0000000000000831
AUTHOR
S. Benmansour
Static and dynamic interaction betweenπanddelectrons in organic superconductorβ″-(BEDT-TTF)4[(H3O)Fe(C2O4)3]·C6H5Brstudied byC13NMR spectroscopy
We present the results of $^{13}\mathrm{C}$ NMR experiments in an organic superconductor with localized Fe spins ${\ensuremath{\beta}}^{\ensuremath{''}}\ensuremath{-}{(\text{BEDT-}\mathrm{TTF})}_{4}[({\mathrm{H}}_{3}\mathrm{O})\mathrm{Fe}{({\mathrm{C}}_{2}{\mathrm{O}}_{4})}_{3}]\ifmmode\cdot\else\textperiodcentered\fi{}{\mathrm{C}}_{6}{\mathrm{H}}_{5}\mathrm{Br}$. We reveal the antiferromagnetic coupling between Fe $d$ spins and $\ensuremath{\pi}$ spins, which creates an exchange field antiparallel to the external field direction at the $\ensuremath{\pi}$ electrons. In addition to the static effects of Fe spins, we show from the nuclear spin-lattice relaxation rate measurement that the magn…
CCDC 871616: Experimental Crystal Structure Determination
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CCDC 1046599: Experimental Crystal Structure Determination
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CCDC 848173: Experimental Crystal Structure Determination
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CCDC 703838: Experimental Crystal Structure Determination
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CCDC 675204: Experimental Crystal Structure Determination
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CCDC 681020: Experimental Crystal Structure Determination
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CCDC 681021: Experimental Crystal Structure Determination
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CCDC 681022: Experimental Crystal Structure Determination
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CCDC 604825: Experimental Crystal Structure Determination
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CCDC 673976: Experimental Crystal Structure Determination
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CCDC 604826: Experimental Crystal Structure Determination
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CCDC 673977: Experimental Crystal Structure Determination
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CCDC 276678: Experimental Crystal Structure Determination
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CCDC 855227: Experimental Crystal Structure Determination
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CCDC 604823: Experimental Crystal Structure Determination
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CCDC 1046598: Experimental Crystal Structure Determination
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CCDC 628140: Experimental Crystal Structure Determination
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CCDC 871619: Experimental Crystal Structure Determination
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CCDC 261263: Experimental Crystal Structure Determination
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CCDC 848172: Experimental Crystal Structure Determination
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CCDC 703839: Experimental Crystal Structure Determination
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CCDC 675203: Experimental Crystal Structure Determination
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CCDC 871618: Experimental Crystal Structure Determination
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CCDC 675200: Experimental Crystal Structure Determination
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CCDC 602812: Experimental Crystal Structure Determination
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CCDC 848174: Experimental Crystal Structure Determination
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CCDC 293662: Experimental Crystal Structure Determination
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CCDC 675202: Experimental Crystal Structure Determination
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CCDC 604824: Experimental Crystal Structure Determination
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CCDC 261262: Experimental Crystal Structure Determination
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CCDC 265898: Experimental Crystal Structure Determination
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CCDC 1046600: Experimental Crystal Structure Determination
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CCDC 673978: Experimental Crystal Structure Determination
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CCDC 871625: Experimental Crystal Structure Determination
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CCDC 848171: Experimental Crystal Structure Determination
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