Search results for "equilibrium"
showing 10 items of 1021 documents
Stabilization Effects of Dichotomous Noise on the Lifetime of theSuperconducting State in a Long Josephson Junction
2015
We investigate the superconducting lifetime of a long overdamped current-biased Josephson junction, in the presence of telegraph noise sources. The analysis is performed by randomly choosing the initial condition for the noise source. However, in order to investigate how the initial value of the dichotomous noise affects the phase dynamics, we extend our analysis using two different fixed initial values for the source of random fluctuations. In our study, the phase dynamics of the Josephson junction is analyzed as a function of the noise signal intensity, for different values of the parameters of the system and external driving currents. We find that the mean lifetime of the superconductive…
Equilibria in the anionic polymerization of methyl methacrylate, 1. Chain-length dependence of the rate and equilibrium constants
1986
The rate constants of polymerization and cyclization and the equilibrium constants of polymerization are calculated from kinetic data of the anionic oligomerization of methyl methacrylate initiated by methyl α-lithioisobutyrate in THF at 25°C, and of the “disproportionation” of living oligomers. The numeric method reported earlier was improved. The rate constants of cyclization decrease with chain-length, due to increasing steric hindrance. The rate constants of polymerization depend on the concentration of active centres, due to the formation of associates. Rate and equilibrium constants of polymerization decrease with chain-length. This is discussed in terms of intramolecular coordination…
European traditional tomatoes galore: a result of farmers' selection of a few diversity-rich loci
2022
A comprehensive collection of 1254 tomato accessions, corresponding to European traditional and modern varieties, early domesticated varieties, and wild relatives, was analyzed by genotyping by sequencing. A continuous genetic gradient between the traditional and modern varieties was observed. European traditional tomatoes displayed very low genetic diversity, with only 298 polymorphic loci (95% threshold) out of 64 943 total variants. European traditional tomatoes could be classified into several genetic groups. Two main clusters consisting of Spanish and Italian accessions showed higher genetic diversity than the remaining varieties, suggesting that these regions might be independent seco…
Pension Schemes and Falling Birth-Rates: Change in Customs or Microeconomic Optimization?
2004
In this paper, we develop an overlapping generations model where fertility is endogenous. The utility of the parents is a function of the number of their children, and each child implies two types of fixed costs: the financial cost and the cost in terms of time. A "pay-as-you-go" pension scheme introduces an externality in that the number of children will be fewer than optimal because their favorable impact on the level of pension income is not taken into account. First, we define the competitive equilibrium dynamics and the steady state. This allows comparisons with the optimal stationary state, a notion which generalizes the golden rule. Two instruments, pensions and child benefits, are n…
D2/H2 adsorption selectivity on FAU zeolites at 77.4 K: Influence of Si/Al ratio and cationic composition
2018
Abstract Equilibrium D2/H2 adsorption selectivity was determined at 77.4 K below 1000 hPa for a series of FAU type zeolites X exchanged with different cations (Li+, Na+, K+, Mg2+, Ca2+, Ba2+ and Mn2+). In addition NaY, DAY (dealuminated Y) and pure silica CHA and MFI zeolites were studied. Two experimental approaches were used to determine the D2/H2 adsorption selectivity: direct determination at the thermodynamic equilibrium from manometric coadsorption experiments and calculations by Ideal Adsorbed Solution Theory (IAST) from single gas adsorption isotherms. While these two approaches are not in quantitative agreement, they reveal similar trends. At low loading ( MnX > LiX > CaX ≈ NaX > …
Immunochemical method for penthiopyrad detection through thermodynamic and kinetic characterization of monoclonal antibodies.
2021
Immunoassays are nowadays being employed for rapid contaminant analysis in clinical, environmental, and agrochemical samples. A thorough characterization of the antibody‒antigen interaction can bring light to the immunoreagent selection process in order to develop sensitive and robust tests. Thus, determination of equilibrium and reaction rate constants is usually recommendable. However, this can be quite tricky for low molecular weight compounds, and competitive strategies are commonly followed to estimate apparent affinity values. In the present study, a collection of monoclonal antibodies to penthiopyrad was raised for the first time, and apparent equilibrium constants were assessed by t…
Production technologies in stochastic continuous time models
2011
Abstract Properties of dynamic stochastic general equilibrium models can be revealed by either using numerical solutions or qualitative analysis. Very precise and intuition-building results are obtained by working with models which provide closed-form solutions. Closed-form solutions are known for a large class of models some of which, however, have some undesirable features such as potentially negative output. This paper offers closed-form solutions for models which are just as tractable but do not suffer from these shortcomings.
Solving Two-Person Zero-Sum Stochastic Games With Incomplete Information Using Learning Automata With Artificial Barriers
2021
Learning automata (LA) with artificially absorbing barriers was a completely new horizon of research in the 1980s (Oommen, 1986). These new machines yielded properties that were previously unknown. More recently, absorbing barriers have been introduced in continuous estimator algorithms so that the proofs could follow a martingale property, as opposed to monotonicity (Zhang et al., 2014), (Zhang et al., 2015). However, the applications of LA with artificial barriers are almost nonexistent. In that regard, this article is pioneering in that it provides effective and accurate solutions to an extremely complex application domain, namely that of solving two-person zero-sum stochastic games that…
Scheduling Domestic Shiftable Loads in Smart Grids: A Learning Automata-Based Scheme
2017
In this paper, we consider the problem of scheduling shiftable loads, over multiple users, in smart grids. We approach the problem, which is becoming increasingly pertinent in our present energy-thirsty society, using a novel distributed game-theoretic framework. From a modeling perspective, the distributed scheduling problem is formulated as a game, and in particular, a so-called “Potential” game. This game has at least one pure strategy Nash Equilibrium (NE), and we demonstrate that the NE point is a global optimal point. The solution that we propose, which is the pioneering solution that incorporates the theory of Learning Automata (LA), permits the total supplied loads to approach the p…
Adducts of 1,4-diazabutadienes with group IIB metal halides
1981
Abstract The reactions of 1,4-diazabutadienes (or α-diimines) RNC(R′)C(R″)NR, DAB, (R = p -C 6 H 4 OMe, R′ = R″ = H, DAB I ; R = p -C 6 H 4 OMe,R′ = H, R″ = Me, DAB II ; R = p -C 6 H 4 OMe, R′= R″ = Me; DAB III ; R = CMe 3 , R′ = R″ = H, DAB IV ) with MX 2 M = Zn, Cd, Hg; X = CI, Br) yield in general 1/1 adducts. These species are assigned a monomeric configuration with a σ,σ′-N,N′, chelating DAB ligand for M = Zn, Hg, whereas the CdCl 2 adducts have polymeric structures with terminal and/or bridging chlorides. In the reactions of CdCl 2 with DAB I or DAB IV polymeric species [(CdCl 2 ) 2 (DAB)] x are obtained in which all chlorides are bridging. Spectrophotometric dissociation equilib…