bonded joints aluminium/composite was investigated. Particularly, the effects of metallic surface condition, adhesive properties and thickness on single-lap joint resistance were analysed. To these aims, two adhesives were used and, for each adhesive, two different adhesive thicknesses (0.5 and 1.5 mm) have been investigated. Furthermore, two sets of joints for each adhesive kind and thickness were investigated: the former was obtained using aluminium blanks which were previously mechanically treated with sandpaper (P60) and the latter using aluminium treated with sandpaper and with pr…
Effect of Chemical Etching on Adhesively Bonded Aluminum AA6082
2007
The efforts of new automotive industry are mainly directed towards the substitution of aluminum for steel in the body structure because the aluminum structures are lighter than traditional steel ones and meet the requirements, in terms of both vehicle design and manufacture. However, this substitution is not so automatic, but it is important to study the material properties and the structure design, focusing the attention on the methods of joining. Welding, typical technique to joint steel parts, is particularly difficult when applied on aluminum ones and then, in many cases, the adhesive bonding is preferred. To optimise the joint performances it is necessary to pre-treat the metal surface…
A shear test for structural adhesives used in the consolidation of old timber
2001
A test method was developed specifically for structural adhesives used in thick joints. It is based on compressive shear loading of glued joints (GJ) and solid wood (SW) specimens, before and after a suitable accelerated ageing cycle. The evaluation of results is based on the ratios of wet strength to dry strength and on the comparison of GJ specimens to SW specimens which are prepared from the same batch of wood, in order to minimise the influence of the variability in wood characteristics. On a group of 10 epoxy-based adhesives, specifically marketed for the consolidation of old timber structures, the method has proved to be effective to differentiate the performances of each product. Amo…
Thermally Stimulated Ionic and Electronic Processes and Radiation-Induced Defect Annealing in LiBaF3 Crystals
2000
The electronic, ionic and ion-diffusion controlled thermally stimulated relaxation (TSR) processes in X-ray irradiated (at 80 K or 290 K) nominally pure LiBaF3 fluoroperovskite crystals have been investigated in the 90–550 K range by means of the ionic conductivity, ionic thermally stimulated depolarization current (TSDC), as well as the thermally stimulated current (TSC), thermally stimulated luminescence (TSL) and the X-ray induced optical absorption spectra thermal bleaching techniques. The role of the thermoactivated ionic and ionic-electronic processes in the TSR (thermal bleaching, TSC and TSL) of X-ray irradiated crystals is studied above 250 K. The TSL efficiency (ratio TSL/TSC) ver…
A full-atom multiscale modelling for sodium chloride diffusion in anion exchange membranes
2021
Abstract A novel full-atom multiscale method, combining different computational approaches and aimed to describe diffusion of multiple ions in anion exchange membranes (AEM), is presented. The method is used to evaluate diffusion of chloride and sodium ions in polysulfone tetramethylammonium (PSU-TMA) membranes, with particular attention to the co-ion diffusion. The hydration of the PSU-TMA is computed as a function of the membrane ionic exchange capacity via Density Functional Theory (DFT) and used for carrying out molecular dynamics simulations (MD). An upgraded DFT-based approach is proposed to obtain the atoms’ charges used in the force field for the MD simulations. Three approaches hav…
Ionic conduction through single-pore and multipore polymer membranes in aprotic organic electrolytes
2021
Abstract We experimentally characterize the ionic conduction of single and multipore nanoporous membranes in aprotic organic electrolytes. To this end, soft-etched (SE) membranes with pore diameters in the nanometer range and track-etched (TE) membranes with pore diameters in the tens of nanometers range are investigated. In aqueous conditions, the membrane ionic conduction rates follow the same trend of the bulk solution conductivities. However, the ionic transport through the narrow SE-nanopores dramatically decreases in aprotic electrolytes due to the formation of solvated metal cations and their adsorption on the pore surface. The current-voltage recordings of single conical nanopores i…
Small radius electron and hole polarons in PbX2 (X = F, Cl, Br) crystals: a computational study
2021
First-principles hybrid density functional theory (DFT) calculations were performed for small radius polarons – self-trapped electrons (STELs) and holes (STHs) in PbX2 (X = F, Cl, Br) crystals, widely used as parent materials for inorganic halide perovskites (CsPbX3) and scintillators. The atomic and electronic structures, spin and charge distributions and formation energies for both types of polarons were predicted for orthorhombic PbF2 and STELs for cubic PbF2. The STH structure was identified in a controversial case of PbCl2. We also confirmed and analyzed in detail experimentally suggested configurations for other cases. It is shown how, due to a delicate balance of ionic and covalent c…
Ab initio calculations of MgF2 (001) and (011) surface structure
2010
We present the results of calculations of surface relaxations, rumplings, and charge distribution for the MgF2 (0 0 1) and (0 1 1) surfaces using ab initio code Crystal-2003 and the hybrid exchange-correlation B3PW functional. These two neutral and polar surfaces show very small relaxation and negligible increase of covalent contribution to the chemical bonding thus remaining considerably ionic. The calculated bulk optical band gap is in a good agreement with the experimental value, whereas optical band gap for the polar (0 1 1) surface is reduced by 0.6 eV compared with the calculated bulk value, in contrast to the (0 0 1) surface gap which remains very close to the bulk.
Ab initio calculations of the atomic and electronic structure of MgF2 (011) and (111) surfaces
2011
Abstract The results of ab initio slab calculations of surface relaxations, rumplings and charge distribution for the different terminations of the MgF2 (011) and (111) polar surfaces are presented and discussed. We have employed the computer code CRYSTAL with the Gaussian basis set and the hybrid B3PW exchange-correlation functional. Despite the ionic nature of the chemical bonding at both surfaces, a considerable decrease of the optical band gap is predicted (1.3 eV or 10%) for the (111) surface as compared to the bulk.
The effect of polycations on early cement paste
2010
International audience; This paper studies the possibility for improving the ductility of cement based materials by means of oligocationic additives. Actually, the setting of cement is due to ionic correlation forces between highly negatively charged C-S-H nanoparticles throughout a calcium rich solution. The main drawback of this strong attraction is its very short range that results in low elastic deformation of hydrated cementitious materials. A way to enlarge the attraction range between C-S-H particles would be to add cationic oligomers that would compete with calcium ions modifying the ionic correlation forces via a bridging mechanism of longer range, which could lead to a more ductil…