1D coordination polymer based on copper(II)-containing tetrameric 1,2,3-triazole ligand from click chemistry: Magnetic and catalytic properties
Abstract A novel tetrameric tetra[O-((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)]-pentaerythritol (TBTP) has been synthesized using click chemistry strategy. TBTP was characterized and used as ligand to form new Cu(II) complexes, forming 1-D coordination polymers. Two square planar complexes were characterized by single-crystal X-ray diffraction, presenting formula [Cu(TBTP)][Cu(NO3)4] (1) and [Cu(TBTP)](NO3)2 (2). In both structures, a cationic 1-D coordination polymer (CP) has been formed. The CP contain a 1:1 Cu(II)/TBTP ratio with four neutral triazole groups coordinating the Cu(II) center, forming a Cu N bonds ranging 1.988(2)–2.001(2) A. The study of the magnetic properties of compounds 1…
CCDC 1811037: Experimental Crystal Structure Determination
Related Article: Leonardo C. Moraes, Gilmar P. de Souza, Humberto V. Fajardo, Sulusmon C. Luz, Eleuterio Álvarez, Francesc Lloret, Renato M. Ribeiro-Viana, Javier Rojo, Humberto O. Stumpf, Rute C. Figueiredo, Rodrigo S. Corrêa|2019|Inorg.Chim.Acta|489|93|doi:10.1016/j.ica.2019.02.010
CCDC 1811038: Experimental Crystal Structure Determination
Related Article: Leonardo C. Moraes, Gilmar P. de Souza, Humberto V. Fajardo, Sulusmon C. Luz, Eleuterio Álvarez, Francesc Lloret, Renato M. Ribeiro-Viana, Javier Rojo, Humberto O. Stumpf, Rute C. Figueiredo, Rodrigo S. Corrêa|2019|Inorg.Chim.Acta|489|93|doi:10.1016/j.ica.2019.02.010