0000000000082212
AUTHOR
J. Knuutinen
Gas chromatographic study of acetyl derivates of chlorinated guaiacols
The gas chromatography of acetyl derivatives of guaiacol and all chlorinated guaiacols has been studied on SE-30, OV-351 and Carbowax 20M capillary columns. The retention order and relative retention times under isotermal and temperature-programmed conditions are discussed. Different retention times for all mono- and dichloro compounds have been observed on the SE-30 column. However, all trichloroguaiacol isomers were separated only on polar columns. The best overall temperature-programmed separations have been achieved on an SE-30 capillary column.
Multiple linear regression analysis of RF values of chlorinated catechols and guaiacols
The multiple linear regression analysis of the RF values of chlorinated catechols and guaiacols has been carried out. The resolved terms, in the regression equation have been used to explain the relative mobility of chlorinated compounds to the reference compound (catechol or guaiacol). The best correlations have been observed for solvent systems which give the greatest standard deviations and relative differences between the RF values. A good correlation between the standard deviation of the RF values and the term which represents the effect of the chlorine atom ortho to the hydroxyl group(s) have also been observed.