0000000000004115
AUTHOR
J. Shakina
catena-Poly[[(18-crown-6-κ6O)potassium]-μ-chlorido-[(1H-benzotriazol-1-ol-κN3)chloridoplatinum(II)]-μ-(benzotriazol-1-olato-κ2N3:O)]
In the structure of the title compound, [KPt(C6H4N3O)Cl2(C6H5N3O)(C12H24O6)], the PtII atom is in a distorted square-planar geometry. The crystal structure is consolidated by O—H⋯O hydrogen bonds. The measured crystal was a non-merohedral twin with four components.
1-Mesitylmethyl-1Hbenzotriazole 3-oxide.
In the title compound, C16H17N3O, the benzotriazole ring forms a dihedral angle of 77.25 (6)° with the phenyl ring. The benzotriazole ring is essentially planar with a maximum deviation of 0.012 (19) Å. Weak intermolecular C—H...O hydrogen bonds form R22(10) motifs. The crystal packing is consolidated by π—π interactions with centroid–centroid distances of 3.5994 (12) Å together with very weak C—H...π interactions.
CCDC 720015: Experimental Crystal Structure Determination
Related Article: B.R.D.Nayagam, S.R.Jebas, J.Shakina, R.Murugesan, D.Schollmeyr|2010|Acta Crystallogr.,Sect.E:Struct.Rep.Online|66|m631|doi:10.1107/S1600536810015898
CCDC 770024: Experimental Crystal Structure Determination
Related Article: B.R.D.Nayagam, S.R.Jebas, J.Shakina, R.Murugesan, D.Schollmeyer|2010|Acta Crystallogr.,Sect.E:Struct.Rep.Online|66|o637|doi:10.1107/S1600536810004824