Search results for "bonding"
showing 10 items of 996 documents
Chitosan-based smart hybrid materials: a physico-chemical perspective.
2020
Chitosan is one of the most studied cationic polysaccharides. Due to its unique characteristics of being water soluble, biocompatible, biodegradable, and non-toxic, this macromolecule is highly attractive for a broad range of applications. In addition, its complex behavior and the number of ways it interacts with different components in a system result in an astonishing variety of chitosan-based materials. Herein, we present recent advances in the field of chitosan-based materials from a physico-chemical perspective, with focus on aqueous mixtures with oppositely charged colloids, chitosan-based thin films, and nanocomposite systems. In this review, we focus our attention on the physico-che…
Solid polymer electrolytes from a fluorinated copolymer bearing cyclic carbonate pendant groups
2018
International audience; A poly(vinylidene fluoride-co-(2-oxo-1,3-dioxolan-4-yl)methyl 2-(trifluoromethyl)acrylate) random copolymer, poly(VDF-co-MAF-cyCB), with a MAF-cyCB weight fraction of 59% was synthesized via free radical copolymerization of VDF and MAF-cyCB, which is a methacrylate bearing cyclocarbonate side-chain. This copolymer showed nano-structured morphology, where crystalline PVDF-rich domains co-existed with amorphous poly(VDF-co-MAF-cyCB) segments. Solid polymer electrolytes were further obtained by loading the poly(VDF-co-MAF-cyCB) copolymer with various amounts of LiClO4. The added lithium salt was dissolved in the poly(VDF-co-MAF-cyCB) amorphous phase, which allowed the f…
Super-Ionic State Studies in LNTN Solid Solutions by Raman Spectroscopy
2012
Raman studies of the thermal phase transformations and structural disordering preceding transition to the super-ionic state in the Li0.12Na0.88TaуNb1-уO3 solid solution ceramics are reported. Disordering of the structure brought up by the extremely mobile Li+ ions at heating is found to be homogeneous and to proceed gradually. Disorientation and considerable deformation of the BO6 oxygen octahedrons facilitate translational mobility of the Li+ ions. The static disordering of the Nb5+ and Ta5+ sub-lattice caused by tantalum decreases the temperature of the phase transformation and increases the probability of transition to the super-ionic state supposed to occur over a broad temperature rang…
Numerical and Experimental Assessment of FRP-Concrete Bond System
2021
Fiber reinforced polymer (FRP) composite systems are widely used to repair structurally deficient constructions thanks to their good corrosion resistance, light weight and high strength. The quality of the FRP-substrate interface bond is a crucial parameter affecting the performance of retrofitted structures. In this study, ultrasonic testing have been used to assess the quality of the bonding. In the case of FRP laminates adhesively bonded to concrete, high scattering attenuation occurs due to the presence of concrete heterogeneities. The substrate material behaves almost like a perfect absorber generating a considerable number of short-spaced echo peaks that make the defect echo not disti…
Hybrid density functional theoretical study of NASICON-type NaxTi2(PO4)3 (x = 1–4)
2020
Sodium Super Ionic Conductor (NASICON) structured phosphate framework compounds represent a very attractive class of materials for their use as Na-ion battery electrodes. A series of NASICON-structured NaxTi2(PO4)3 compounds corresponding to varying degrees of sodiation (x = 1–4) have been investigated using high-level hybrid density functional theory calculations using the Linear Combination of Atomic Orbitals and Gaussian-type basis set formalism together with hybrid B1WC and HSE06 exchange–correlation functionals. Using primitive cells of NaxTi2(PO4)3 compounds with different stoichiometry, sodium sublattice structure and titanium oxidation states are constructed and analyzed using group…
Light-induced ionic processes in optical oxide glasses
1991
Abstract The density of optical glasses is changed by the influence of light capable of generating color centers in these materials. Such defect generation is not only an electronic process, but an atomic displacement is also necessary. The strong localization of electronic and vibrational excitations in the glass network leads to the high efficiency of sub-threshold defect generation. Secondary ionic processes lead to the changes of basic glass properties (light refractive index, density, mechanical strength, etc.); thus, it is possible to use optical glasses as light detectors for appropriate wavelengths.
Correlating the Lifetime and Fluorine Content of Iridium(III) Emitters in Green Light-Emitting Electrochemical Cells
2013
In light-emitting electrochemical cells, the lifetime of the device is intrinsically linked to the stability of the phosphorescent emitter. In this study, we present a series of ionic iridium(III) emitters based on cyclometalating phenylpyridine ligands whose fluorine substituents are varied in terms of position and number. Importantly, despite these structural modifications, the emitters exhibit virtually identical electrochemical and spectroscopic properties, which allows for proper comparison in functional devices. Quantum chemical calculations support the properties measured in solution and suggest great similarities regarding the electronic structures of the emitters. In electrolumines…
Improving the Turn-On Time of Light-Emitting Electrochemical Cells without Sacrificing their Stability
2010
The luminance, efficiency, and turn-on time of ionic iridium complex-based light-emitting electrochemical cells can be improved by inserting an ionic liquid with high intrinsic conductivity. This results in a device in which the decrease in turn-on time is achieved while maintaining the stability.
Ionic circuitry with nanofluidic diodes
2019
Ionic circuits composed of nanopores functionalized with polyelectrolyte chains can operate in aqueous solutions, thus allowing the control of electrical signals and information processing in physiological environments. We demonstrate experimentally and theoretically that different orientations of single-pore membranes with the same and opposite surface charges can operate reliably in series, parallel, and mixed series-parallel arrangements of two, three, and four nanofluidic diodes using schemes similar to those of solid-state electronics. We consider also different experimental procedures to externally tune the fixed charges of the molecular chains functionalized on the pore surface, show…
On the Field Variables Influence on Bonding Phenomena during FSW Processes: Experimental and Numerical Study
2013
Solid state bonding recurs in several manufacturing processes, as Friction Stir Welding (FSW), Linear Friction Welding (LFW), extrusion of hollow profiles and Accumulative Roll Bonding (ARB). The former processes are nowadays of particular industrial interest because of the specific advantages with respect to the classic welding technologies. In FSW the solid state bonding is obtained between an undeformed cold material, already placed in the advancing side of the joint, and the hot material flow incoming from the retreating side. Proper conditions of pressure, temperature, strain and strain rate are needed in order to get the final effective bonding. In the paper experimental tests on butt…