Quasielastic neutron scattering study of dynamics at the crossover from dilute to semidilute behavior in polymer solutions

Dynamics at the Temperature Crossover in Dilute Polymer Solutions Investigated by Neutron Spin-Echo Spectroscopy

Applying ultrahigh-resolution neutron spin-echo spectroscopy the existence of a $q$-dependent temperature crossover in the dynamics of dilute polymer solutions was proved. It is associated with the transition from $\ensuremath{\theta}$ to good solvent conditions. At small momentum transfers $q$ a nearly stepwise increase of the reduced quasielastic linewidth versus the reduced temperature was observed. With increasing $q$, both the sharpness of the transition and the step height decrease.

Richteret al.Respond

Dynamical Scaling in Polymer Solutions Investigated by the Neutron Spin-Echo Technique

Chain dynamics in polymer solutions was investigated by means of the recently developed neutron spin echo spectroscopy. — By this technique, it was possible for the first time to verify unambiguously the scaling predictions of the Zimm model in the case of single chain behaviour and to observe the cross over to many chain behaviour. The segmental diffusion of single chains exhibits deviations from a simple exponential law, indicating the importance of memory effects. Mit Hilfe der erst kurzlich entwickelten Neutronen-Spin-Echo-Spektroskopie wurde die Kettendynamik von Polymermolekulen im gelosten Zustand untersucht. - Die Methode eroffnete die Moglichkeit, zum ersten Mal fur das Einzelkette…