Author: Yun Xiong

0000000000016337

AUTHOR

Yun Xiong

Homo‐ and Heteroleptic Hypersilylcuprates — Valuable Reagents for the Synthesis of Molecular Compounds with a Cu−Si Bond

Unsolvated hypersilanides MHyp [Hyp = Si(SiMe3)(3)] of the heavier alkali metals (M-I = Na, K, Cs) react with copper tert-butoxide in toluene to yield crystalline heteroleptic cuprates [M-I(toluene)][tBuOCuHyp]. These cuprates proved to be valuable sources for pure hypersilylcopper and other cuprates bearing hypersilyl ligands such as the di(hypersilyl)cuprates M-I[CuHyp(2)]((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003).

research product

Molekulare Bleicluster - von der unerwarteten Entdeckung zur gezielten Synthese

research product

Molecular Lead Clusters?From Unexpected Discovery to Rational Synthesis

research product

CCDC 213801: Experimental Crystal Structure Determination

Related Article: K.W.Klinkhammer, J.Klett, Yun Xiong, Shenglai Yao|2003|Eur.J.Inorg.Chem.||3417|doi:10.1002/ejic.200300416

research product

CCDC 213804: Experimental Crystal Structure Determination

Related Article: K.W.Klinkhammer, J.Klett, Yun Xiong, Shenglai Yao|2003|Eur.J.Inorg.Chem.||3417|doi:10.1002/ejic.200300416

research product

CCDC 213803: Experimental Crystal Structure Determination

Related Article: K.W.Klinkhammer, J.Klett, Yun Xiong, Shenglai Yao|2003|Eur.J.Inorg.Chem.||3417|doi:10.1002/ejic.200300416

research product

CCDC 247553: Experimental Crystal Structure Determination

Related Article: K.W.Klinkhammer, Yun Xiong, Shenglai Yao|2004|Angew.Chem.,Int.Ed.|43|6202|doi:10.1002/anie.200461670

research product

CCDC 213802: Experimental Crystal Structure Determination

Related Article: K.W.Klinkhammer, J.Klett, Yun Xiong, Shenglai Yao|2003|Eur.J.Inorg.Chem.||3417|doi:10.1002/ejic.200300416

research product

CCDC 247552: Experimental Crystal Structure Determination

Related Article: K.W.Klinkhammer, Yun Xiong, Shenglai Yao|2004|Angew.Chem.,Int.Ed.|43|6202|doi:10.1002/anie.200461670

research product

CCDC 213800: Experimental Crystal Structure Determination

Related Article: K.W.Klinkhammer, J.Klett, Yun Xiong, Shenglai Yao|2003|Eur.J.Inorg.Chem.||3417|doi:10.1002/ejic.200300416

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PEPhysical Sciences and Engineering
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