0000000000014548

AUTHOR

Christoph Hauzenberger

Reworking of Archaean and Palaeoproterozoic crust in the Mozambique belt of central Tanzania as documented by SHRIMP zircon geochronology

Abstract New SHRIMP zircon ages for high-grade rocks from the Pan-African Mozambique belt (MB) of central Tanzania document reworking of Archaean–Palaeoproterozoic crust during the formation of this Neoproterozoic collisional orogen. Several gneisses and granulites from the Great Ruaha river area yielded late Archaean emplacement ages of 2575–2680 Ma for their magmatic precursors. Core-rim relationships in some zircons revealed new zircon growth during relatively short episodes of granitoid magmatism. Metamorphic zircons, dated at 1925 Ma, provide new evidence for high-grade metamorphism during formation of the Palaeoproterozoic Usagaran mobile belt. Metamorphic rims around magmatic cores i…

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SHRIMP zircon ages for post-Usagaran granitoid and rhyolitic rocks from the Palaeoproterozoic terrain of southwestern Tanzania

We report SHRIMP zircon U-Pb ages for post-Usagaran granitic- to granodioritic intrusives and a rhyolitic agglomerate from the Palaeoproterozoic terrain of southwestern Tanzania. This terrain consists of strongly deformed and metamorphosed rocks ascribed to the ca. 2 Ga Usagaran mobile belt, voluminous post-Usagaran granitoids, and minor supracrustal successions. The southeastern part of this terrain is characterized by the occurrence of little deformed and virtually unmetamorphosed rhyolithic, dacitic and andesitic volcanic rocks which overlie the older Usagaran basement. These rocks extruded between 1820 and 1921 Ma, as documented by SHRIMP zircon ages, which are in good agreement with pr…

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Experimental study on the solubility of the “model”-pelite mineral assemblage albite + K-feldspar + andalusite + quartz in supercritical chloride-rich aqueous solutions at 0.2 GPa and 600°C

A total of 34 solubility experiments using the “model”-pelite mineral assemblage microcline + low albite + andalusite + quartz were performed at 600°C and 0.2 GPa over a total chloride range of 0.03–2.9 molal. The concentrations of sodium, potassium, aluminum, and silica were measured and the results are compared with four different thermodynamic datasets. The K/Na ratio was approached from below and above for the thermodynamically buffered mineral assemblage microcline + low albite + andalusite + quartz. Tight brackets were obtained for experiments performed in up to 1 molal chloride concentration. From 0.03 to ∼1 molal chloride concentration, a constant K/Na ratio of 0.33 was obtained. At…

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Isothermal decompression history in the “Western Granulite” terrain, central Tanzania: Evidence from reaction textures and trapped fluids in metapelites

Abstract The Mozambique Belt (MB) of the East Africa Orogen contains large areas of granulite-facies migmatitic gneisses with Archaean and Palaeoproterozoic protolith ages and that were recycled during the Neoproterozoic Pan-African orogeny. The study area is situated along the Great Ruaha River and within the Mikumi National Park in central Tanzania where migmatitic gneisses and mafic to intermediate granulites are interlayered with Neoproterozoic granulite-facies migmatitic metapelites. Mineral textures suggest isothermal decompression, with the peak mineral assemblage comprising Grt–Bt–Ky–Kfs–Pl–Qtz ± Phn ± Ti-Oxide ± melt and amphibolite-facies retrograde assemblage Grt–Bt–Sil–Ms–Kfs–Pl…

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Metamorphic petrology and zircon geochronology of high-grade rocks from the central Mozambique Belt of Tanzania: crustal recycling of Archean and Palaeoproterozoic material during the Pan-African orogeny

New data on the metamorphic petrology and zircon geochronology of high-grade rocks in the central Mozambique Belt (MB) of Tanzania show that this part of the orogen consists of Archean and Palaeoproterozoic material that was structurally reworked during the Pan-African event. The metamorphic rocks are characterized by a clockwise P–T path, followed by strong decompression, and the time of peak granulite facies metamorphism is similar to other granulite terranes in Tanzania. The predominant rock types are mafic to intermediate granulites, migmatites, granitoid orthogneisses and kyanite/sillimanite-bearing metapelites. The meta-granitoid rocks are of calc-alkaline composition, range in age fr…

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Solubility of the assemblage albite+K-feldspar+andalusite+quartz in supercritical aqueous chloride solutions at 650 °C and 2 kbar

Abstract The solubility of the high grade pelite assemblage albite+K-feldspar+andalusite+quartz at 650 °C and 2 kbar was determined in aqueous solutions over a total chloride range of 0.01–3 mCltot using rapid-quench hydrothermal technique. The concentration of Na, K, Si, and Al was determined in the fluid phase after quench. The K/Na ratio was determined by approaching the equilibrium from below and above. It is 0.34 at low chloride concentrations and decreases slightly to 0.31 with increasing total chloride. Silica and aluminum concentrations were determined only from undersaturation. The silica solubility is found to be independent of chloride concentration and is ∼0.13 molal. Aluminum i…

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Vestiges of the Mesoproterozoic Events in the Neoproterozoic Mozambique Belt: the East African Perspective in the Rodinia Puzzle

Abstract Most of the geological and palaeogeographical models consider the Neoproterozoic supercontinent Gondwana (∼650-550 Ma) as the direct offspring of the disintegrated Mesoproterozoic supercontinent Rodinia (∼1300-750 Ma). One of the main classical sutures along which the dispersing Rodinia fragments were fused into a new supercontinent (Godwana) is identified as the Mozambique belt of East Africa. The calc-alkaline magmatism (∼1200-950 Ma) in northern Mozambique, southern Malawi and southern Tanzania is regarded as the sole evidence for fragmentation of Rodinia, which is traced within this Neoproterozoic orogenic belt. There are no unequivocal Mesoproterozoic (Kibaran) sediments in th…

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SHRIMP U–Pb zircon and Sm–Nd garnet ages from the granulite-facies basement of SE Kenya: evidence for Neoproterozoic polycyclic assembly of the Mozambique Belt

The Taita Hills–Galana River region is a key area to demonstrate the polycyclic nature of the Mozambique Belt in SE Kenya. On the basis of petrological and tectonic data, this area is composed of two different granulite-facies terranes, which are separated by the 20–30 km wide Galana Shear Zone. The Taita Hills and adjoining Sagala Hills exhibit a metamorphic overprint at 630–645 Ma, similar to areas in Tanzania. An emplacement age for the magmatic precursor rocks of 850–960 Ma was derived from zircon cores. Sm–Nd garnet–whole-rock analyses give an age of 585 Ma, interpreted as the cooling age after 630–645 Ma metamorphism. Nd crustal residence ages are between 1000 and 1500 Ma. The Galana …

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