Search results for "equilibrium"
showing 10 items of 1021 documents
Breakdown of weak-turbulence and nonlinear wave condensation
2009
Abstract The formation of a large-scale coherent structure (a condensate) as a result of the long time evolution of the initial value problem of a classical partial differential nonlinear wave equation is considered. We consider the nonintegrable and unforced defocusing NonLinear Schrodinger (NLS) equation as a representative model. In spite of the formal reversibility of the NLS equation, the nonlinear wave exhibits an irreversible evolution towards a thermodynamic equilibrium state. The equilibrium state is characterized by a homogeneous solution (condensate), with small-scale fluctuations superposed (uncondensed particles), which store the information necessary for “time reversal”. We an…
A theory of spatial general equilibrium in a fuzzy economy
1984
Let an economic space be characterized by the existence of a given distribution of locations, i.e. consumers' residential locations and producers' plants. It is equipped with a system of prices. The economy is fuzzy because the economic behaviors of agents are imprecise. In this context, spatial partial equilibria theories are applications of a fuzzy economic calculation model. The aim of the present paper is to study the conditions which must be fulfilled in order that the compatibility of consumers' equilibria and producers' equilibria be verified. Mathematical tools are Butnariu's theorems which extend the Brouwer's and Kakutani's theorems to the cases of fuzzy functions and fuzzy point-…
Self-consistent GW calculations of electronic transport in thiol- and amine-linked molecular junctions
2011
The electronic conductance of a benzene molecule connected to gold electrodes via thiol, thiolate, or amino anchoring groups is calculated using nonequilibrium Green functions in combination with the fully self-consistent GW approximation for exchange and correlation. The calculated conductance of benzenedithiol and benzenediamine is one-fifth that predicted by standard density functional theory (DFT), in very good agreement with experiments. In contrast, the widely studied benzenedithiolate structure is found to have a significantly higher conductance due to the unsaturated sulfur bonds. These findings suggest that more complex gold-thiolate structures where the thiolate anchors are chemic…
Levels of self-consistency in the GW approximation
2009
We perform $GW$ calculations on atoms and diatomic molecules at different levels of self-consistency and investigate the effects of self-consistency on total energies, ionization potentials and on particle number conservation. We further propose a partially self-consistent $GW$ scheme in which we keep the correlation part of the self-energy fixed within the self-consistency cycle. This approximation is compared to the fully self-consistent $GW$ results and to the $G W_0$ and the $G_0W_0$ approximations. Total energies, ionization potentials and two-electron removal energies obtained with our partially self-consistent $GW$ approximation are in excellent agreement with fully self-consistent $…
Allelic age of the USH2A c.2299delG mutation
2010
24 p., figuras y bibliografía
The impacts of the ALE and hydrostatic-pressure approaches on the energy budget of unsteady free-surface flows
2008
Abstract This paper focuses on the energy budget in the calculation of unsteady free-surface flows on moving grids with and without using the ‘arbitrary Lagrangian–Eulerian’ (ALE) formulation or hydrostatic-pressure assumption. The numerical tool is an in-house general-purpose solver for the unsteady, incompressible and homogeneous Navier–Stokes equations in a Cartesian domain. An explicit fractional-step method and co-located finite-volume method are used for the second-order accurate integrations in time and space. The test cases are nonlinear and linear irrotational standing waves, which allow to characterise the impacts of an ALE or Eulerian formulation with moving grids by comparison w…
Calcium binding and ionic conduction in single conical nanopores with polyacid chains: model and experiments.
2012
Calcium binding to fixed charge groups confined over nanoscale regions is relevant to ion equilibrium and transport in the ionic channels of the cell membranes and artificial nanopores. We present an experimental and theoretical description of the dissociation equilibrium and transport in a single conical nanopore functionalized with pH-sensitive carboxylic acid groups and phosphonic acid chains. Different phenomena are simultaneously present in this basic problem of physical and biophysical chemistry: (i) the divalent nature of the phosphonic acid groups fixed to the pore walls and the influence of the pH and calcium on the reversible dissociation equilibrium of these groups; (ii) the asym…
Dynamical Casimir-Polder force between an excited atom and a conducting wall
2016
We consider the dynamical atom-surface Casimir-Polder force in the non-equilibrium configuration of an atom near a perfectly conducting wall, initially prepared in an excited state with the field in its vacuum state. We evaluate the time-dependent Casimir-Polder force on the atom, and find that it shows an oscillatory behavior from attractive to repulsive both in time and in space. We also investigate the asymptotic behavior in time of the dynamical force and of related local field quantities, showing that the static value of the force, as obtained by a time-independent approach, is recovered for times much larger than the timescale of the atomic self-dressing, but smaller than the atomic d…
Capital Regulation with Heterogeneous Banks
2013
We provide a general equilibrium analysis of potential consequences from the introduction of a binding leverage ratio, as proposed in Basel III. If banks differ in their monitoring skills and their ability to successfully complete a risky investment project, a tighter leverage ratio does not only mitigate moral hazard arising from limited liability, but also carries an unintended consequence: Banks are not allowed to absorb the entire supply of debt if they cannot raise new equity, which induces agents with a lower monitoring skill to open a bank. This decreases the average ability of operating banks. We further show that rising heterogeneity in the banking sector increases this negative ef…
Stackelberg-Walras and Cournot-Walras equilibria in mixed markets: a comparison
2012
In this note, we compare two strategic general equilibrium concepts: the Stackelberg-Walras equilibrium and the Cournot-Walras equilibrium. We thus consider a market exchange economy embodying atoms and a continuum of traders. It is shown that, when the preferences of the small traders are represented by Cobb-Douglas utility functions, the Stackel-berg-Walras and the Cournot-Walras equilibria can coincide only if 1) the endowments and preferences of atoms are identical and 2) the elasticity of the followers’ best response functions are equal to zero in equilibrium.