0000000000017563

AUTHOR

Georges Boulon

showing 2 related works from this author

Optical characterization of YCa4O(BO3)3 and Nd:YCa4O(BO3)3 crystals

2007

International audience; We report a complete optical characterization of YCa4O(BO3)3 and Nd:YCa4O(BO3)3 crystals. We studied the relative orientation between the dielectric and the crystallographic frames as a function of the wavelength and performed accurate phase-matching angles measurements for second harmonic generation, using a single crystal cut as a sphere. We also recorded polarized luminescence spectra of Nd:YCOB along the principal axes of the dielectric frame. For both crystals, we measured the gray-tracking and the thermo-optic properties as a function of temperature and wavelength using oriented slabs. Finally, we measured all their dielectric and electro-optic coefficients, as…

Neodymium additionsLuminescenceNonlinear opticsInorganic compoundsPhysics::OpticsCrystal growth02 engineering and technologyDielectricMonocrystals01 natural sciencesDoped materials010309 opticsInorganic ChemistryDielectric materialsColor centersOptics0103 physical sciencesOptical phase matchingAngular measurementElectrical and Electronic EngineeringPhysical and Theoretical ChemistrySpectroscopy[PHYS]Physics [physics][PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]Optical propertiesbusiness.industryChemistryElectro-optical effectsThermo-optical effectsOrganic ChemistryOptical frequency conversionNonlinear opticsSecond-harmonic generationSecond harmonic generation021001 nanoscience & nanotechnologyAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsWavelengthTemperature dependenceOptical materialsYttrium BoratesQuaternary compoundsCrystal growth0210 nano-technologybusinessLuminescenceSingle crystalPrincipal axis theorem
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Optical behavior of Eu3+-doped BaTiO3 nano-crystallites prepared by sol–gel method

2003

Abstract Eu 3+ -doped BaTiO 3 nano-crystallites with grain sizes 32–38 nm have been obtained by a sol–gel method. It has been found that the luminescence characteristics are strongly dependent on the sintering temperature. Powders sintered at temperatures below 1000 °C demonstrate a luminescence behavior at room temperature associated with a lack of the inversion symmetry of Eu 3+ sites. Above 1000 °C nano-crystallites undergo a phase transition characterized by an inversion symmetry of Eu 3+ sites. The size effect of Eu 3+ :BaTiO 3 nano-crystallites on luminescence characteristics is observed.

Phase transitionMaterials scienceOrganic ChemistryDopingSinteringMineralogyAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsInorganic Chemistrysymbols.namesakeNanocrystalChemical engineeringsymbolsCrystalliteElectrical and Electronic EngineeringPhysical and Theoretical ChemistryRaman spectroscopyLuminescenceSpectroscopySol-gelOptical Materials
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