Search results for "medium"
showing 10 items of 3746 documents
Effect of a finite external heat transfer coefficient on the Darcy-Bénard instability in a vertical porous cylinder
2013
Publised version of an article from the journal: Physics of Fluids. Copyright (2013) American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. Article appears in Volume 25 issue 4 of the journal: http://dx.doi.org/10.1063/1.4799253 The onset of thermal convection in a vertical porous cylinder is studied by considering the heating from below and the cooling from above as caused by external forced convection processes. These processes are parametrised through a finite Biot number, and hence through third-kind, or Robin, temperature conditions imposed on the lower and upper b…
Thermoconvective instabilities in an inclined porous channel heated from below
2011
Abstract The thermoconvective instability in an inclined rectangular channel filled with a fluid saturated porous medium and heated from below with a uniform flux is investigated. A stationary parallel buoyant flow with a linear temperature change in the transverse direction is considered. The linear stability to transverse and longitudinal roll disturbances of this basic state is examined. The thermoconvective instability onset of transverse rolls occurs when the Darcy–Rayleigh number exceeds a critical value, that increases with the inclination angle. The critical Darcy–Rayleigh number is discontinuous at the inclination angle 23.4749° above the horizontal. It is shown that, when the incl…
Experimental research of surfaced nanoparticle thermal transport in a porous medium
2018
Abstract Experimental research on thermally induced nanocolloid transport in a porous environment is presented. Addition of excess surfactant to a colloid with dispersed phase made of surfaced nanoparticles results in a decrease of effective Soret coefficient in a porous environment. It is shown that with sufficient amounts of surfactant added, this effect extends to a reversal of nanoparticle thermophoretic transport direction, and that the effect shows a tendency of saturation. A mechanism of thermal transport that involves slip velocity of surfactant molecules appearing near pore walls is evaluated as a possible cause of the decrease of Soret coefficient. Effects of temperature on partic…
Local thermal non-equilibrium effects in the Darcy–Bénard instability of a porous layer heated from below by a uniform flux
2013
Abstract The influence of the lack of thermal equilibrium between the solid phase and the fluid phase on the convective instability in a porous medium is studied. A horizontal layer with parallel and impermeable bounding walls is considered. The lower wall is assumed to be isoflux, and the upper wall isothermal. The basic motionless state is perturbed with small-amplitude disturbances, so that a linear analysis of the instability is carried out with a streamfunction-temperature formulation of the local balance equations. Then, the governing equations are solved for the normal modes, leading to an eigenvalue problem for the neutral stability. This eigenvalue problem is solved analytically, t…
Apatite and clinopyroxene as tracers for metasomatic processes in nepheline clinopyroxenites of Uralian-Alaskan-type complexes in the Ural Mountains,…
2013
Clinopyroxene and apatite are found to trace metasomatic processes in nepheline-bearing clinopyroxenites (tilaites) from the igneous, mafic-ultramafic Uralian-Alaskan-type complexes of Kytlym and Nizhny Tagil, Ural Mountains, Russian Federation. The clinopyroxenites consist predominantly of coarse-grained, partially to totally altered clinopyroxene phenocrysts in a matrix of fine-grained olivine, clinopyroxene, plagioclase, K-feldspar, and nepheline. Apatite occurs as idiomorphic inclusions (2O-, Na2O-, and Al2O3-bearing fluid. During conversion of the plagioclase, CaO and SiO2 were partitioned into the fluid. Altered areas in the clinopyroxene phenocrysts are characterized by the redistrib…
Chemical composition and roughness of enamel and composite after bleaching, acidic beverages and toothbrushing
2019
Background In this study was assessed the surface roughness and chemical composition of tooth enamel and composite resin after bleaching treatment, immersion in acidic beverages, and simulated toothbrushing. Material and methods One hundred and twenty dental blocks (10 x 10 x 3 mm) were randomly assigned (n = 10) according to surface treatment [none (N), bleaching (B), toothbrushing (T), and B+T] and storage medium [saliva (S), whiskey (W), and orange juice (O)]: experimental groups - N+S, N+W, N+O, B+S, B+W, B+O, S+T, W+T, O+T, B+S+T, B+W+T, and B+O+T. Two bleaching sessions were conducted using 38% hydrogen peroxide (3 applications). Surface roughness was measured using a roughness tester…
Laser-Induced Fluorescence Imaging of Paper Surfaces
1993
Laser-induced fluorescence imaging has been used to study the microstructure of paper surfaces. Pulses from a XeCl-excimer laser, 10 ns in duration at 308 nm, were used for excitation, and fluorescence was collected at 420 nm. The excitation spot diameter was approximately 20 µm, and the sampling interval 0.15 mm. Within an area of 5*5 mm2, 1023 sampling points were recorded to generate 3D fluorescence maps of paper surfaces. Papers containing fluorescence whitening agents (FWAs) gave the highest average fluorescence signals. Coated papers with no FW As show weaker signals than the base sheet. For some thirty different paper samples, an obvious correlation between the amount of coating and…
The evolution of the local role(s) of the university in a low-tech region
2013
The present case study addresses the case of a geographical area neglected by most of the literature about the changing role of Higher Education Institutions (HEIs): the low-tech contexts. This literature has traditionally exhibited two primary aspects. First, a focus on success stories such as entrepreneurial universities located in high-tech regions (e.g. Silicon Valley). Second, it reveals an inclination towards an evolution from ivory towers to entrepreneurial universities. The article argues that this oversimplification does not apply exactly to some environments where the HEIs have maintained links with industry since their inception. The purpose is to demonstrate HEIs' relevance in l…
Liquid chromatography‐Orbitrap Tribrid high‐resolution mass spectrometry using data dependent‐tandem mass spectrometry with triple stage fragmentatio…
2021
A new, fast, and automatic approach has been applied for the tentative identification of unknown substances released by food contact epoxy resin after performing a migration test with food simulant. This approach combines intelligent data acquisition with AcquireX linked to liquid chromatography-Orbitrap Tribrid high-resolution mass spectrometry using data dependent-tandem mass spectrometry with triple stage fragmentation coupled to Compound Discoverer™ software for automated data processing and compound identification. The identification of the observed features was performed using a set of identification criteria, including exact mass, isotope pattern, tandem mass spectrometry spectra mat…
The Reduction Pathway of End-on Coordinated Dinitrogen. II. Electronic Structure and Reactivity of Mo/W−N2, −NNH, and −NNH2 Complexes
2001
DFT calculations (B3LYP/LanL2DZ) of simplified models of [Mo(N(2))(2)(dppe)(2)] and the two protonated derivatives [MoF(NNH)(dppe)(2)] and [MoF(NNH(2))(dppe)(2)](+) (dppe = 1,2-bis(diphenylphosphino)ethane) provide quantitative insight into the reduction and protonation of dinitrogen bound end-on terminally to transition metals. This "asymmetric" reduction pathway is characterized by a stepwise increase of covalency and a concomitant charge donation from the metal center during each protonation reaction. The major part of metal-to-ligand charge transfer occurs after the first protonation leading to coordinated diazenido(-). In contrast, addition of the second proton is accompanied by a mino…