Search results for "trifluoromethanesulfonate"
showing 10 items of 276 documents
CCDC 1002402: Experimental Crystal Structure Determination
2014
Related Article: Chandan Giri, Filip Topić, Prasenjit Mal, Kari Rissanen|2014|Dalton Trans.|43|17889|doi:10.1039/C4DT02754J
CCDC 1873813: Experimental Crystal Structure Determination
2019
Related Article: Kristina S. Kisel, Alexei S. Melnikov, Elena V. Grachova, Antti J. Karttunen, Antonio Doménech-Carbó, Kirill Yu. Monakhov, Valentin G. Semenov, Sergey P. Tunik, Igor O. Koshevoy|2019|Inorg.Chem.|58|1988|doi:10.1021/acs.inorgchem.8b02974
CCDC 1868871: Experimental Crystal Structure Determination
2019
Related Article: Nadia Marino, Rosaria Bruno, Abdeslem Bentama, Alejandro Pascual-Álvarez, Francesc Lloret, Miguel Julve, Giovanni De Munno|2019|CrystEngComm|21|917|doi:10.1039/C8CE01894D
CCDC 1874712: Experimental Crystal Structure Determination
2019
Related Article: Biswanath Das, Afnan Al-Hunaiti, Brenda N. S��nchez-Egu��a, Erica Zeglio, Serhiy Demeshko, Sebastian Dechert, Steffen Braunger, Matti Haukka, Timo Repo, Ivan Castillo, Ebbe Nordlander|2019|Frontiers in Chemistry|7|97|doi:10.3389/fchem.2019.00097
CCDC 1407136: Experimental Crystal Structure Determination
2015
Related Article: Pia Bonakdarzadeh, Fangfang Pan, Elina Kalenius, Ondřej Jurček, Kari Rissanen|2015|Angew.Chem.,Int.Ed.|54|14890|doi:10.1002/anie.201507295
CCDC 1407137: Experimental Crystal Structure Determination
2015
Related Article: Pia Bonakdarzadeh, Fangfang Pan, Elina Kalenius, Ondřej Jurček, Kari Rissanen|2015|Angew.Chem.,Int.Ed.|54|14890|doi:10.1002/anie.201507295
CCDC 992712: Experimental Crystal Structure Determination
2014
Related Article: Anssi Peuronen, Samu Forsblom, Manu Lahtinen|2014|Chem.Commun.|50|5469|doi:10.1039/C3CC49663E
Mono- and di-nuclear complexes of ortho-palladated and -platinated 4,4′-dimethylazobenzene with bis(diphenylphosphino)methane. More data on transphob…
2002
Abstract Complexes [Pd(κ2-R)(μ-Cl)]2 [κ2-R=κ2-C,N′-C6H3(NNC6H4Me-4′)-2-Me-5 (1)] and [Pd(κ1-R)Cl(κ1-dppm)(κ2-dppm)]TfO [dppm=bis(diphenylphosphino)methane (2)] have been used to prepare new palladium derivatives containing dppm. Thus, complex 1 reacts with one equivalent of dppm to afford [{Pd(κ2-R)Cl}2(μ-dppm)] (3) and with AgClO4 and dppm (1:2:2 molar ratios) to give [Pd(κ2-R)(κ2-dppm)]ClO4 (4·ClO4). The triflate salt of this complex (4·TfO) reacts with PPh3 to yield [Pd(κ1-R)(PPh3)(κ2-dppm)]TfO (5). Dinuclear complexes were obtained by reacting 2, (i) with [AuCl(PPh3)] or [AuCl(tht)] (tht=tetrahydrothiophene) (1:1, −60 °C) and (ii) with 1 (2:1) to give, respectively, [Pd(κ1-R)Cl(μ-dppm…
Enantioselective synthesis of herbertane sesquiterpenes: synthesis of (−)-α-formylherbertenol
2000
Abstract The synthesis of 4-hydroxy-3-[(1 S )-1,2,2-trimethylcyclopentyl]benzaldehyde [(−)-α-formylherbertenol 1 ], a herbertane-type sesquiterpene isolated from the leafy liverwort Herberta adunca , from β-cyclogeraniol is described. The synthesis is based on the previously described preparation of an enantiopure 1,2,2-trimethylcyclopentane synthon from which the characteristic aromatic moiety of 1 is elaborated, using a Robinson annulation and a palladium-catalysed methoxycarbonylation of an aryl triflate as key synthetic steps. The synthesis of the natural sesquiterpene (−)-α-herbertenol, also a natural sequiterpene, using the same methodology is also described.
Self-assembly of 1D- and 3D-networks through non-coordination intermolecular forces: synthesis and crystal structures of copper(I) complexes based on…
2007
Reaction of [Cu2(H3CCN)2(μ-pydz)3][PF6]2 (1) with an excess of pyridazine or phthalazine yielded the novel dinuclear complexes [Cu2(μ-pydz)3(pydz)2][PF6]2 (2) and [Cu2 (μ- pydz)(μ-phtz)2(phtz)2][PF6]2 (5), respectively. Depolymerisation of the coordination polymer 1 ∞ {[Cu(μ-pydz)2][PF6]} (3) in dichloromethane by addition of an excess of benzo[c]cinnoline afforded the dinuclear copper(I) salt [Cu2(μ-pydz)2(pydz)2(benzo[c]cinnoline)2][PF6]2 (4). Furthermore, a new route for the preparation of bis(benzonitrile)tris(μ-phthalazine)dicopper(I) bis(trifluoromethanesulfonate), [Cu2(C6H5CN)2(μ-phtz)3][CF3SO3]2 (7), was established from {[Cu(CF3SO3)]2 ・C6H5Me}, phthalazine and benzonitrile via the …