0000000000076533

AUTHOR

Antonio Martín

showing 2 related works from this author

Aportaciones a la flora de Extremadura (España)

2002

New records on the flora of Extremadura (Spain).Palabras clave. Cormofitos, flora, Caceres, Badajoz.Key words. Cormophyta, flora, Caceres, Badajoz.

Pulmonary and Respiratory MedicineFloraGeographyPediatrics Perinatology and Child HealthArchaeology
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Highly Luminescent Half-Lantern Cyclometalated Platinum(II) Complex: Synthesis, Structure, Luminescence Studies, and Reactivity.

2012

The half-lantern compound [{Pt(bzq)(μ-C 7H 4NS 2-κN,S)} 2]•Me 2CO (1) was obtained by reaction of equimolar amounts of potassium 2-mercaptobenzothiazolate (KC 7H 4NS 2) and [Pt(bzq)(NCMe) 2]ClO 4. The Pt(II)•••Pt(II) separation in the neutral complex [{Pt(bzq)(μ-C 7H 4NS 2-κN,S)} 2] is 2.910 (2) Å, this being among the shortest observed in half-lantern divalent platinum complexes. Within the complex, the benzo[h]quinoline (bzq) groups lie in close proximity with most C•••C distances being between 3.3 and 3.7 Å, which is indicative of significant π-π interactions. The reaction of 1 with halogens X 2 (X 2 = Cl 2, Br 2, or I 2) proceeds with a two-electron oxidation to give the corresponding d…

chemistry.chemical_classificationStereochemistryQuinolinechemistry.chemical_elementBridging ligandDivalentInorganic ChemistryCrystallographychemistry.chemical_compoundchemistryHalogenReactivity (chemistry)Physical and Theoretical ChemistryPlatinumLuminescenceInorganic Chemistry
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