0000000000065185

AUTHOR

Maxim L. Kuznetsov

0000-0001-5729-6189

showing 18 related works from this author

Coupling of Azomethine Ylides with Nitrilium Derivatives ofcloso-Decaborate Clusters: A Synthetic and Theoretical Study

2012

The azomethine ylides p-R3C5H4N+CH−COC6H4R2-p (3 a: R3=H, R2=H, X=Br; 3 b: R3=H, R2=Me, X=I; 3 c: R3=H, R2=OMe, X=I; 3 d: R3=H, R2=F, X=I; 3 e: R3=Me, R2=Me, X=Br) react with the nitrile functionality of the closo-decaborate clusters [Bun4N][B10H9(NCR1)] (1 a: R1=Me; 1 b: R1=Et; 1 c: R1=Ph) in a CH3NO2 solution under mild conditions (20–25 °C, 2 min) to afford selectively products of the nucleophilic addition (ca. quantitative yields based on NMR analysis in [D6]DMSO, 71–87 % yield of isolated products). These products are the borylated enamino ketones as the salts bearing exclusively a tetrabutylammonium cation [Bun4N][B10H9{NCR1=C(N+C5H4R3-p)COC6H4R2-p}] (4 a–h,k–n) or the mixed salts [Bu…

Nucleophilic additionNitrileAzomethine ylideBoranesGeneral ChemistryPhotochemistryMedicinal chemistryCycloadditionchemistry.chemical_compoundchemistryNucleophilePyridiniumNitriliumta116ChemPlusChem
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Reaction between Indazole and Pd-Bound Isocyanides-A Theoretical Mechanistic Study

2018

The mechanism of the addition of indazole (Ind)&mdash

Models Molecular3003Activation of small moleculesIndazolesisocyanideIsocyanidePharmaceutical ScienceDFT calculationProtonation010402 general chemistryDFT calculationsactivation of small molecule01 natural sciencesMedicinal chemistryArticleAnalytical Chemistrylcsh:QD241-441chemistry.chemical_compoundDeprotonationNucleophilelcsh:Organic chemistryTheoreticalModelsDrug DiscoveryNitrilesPhysical and Theoretical ChemistryMechanical PhenomenaIndazoleNucleophilic additionCyanidesMolecular Structure010405 organic chemistrynitrileDrug Discovery3003 Pharmaceutical ScienceOrganic ChemistryRegioselectivityMolecularIsocyanidesModels TheoreticalTautomer0104 chemical sciencesnucleophilic additionchemistryChemistry (miscellaneous)Settore CHIM/03 - Chimica Generale E InorganicaMolecular Medicinereaction mechanismActivation of small molecules; DFT calculations; Isocyanides; Nitriles; Nucleophilic addition; Reaction mechanism; Cyanides; Indazoles; Models Molecular; Molecular Structure; Palladium; Mechanical Phenomena; Models Theoretical; Analytical Chemistry; Chemistry (miscellaneous); Molecular Medicine; 3003; Drug Discovery3003 Pharmaceutical Science; Physical and Theoretical Chemistry; Organic ChemistryPalladium
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Back Cover Picture: Coupling of Azomethine Ylides with Nitrilium Derivatives ofcloso-Decaborate Clusters: A Synthetic and Theoretical Study (ChemPlus…

2012

Couplingchemistry.chemical_compoundNucleophilic additionchemistryComputational chemistryCover (algebra)BoranesGeneral ChemistryNitriliumPhotochemistryCycloadditionChemPlusChem
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Anionic halide···alcohol clusters in the solid state.

2014

The cationic (1,3,5-triazapentadiene)Pt(II) complexes [1](Cl)2, [2](Cl)2, [3](Br)2, and [4](Cl)2, were crystallized from ROH-containing systems (R = Me, Et) providing alcohol solvates studied by X-ray diffraction. In the crystal structures of [1-4][(Hal)2(ROH)2] (R = Me, Et), the Hal(-) ion interacts with two or three cations [1-4](2+) by means of two or three or four contacts thus uniting stacked arrays of complexes into the layers. The solvated MeOH or EtOH molecules occupy vacant space, giving contacts with [1-4](2+), and connects to the Hal(-) ion through a hydrogen bridge via the H(1O)O(1S) H atom forming, by means of the Hal(-)···HOR (Hal = Cl, Br) contact, the halide-alcohol cluster.…

ChemistryStereochemistrySolid-stateCationic polymerizationHalideAlcoholCrystal structureIonchemistry.chemical_compoundCrystallographyCluster (physics)MoleculePhysical and Theoretical Chemistryta116The journal of physical chemistry. A
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Halogen Bonding Involving Palladium(II) as an XB Acceptor

2020

The half-lantern PdII2 complexes trans-(O,C)-[Pd(ppz)(μ-O∩N)]2 (1) and trans-(E,N)-[Pd(ppz)(μ-E∩N)]2 (E∩N is a deprotonated 2-substituted pyridine; E = S (2), Se (3); Hppz = 1-phenylpyrazole) were ...

Halogen bond010405 organic chemistrychemistry.chemical_elementGeneral Chemistry010402 general chemistryCondensed Matter Physics01 natural sciencesMedicinal chemistryAcceptor0104 chemical scienceschemistry.chemical_compoundDeprotonationchemistryPyridineGeneral Materials SciencePalladiumCrystal Growth & Design
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"Recognition of a Novel Type X=N-Hal•••Hal' (X = , S, P; Hal = F, Cl, Br, I) Halogen Bonding"

2013

The chlorination of the eight-membered platinum(II) chelates (PtCl2{NHC(NR2)N(Ph)C(NH)- N(Ph)C(NR2)NH}) (R = Me (1); R2 = (CH2)5 (2)) with uncomplexed imino group with Cl2 gives complexes bearing the N−Cl moiety (PtCl4{NHC(NR2)N(Ph)C(NCl)N- (Ph)C(NR2)NH}) (R = Me (3); R2 = (CH2)5 (4)). X-ray study for 3 revealed a novel type intermolecular halogen bonding N−Cl···Cl − , formed between the Cl atom of the chlorinated imine and the chloride bound to the platinum(IV) center. The processing relevant structural data retrieved from the Cambridge Structural Database (CSDB) shows that this type of halogen bonding is realized in 18 more molecular species having XN−Hal moieties (X = C, P, S, V…

Halogen bondStereochemistryImineIntermolecular forceCenter (category theory)chemistry.chemical_elementMedicinal chemistrychemistry.chemical_compoundchemistryMoietyChelationDensity functional theoryPhysical and Theoretical ChemistryPlatinumta116The Journal of Physical Chemistry A
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CCDC 2040618: Experimental Crystal Structure Determination

2020

Related Article: Eugene A. Katlenok, Anton V. Rozhkov, Oleg V. Levin, Matti Haukka, Maxim L. Kuznetsov, Vadim Yu. Kukushkin|2021|Cryst.Growth Des.|21|1159|doi:10.1021/acs.cgd.0c01474

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-pyridin-2-olato)-bis[2-(1H-pyrazol-1-yl)phenyl]-di-palladium(ii) 1245-tetrafluoro-36-diiodobenzene unknown solvateExperimental 3D Coordinates
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CCDC 1009523: Experimental Crystal Structure Determination

2015

Related Article: Pavel V. Gushchin, Maxim L. Kuznetsov, Matti Haukka, and Vadim Yu. Kukushkin|2014|J.Phys.Chem.A|118|9529|doi:10.1021/jp506256a

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(N-phenyl-N-(N'-phenylcarbamimidoyl)morpholine-4-carboximidamide)-platinum(ii) dichloride ethanol solvateExperimental 3D Coordinates
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CCDC 1009524: Experimental Crystal Structure Determination

2015

Related Article: Pavel V. Gushchin, Maxim L. Kuznetsov, Matti Haukka, and Vadim Yu. Kukushkin|2014|J.Phys.Chem.A|118|9529|doi:10.1021/jp506256a

Space GroupCrystallographyCrystal Systembis(N-phenyl-N-(N'-phenylcarbamimidoyl-kappaN')piperidine-1-carboximidamide)-platinum(ii) dibromide methanol solvateCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2040622: Experimental Crystal Structure Determination

2020

Related Article: Eugene A. Katlenok, Anton V. Rozhkov, Oleg V. Levin, Matti Haukka, Maxim L. Kuznetsov, Vadim Yu. Kukushkin|2021|Cryst.Growth Des.|21|1159|doi:10.1021/acs.cgd.0c01474

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-pyridine-2-selenolato)-bis[2-(1H-pyrazol-1-yl)phenyl]-di-palladium(ii)Experimental 3D Coordinates
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CCDC 2040620: Experimental Crystal Structure Determination

2020

Related Article: Eugene A. Katlenok, Anton V. Rozhkov, Oleg V. Levin, Matti Haukka, Maxim L. Kuznetsov, Vadim Yu. Kukushkin|2021|Cryst.Growth Des.|21|1159|doi:10.1021/acs.cgd.0c01474

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatesbis(mu-pyridine-2-thiolato)-bis[2-(1H-pyrazol-1-yl)phenyl]-di-palladium(ii) dichloromethane solvate
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CCDC 1009520: Experimental Crystal Structure Determination

2015

Related Article: Pavel V. Gushchin, Maxim L. Kuznetsov, Matti Haukka, and Vadim Yu. Kukushkin|2014|J.Phys.Chem.A|118|9529|doi:10.1021/jp506256a

Space GroupCrystallographybis(NN-dimethyl-NN''-diphenylimidodicarbonimidic diamide)-platinum(ii) dichloride ethanol solvateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1009521: Experimental Crystal Structure Determination

2015

Related Article: Pavel V. Gushchin, Maxim L. Kuznetsov, Matti Haukka, and Vadim Yu. Kukushkin|2014|J.Phys.Chem.A|118|9529|doi:10.1021/jp506256a

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(NN-diethyl-NN''-diphenylimidodicarbonimidic diamide)-platinum(ii) dichloride methanol solvateExperimental 3D Coordinates
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CCDC 1009522: Experimental Crystal Structure Determination

2015

Related Article: Pavel V. Gushchin, Maxim L. Kuznetsov, Matti Haukka, and Vadim Yu. Kukushkin|2014|J.Phys.Chem.A|118|9529|doi:10.1021/jp506256a

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(N-phenyl-N-(N'-phenylcarbamimidoyl)morpholine-4-carboximidamide)-platinum(ii) dichloride methanol solvateExperimental 3D Coordinates
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CCDC 2040617: Experimental Crystal Structure Determination

2020

Related Article: Eugene A. Katlenok, Anton V. Rozhkov, Oleg V. Levin, Matti Haukka, Maxim L. Kuznetsov, Vadim Yu. Kukushkin|2021|Cryst.Growth Des.|21|1159|doi:10.1021/acs.cgd.0c01474

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-pyridin-2-olato)-bis[2-(1H-pyrazol-1-yl)phenyl]-di-palladium(ii) unknown solvateExperimental 3D Coordinates
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CCDC 2040619: Experimental Crystal Structure Determination

2020

Related Article: Eugene A. Katlenok, Anton V. Rozhkov, Oleg V. Levin, Matti Haukka, Maxim L. Kuznetsov, Vadim Yu. Kukushkin|2021|Cryst.Growth Des.|21|1159|doi:10.1021/acs.cgd.0c01474

Space GroupCrystallographybis(mu-pyridine-2-thiolato)-bis[2-(1H-pyrazol-1-yl)phenyl]-di-palladium(ii) bis(1245-tetrafluoro-36-diiodobenzene)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 2040621: Experimental Crystal Structure Determination

2020

Related Article: Eugene A. Katlenok, Anton V. Rozhkov, Oleg V. Levin, Matti Haukka, Maxim L. Kuznetsov, Vadim Yu. Kukushkin|2021|Cryst.Growth Des.|21|1159|doi:10.1021/acs.cgd.0c01474

Space GroupCrystallographybis(mu-pyridine-2-selenolato)-bis[2-(1H-pyrazol-1-yl)phenyl]-di-palladium(ii) bis(1245-tetrafluoro-36-diiodobenzene)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1009519: Experimental Crystal Structure Determination

2015

Related Article: Pavel V. Gushchin, Maxim L. Kuznetsov, Matti Haukka, and Vadim Yu. Kukushkin|2014|J.Phys.Chem.A|118|9529|doi:10.1021/jp506256a

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(NN-dimethyl-NN''-diphenylimidodicarbonimidic diamide)-platinum(ii) dichloride methanol solvateExperimental 3D Coordinates
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