0000000000117348

AUTHOR

Christoph Gamer

showing 11 related works from this author

A SIM-MOF: Three-Dimensional Organisation of Single-Ion Magnets with Anion-Exchange Capabilities

2014

The formation of a metal-organic framework (MOF) with nodes that have single-molecule magnet (SMM) behaviour has been achieved by using mononuclear lanthanoid analogues, also known as single-ion magnets (SIMs), which enormously simplifies the challenging issue of making SMM-MOFs. Here we present a rational design of a family of MOFs, [Ln(bipyNO)4](TfO)3⋅x solvent (Ln=Tb (1); Dy (2); Ho (3); Er (4); TfO=triflate), in which the lanthanoid centres have an square-antiprismatic coordination environment suitable for SIM behaviour. Magnetic measurements confirm the existence of slow magnetic relaxation typical of SMMs, which has been rationalised by means of a radial effective charge model. In add…

LanthanideSingle ionIon exchangeChemistryOrganic ChemistryRational designNanotechnologyGeneral ChemistryCatalysisEffective nuclear chargeCrystallographyMagnetMetal-organic frameworkTrifluoromethanesulfonateChemistry - A European Journal
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Metallacrown Complexes Reaching the Nanosize Regime

2018

Abstract The chapter discusses the merit of metallacrown complexes to achieve multifunctional and multidimensional molecular materials. It introduces basic design strategies for discrete metallacrown complexes and discusses the predictability of molecular properties. Thereafter, it reviews two of the most outstanding molecular properties of metallacrown complexes, namely, the magnetic and luminescence characteristics. Most interestingly, for metallacrown complexes, such properties could be combined in one single molecule, giving rise to stable “multifunctional” molecular materials. Moreover, MCs are suitable building blocks to construct multidimensional coordination polymers. The chapter pr…

chemistry.chemical_classificationMaterials sciencechemistryComputational chemistryMoleculePolymerMolecular materialsMetallacrown
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Inside Cover: A SIM-MOF: Three-Dimensional Organisation of Single-Ion Magnets with Anion-Exchange Capabilities (Chem. Eur. J. 34/2014)

2014

Single ionIon exchangeChemistryMagnetOrganic ChemistryInorganic chemistryMetal-organic frameworkCover (algebra)General ChemistryCatalysisChemistry - A European Journal
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CCDC 987661: Experimental Crystal Structure Determination

2014

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(tetracosakis(mu2-44'-Bipyridine-NN'-dioxide)-hexa-erbium hexakis((mu6-oxo)-dodecakis(mu2-oxo)-hexaoxo-hexa-molybdenum) hexakis(trifluoromethanesulfonate) octahydrate)Experimental 3D Coordinates
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CCDC 987659: Experimental Crystal Structure Determination

2014

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetracosakis(mu-44'-bypyridyl-NN'-dioxide)-hexa-dysprosium hexakis(trifluoromethanesulfonate) hexakis(tridecakis(mu-oxo)-hexaoxo-hexa-molybdenum) icosahydrate]Experimental 3D Coordinates
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CCDC 987658: Experimental Crystal Structure Determination

2014

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

Space GroupCrystallographyTri-terbium tris((mu6-oxo)-dodecakis(mu2-oxo)-hexaoxo-hexa-molybdenum) tris(trifluoromethanesulfonate) dodecakis(44'-bipyridinium-11'-diolate) hydrateCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 987660: Experimental Crystal Structure Determination

2014

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetracosakis(mu-44'-bypyridyl-NN'-dioxide)-hexa-holmium hexakis(trifluoromethanesulfonate) hexakis(tridecakis(mu-oxo)-hexaoxo-hexa-molybdenum) icosahydrate]Experimental 3D Coordinates
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CCDC 987656: Experimental Crystal Structure Determination

2014

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

catena-[tetracosakis(mu~2~-44'-Bipyridine 11'-dioxide)-hexa-holmium(iii) octadecakis(trifluoromethanesulfonate) unknown solvate hexahydrate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 987655: Experimental Crystal Structure Determination

2014

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

catena-[tetracosakis(mu~2~-44'-Bipyridine 11'-dioxide)-hexa-dysprosium(iii) octadecakis(trifluoromethanesulfonate) unknown solvate decahydrate]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 987657: Experimental Crystal Structure Determination

2014

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetracosakis(mu~2~-44'-Bipyridine 11'-dioxide)-hexa-erbium(iii) octadecakis(trifluoromethanesulfonate) unknown solvate hexahydrate]Experimental 3D Coordinates
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CCDC 987654: Experimental Crystal Structure Determination

2014

Related Article: José J. Baldoví, Eugenio Coronado, Alejandro Gaita-Ariño, Christoph Gamer, Mónica Giménez-Marqués, Guillermo Mínguez Espallargas|2014|Chem.-Eur.J.|20|10695|doi:10.1002/chem.201402255

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetracosakis(mu2-44'-Bipyridine 11'-dioxide)-hexa-terbium(iii) octadeca(trifluoromethanesulfonate) methanol solvate hydrate]Experimental 3D Coordinates
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