0000000000089928
AUTHOR
Krzysztof Hermanowicz
The structural, phonon and optical properties of [CH3NH3]M0.5CrxAl0.5−x(HCOO)3 (M = Na, K; x = 0, 0.025, 0.5) metal–organic framework perovskites for luminescence thermometry
We report the structural, phonon and luminescence studies of six heterometallic perovskite-type metal–organic frameworks (MOFs) templated by methylammonium cations (CH3NH3+ and MeA+) with the following formulae: [MeA]Na0.5Cr0.5(HCOO)3 (MeANaCr), [MeA]K0.5Cr0.5(HCOO)3 (MeAKCr), [MeA]Na0.5Al0.5(HCOO)3 (MeANaAl), [MeA]K0.5Al0.5(HCOO)3 (MeAKAl), [MeA]Na0.5Cr0.025Al0.475(HCOO)3 (MeANaAlCr, 5 mol% of Cr3+ ions) and [MeA]K0.5Cr0.025Al0.475(HCOO)3 (MeAKAlCr, 5 mol% of Cr3+ ions). All of them crystallise in a monoclinic system (P21/n space group) with one MeA+ cation in an asymmetric unit forming four medium-strength hydrogen bonds (HBs) with a metal-formate framework. The DSC measurements and XRD s…
CCDC 1847383: Experimental Crystal Structure Determination
Related Article: Maciej Ptak, Błażej Dziuk, Dagmara Stefańska, Krzysztof Hermanowicz|2019|Phys.Chem.Chem.Phys.(PCCP)|21|7965|doi:10.1039/C9CP01043B
CCDC 1847385: Experimental Crystal Structure Determination
Related Article: Maciej Ptak, Błażej Dziuk, Dagmara Stefańska, Krzysztof Hermanowicz|2019|Phys.Chem.Chem.Phys.(PCCP)|21|7965|doi:10.1039/C9CP01043B
CCDC 1836882: Experimental Crystal Structure Determination
Related Article: Maciej Ptak, Błażej Dziuk, Dagmara Stefańska, Krzysztof Hermanowicz|2019|Phys.Chem.Chem.Phys.(PCCP)|21|7965|doi:10.1039/C9CP01043B
CCDC 1836883: Experimental Crystal Structure Determination
Related Article: Maciej Ptak, Błażej Dziuk, Dagmara Stefańska, Krzysztof Hermanowicz|2019|Phys.Chem.Chem.Phys.(PCCP)|21|7965|doi:10.1039/C9CP01043B
CCDC 1836884: Experimental Crystal Structure Determination
Related Article: Maciej Ptak, Błażej Dziuk, Dagmara Stefańska, Krzysztof Hermanowicz|2019|Phys.Chem.Chem.Phys.(PCCP)|21|7965|doi:10.1039/C9CP01043B
CCDC 1836885: Experimental Crystal Structure Determination
Related Article: Maciej Ptak, Błażej Dziuk, Dagmara Stefańska, Krzysztof Hermanowicz|2019|Phys.Chem.Chem.Phys.(PCCP)|21|7965|doi:10.1039/C9CP01043B
CCDC 1847386: Experimental Crystal Structure Determination
Related Article: Maciej Ptak, Błażej Dziuk, Dagmara Stefańska, Krzysztof Hermanowicz|2019|Phys.Chem.Chem.Phys.(PCCP)|21|7965|doi:10.1039/C9CP01043B
CCDC 1847384: Experimental Crystal Structure Determination
Related Article: Maciej Ptak, Błażej Dziuk, Dagmara Stefańska, Krzysztof Hermanowicz|2019|Phys.Chem.Chem.Phys.(PCCP)|21|7965|doi:10.1039/C9CP01043B