Author: Alexander Yu. Mitrofanov

0000000000049513

AUTHOR

Alexander Yu. Mitrofanov

showing 14 related works from this author

Front Cover: Facile Synthesis and Self‐Assembly of Zinc (2‐Diethoxyphosphorylethynyl)porphyrins (Eur. J. Inorg. Chem. 10/2019)

2019

Inorganic ChemistryFront coverChemistryPolymer chemistrychemistry.chemical_elementZincSelf-assemblyEuropean Journal of Inorganic Chemistry

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Immobilization of copper complexes with (1,10-phenanthrolinyl)phosphonates on titania supports for sustainable catalysis

2017

Different strategies for the immobilization of copper complexes with 1,10-phenanthroline (phen) using the phosphonate anchoring group were investigated to prepare robust and porous heterogeneous catalysts. Homoleptic and heteroleptic copper(I) complexes with phen bearing the bis(trimethylsiloxy)phosphoryl anchoring group (Pphen-Si) at different positions of the phen backbone were prepared and covalently incorporated into titania (TiO2) xerogels by using the sol–gel process or grafted onto the surface of mesoporous TiO2 (SBET = 650 m2 g−1). Copper(I) bis(Pphen-Si) complexes were the only complexes that were successfully anchored onto the TiO2 surface because the heterogenization was often ac…

Materials science010405 organic chemistryRenewable Energy Sustainability and the EnvironmentInorganic chemistrychemistry.chemical_elementGeneral Chemistry010402 general chemistry01 natural sciencesCopper0104 chemical sciencesCatalysischemistry.chemical_compoundchemistryTransition metalPolymer chemistry[CHIM]Chemical SciencesGeneral Materials ScienceChelationHomolepticMesoporous materialHybrid materialComputingMilieux_MISCELLANEOUSBET theory

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Supramolecular Architectures Based on Phosphonic Acid Diesters

2014

The interest of phosphonic acid dialkyl esters for generation of metal-organic materials is discussed using derivatives of porphyrin and 1,10-phenanthroline series as representative examples.

010405 organic chemistryCoordination polymerOrganic ChemistrySupramolecular chemistry010402 general chemistry01 natural sciencesBiochemistryCombinatorial chemistryPorphyrin0104 chemical sciencesSupramolecular assemblyInorganic Chemistrychemistry.chemical_compoundchemistry[CHIM]Chemical SciencesOrganic chemistryComputingMilieux_MISCELLANEOUSPhosphorus, Sulfur, and Silicon and the Related Elements

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Copper( ii ) complexes with phosphorylated 1,10-phenanthrolines: from molecules to infinite supramolecular arrays

2016

International audience; The reaction of phosphorylated 1,10-phenanthrolines 3-Pphen, 3,8-Pphen and 4,7-Pphen (3-Pphen = 3-diethoxyphosphorylphenanthroline, 3,8-Pphen = 3,8-bis(diethoxyphosphoryl) phenanthroline, 4,7-Pphen = 4,7-bis(diethoxyphosphoryl) phenanthroline) and hydrated copper(II) nitrate in a 1 : 1 ratio leads to the formation of supramolecular architectures. In the 1D coordination polymer [Cu(3-Pphen)(NO3)(2)](n) (2) the copper atom is coordinated to only one phenanthroline ligand and the coordination sphere is completed by two oxygen atoms of nitrate anions and the oxygen atom of the phosphoryl group from the neighbouring phenanthroline ligand. Complex Cu(3,8-Pphen)(NO3)(2) (3)…

constructionCoordination sphereStereochemistryCoordination polymerPhenanthrolinebidentate ligandsdesignSupramolecular chemistryEtherCrystal structuremagnetic-properties010402 general chemistrychemistry01 natural sciences[ CHIM ] Chemical SciencesCatalysischemistry.chemical_compoundMaterials Chemistry[CHIM]Chemical Sciencesmetal-organic frameworks010405 organic chemistryLigandChemistrycrystal-structureGeneral Chemistryself-organization0104 chemical sciences3. Good healthtransition-metalCrystallographycoordination polymersMetal-organic framework

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Facile Synthesis and Self‐Assembly of Zinc (2‐Diethoxyphosphorylethynyl)porphyrins

2019

Inorganic Chemistrychemistrychemistry.chemical_elementHomogeneous catalysisZincSelf-assemblyCombinatorial chemistryEuropean Journal of Inorganic Chemistry

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CCDC 960835: Experimental Crystal Structure Determination

2016

Related Article: Alexander Yu. Mitrofanov, Yoann Rousselin, Roger Guilard, Stéphane Brandès, Alla G. Bessmertnykh-Lemeune, Marina A. Uvarova, Sergey E. Nefedov|2016|New J.Chem.|40|5896|doi:10.1039/C5NJ03572D

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[(mu-diethyl 110-phenanthrolin-3-ylphosphonate)-dinitrato-copper]Cell ParametersExperimental 3D Coordinates

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CCDC 1049575: Experimental Crystal Structure Determination

2016

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[(mu2-38-bis(Diethoxyphosphoryl)-110-phenanthroline)-(nitrato-O)-(nitrato-OO')-copper]Experimental 3D Coordinates

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CCDC 1850850: Experimental Crystal Structure Determination

2019

Related Article: Alexander Yu. Mitrofanov, Yoann Rousselin, Victor N Khrustalev, Andey V. Cheprakov, Alla Lemeune, Irina P. Beletskaya|2019|Eur.J.Inorg.Chem.|2019|1313|doi:10.1002/ejic.201900004

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-((mu-diethyl [(1020-diphenylporphyrin-5-yl)ethynyl]phosphonate)-zinc(ii))

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CCDC 1822340: Experimental Crystal Structure Determination

2019

Related Article: Alexander Yu. Mitrofanov, Yoann Rousselin, Victor N Khrustalev, Andey V. Cheprakov, Alla Lemeune, Irina P. Beletskaya|2019|Eur.J.Inorg.Chem.|2019|1313|doi:10.1002/ejic.201900004

Space GroupCrystallographyCrystal SystemCrystal Structurebis[mu-diethyl {[101520-tris(4-methylphenyl)porphyrin-5-yl]ethynyl}phosphonatato]-di-zinc(ii) chloroform solvateCell ParametersExperimental 3D Coordinates

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CCDC 1567139: Experimental Crystal Structure Determination

2019

Related Article: Alexander Yu. Mitrofanov, Yoann Rousselin, Victor N Khrustalev, Andey V. Cheprakov, Alla Lemeune, Irina P. Beletskaya|2019|Eur.J.Inorg.Chem.|2019|1313|doi:10.1002/ejic.201900004

bis[mu-diethyl {[101520-tris(4-methylphenyl)porphyrin-5-yl]ethynyl}phosphonatato]-di-zinc(ii) toluene solvateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

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CCDC 1009948: Experimental Crystal Structure Determination

2016

Space GroupCrystallographybis(mu-tetraethyl 110-phenanthroline-38-diylbis(phosphonate))-tetrakis(nitrato)-di-copper(ii)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

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CCDC 960834: Experimental Crystal Structure Determination

2016

Space GroupCrystallographyaqua-bis(diethyl 110-phenanthrolin-3-ylphosphonate)-(nitrato)-copper(ii) nitrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates

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CCDC 1009991: Experimental Crystal Structure Determination

2016

Space GroupCrystallographyCrystal Systembis(mu-tetraethyl 110-phenanthroline-47-diylbis(phosphonate))-tetrakis(nitrato)-di-copper(ii)Crystal StructureCell ParametersExperimental 3D Coordinates

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CCDC 1819713: Experimental Crystal Structure Determination

2019

Related Article: Alexander Yu. Mitrofanov, Yoann Rousselin, Victor N Khrustalev, Andey V. Cheprakov, Alla Lemeune, Irina P. Beletskaya|2019|Eur.J.Inorg.Chem.|2019|1313|doi:10.1002/ejic.201900004

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis[mu-diethyl ({1020-bis(4-cyanophenyl)-15-[(diethoxyphosphoryl)ethynyl]porphyrin-5-yl}ethynyl)phosphonatato]-di-zinc(ii) dichloromethane solvateExperimental 3D Coordinates

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