Search results for "viol"

showing 10 items of 2848 documents

Contribution to the Knowledge of Dermatophytic Invasion of Hair

1970

We have used the scanning electron microscope to investigate the changes that occur in scalp hair during infection with Trichophyton violaceum . We provide information on the morphology of these dermatophytes and present evidence that their hyphae dig tunnel-like burrows into the hair shaft, dissociating hair into keratin fibrils.

chemistry.chemical_classificationPathologymedicine.medical_specialtyHyphaintegumentary systemHair shaftfungiTrichophyton violaceumCell BiologyDermatologyBiologyBiochemistryMicrobiologymedicine.anatomical_structurechemistryScalpKeratinmedicineotorhinolaryngologic diseasessense organsskin and connective tissue diseasesMolecular BiologyJournal of Investigative Dermatology
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Photoaffinity labeling of the coupling factor 1 from the thermophilic bacterum PS3 by 8-azido ATP

1984

AbstractTo localize the nucleotide binding sites of the F1ATPase (TF1) from the thermophilic bacterium PS3 we have used 14C-labeled 8-azido ATP (8-N3ATP) as photoaffmity label. 8-N3ATP is hydrolyzed by the F,ATPase in the absence of ultraviolet light. Irradiation by ultraviolet light of the enzyme in the presence of 8-N3ATP results in reduction of ATPase activity and in preferential nucleotide specific labeling of the α subunits (0.8–0.9 mol 8-N3ATP/TF1,α:β = 4:1). Inactivation and labeling do not depend on the presence of Mg2+. Both effects decrease upon addition of various nucleotide di- or triphosphates.

chemistry.chemical_classificationPhotoaffinity labelingStereochemistryNoncatalytic nucleotide binding siteThermophileBiophysicsCell BiologyBiochemistryCoupling (electronics)HydrolysisEnzymechemistryStructural BiologyPhotoaffinity labelingMoleBacterial F1ATPaseGeneticsUltraviolet lightCatalytic nucleotide binding siteNucleotideThermophilic bacterium PS3Molecular BiologyFEBS Letters
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Multiple Short Term Effects of UV-B Radiation on the Diatom Phaeodactylum Tricornutum

1998

Increases in UV-B irradiance lead to many specific damaging effects upon the plants including damage of the thylakoid membrane, partial inhibition of PS II, decrease of chloroplast ATPase activity, loss of enzyme activities in the calvin cycle and alterations in pigment synthesis (1). Under natural conditions enhanced UV-B light is always accompanied by high intensities of photosynthetic active radiation (PAR). Damaging effects due to photoinhibitory PAR and UV-B light which lead to several oxygen radical species (2) could be reduced by photoprotection mechanisms. One of these protection mechanisms is the xanthophyll cycle. In higher plants and green algae violaxanthin is converted to zeaxa…

chemistry.chemical_classificationPhotoinhibitionbiologyDiadinoxanthinfood and beveragesDiatoxanthinbiology.organism_classificationchemistry.chemical_compoundchemistryPhotoprotectionThylakoidXanthophyllBiophysicsPhaeodactylum tricornutumViolaxanthin
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Parity violation energy of biomolecules - III: RNA

2006

The energy of parity-violation associated with a typical DNA double helix is estimated with ab initio techniques. It is shown that weak-nuclear interactions do not favor the formation of the double helices found in nature. Possible implications regarding the potential effect of parity-violation interactions on the evolution of biological homochirality are discussed.

chemistry.chemical_classificationPhysicsQuantitative Biology::BiomoleculesBiomoleculePotential effectAb initioGeneral Physics and AstronomyRNAParity violation; biomoleculesParity (physics)Dna double helixbiomoleculeschemistry.chemical_compoundchemistryParity violationComputational chemistryChemical physicsPhysical and Theoretical ChemistryHomochiralityDNA
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1997

On the basis of an extended series of monodisperse oligomers of the dialkoxy-substituted phenyleneethenylenes 1a–i the Eqs. (3) and (4) were conceived in order to determine the limiting values of the energies Ei and the wavelengths λi of the UV/vis absorption. The convergence of the Ei, and λi values with a growing number n of repeating units permits a precise prediction of the Ei,∞ and λi,∞ values of the corresponding polymer 1j as well as a statement about the overall effect of conjugation ΔEi and the effective conjugation length ECL. A great variety of different conjugated oligomers 2–14 can be evaluated by the same algorithm.

chemistry.chemical_classificationPolymers and PlasticsSeries (mathematics)Absorption spectroscopyGeneral Chemical EngineeringDispersityPolymerConjugated systemSpectral lineUltraviolet visible spectroscopychemistryPolymer chemistryPhysical chemistryAbsorption (electromagnetic radiation)Acta Polymerica
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Stilbene Content of MatureVitis viniferaBerries in Response to UV-C Elicitation

2001

A method using HPLC analysis has been used to compare the level of resveratrol and its derivatives, piceid, pterostilbene and epsilon-viniferin, in grapevine berries of three Vitis vinifera varieties. The concentration of these compounds has been evaluated in healthy and Botrytis cinerea infected grape clusters, both in natural vineyard conditions and in response to UV elicitation.

chemistry.chemical_classificationPterostilbenebiologyPlant ExtractsUltraviolet RaysPhytoalexinGeneral ChemistryFungi imperfectiResveratrolPlant disease resistancebiology.organism_classificationVineyardHorticulturechemistry.chemical_compoundchemistryFruitStilbenesBotanyGeneral Agricultural and Biological SciencesChromatography High Pressure LiquidBotrytis cinereaPiceidJournal of Agricultural and Food Chemistry
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UV-B-Induced acute toxicity of pyrene to the waterflea Daphnia magna in natural freshwaters.

1999

Abstract The effects of various water characteristics in natural freshwaters on the acute toxicity of one polycyclic aromatic hydrocarbon (PAH), pyrene, to a pelagic invertebrate Daphnia magna was studied under ultraviolet B (UV-B) radiation and in the dark. Pyrene was photoactivated and was more toxic to D. magna in the presence of UV-B radiation. Dissolved organic material (DOM), measured as dissolved organic carbon (DOC), significantly reduced the photoenhanced toxicity of pyrene. Under UV-B radiation the EC50 values were lower and in relation to the amount of DOM, ranging from 3.0 to 30.0 μg/L pyrene, whereas in the dark they were between 29.2 and 54.8 μg/L and not related to the amount…

chemistry.chemical_classificationPyrenesbiologyDose-Response Relationship DrugUltraviolet RaysHealth Toxicology and MutagenesisDaphnia magnaPublic Health Environmental and Occupational HealthPolycyclic aromatic hydrocarbonFresh WaterGeneral Medicinebiology.organism_classificationPollutionAcute toxicitychemistry.chemical_compoundchemistryCladoceraDaphniaEnvironmental chemistryDissolved organic carbonToxicityPyreneAnimalsOrganic matterOrganic ChemicalsEcotoxicology and environmental safety
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Biopartitioning micellar chromatography: An alternative high-throughput method for assessing the ecotoxicity of anilines and phenols

2007

An investigation of the use of the chromatographic retention (log k) as an in vitro approach for modelling the toxicity to Fathead Minnows of anilines and phenols is developed. A data set of 65 compounds with available experimental toxicity data was used. Log k data at three pH values were used for the compounds classification and two groups or 'MODEs' were identified. For one 'MODE' a quantitative retention-activity relationship (QRAR) model was calculated. Finally, it was used to estimate the toxicity to Fathead minnows of anilines and phenols for which experimental data are not available. These estimations were compared to those obtained from another toxicity (to Tetrahymena pyriformis) …

chemistry.chemical_classificationQuantitative structure–activity relationshipAniline CompoundsChromatographyToxicity dataTetrahymena pyriformisClinical BiochemistryCyprinidaeQuantitative Structure-Activity RelationshipAromatic amineExperimental dataCell BiologyGeneral MedicineBiochemistryAnalytical Chemistrychemistry.chemical_compoundPhenolschemistryTetrahymena pyriformisToxicityAnimalsSpectrophotometry UltravioletPhenolsEcotoxicityChromatography Micellar Electrokinetic CapillaryJournal of Chromatography B
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Influence of Several Effectors on the Structure-Activity Relationship of Spleen Phosphodiesterase

1993

The influence of Mg(II) and organic solvents on the structure-activity relationship of spleen phosphodiesterase II was analyzed using UV and fluorescence spectroscopies. An increase in the RNase activity found in the presence of Mg(II) was related to the enzyme-Mg(II) interaction detected by UV spectroscopy. In the fluorescence spectra of phosphodiesterase strong hypochromic and bathochromic effects were observed when RNA was present at a concentration (52 μg ml−1) of the same magnitude as the concentration that inhibits the activity (Ki = 40 μg ml−1). The strong quenching observed in the presence of RNA shows the importance of large dynamic and static quenching of the Trp residues of the e…

chemistry.chemical_classificationQuenching (fluorescence)ChemistryPhosphodiesteraseBiochemistryFluorescenceCatalysisFluorescence spectroscopyUltraviolet visible spectroscopyEnzymeBiochemistryBathochromic shiftBiophysicsDenaturation (biochemistry)General Agricultural and Biological SciencesBiotechnologyBiocatalysis
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O-Ribosyl-phosphate purine as a constant modified nucleotide located at position 64 in cytoplasmic initiator tRNAsMetof yeasts

1991

The unknown modified nucleotide G*, isolated from both Schizosaccharomyces pombe and Torulopsis utilis initiator tRNAs(Met), has been identified as an O-ribosyl-(1"----2')-guanosine-5"-phosphate, called Gr(p), by means of HPLC, UV-absorption, mass spectrometry and periodate oxidation procedures. By comparison with the previously published structure of Ar(p) isolated from Saccharomyces cerevisiae initiator tRNA(Met), the (1"----2')-glycosidic bond in Gr(p) has been postulated to have a beta-spatial conformation. The modified nucleotide Gr(p) is located at position 64 in the tRNA(Met) molecules, i.e. at the same position as Ar(p). Since we have also characterized Gr(p) in Candida albicans ini…

chemistry.chemical_classificationRNA Transfer MetbiologyPeriodic AcidSaccharomyces cerevisiaeGuanosine MonophosphateGuanosineRNA Fungalbiology.organism_classificationSaccharomycesMass Spectrometrychemistry.chemical_compoundchemistryBiochemistrySchizosaccharomycesGuanosine monophosphateTransfer RNASchizosaccharomyces pombeGeneticsSpectrophotometry UltravioletNucleotideOxidation-ReductionChromatography High Pressure LiquidSchizosaccharomycesCandidaNucleic Acids Research
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