0000000000132883
AUTHOR
Norbert Clauer
Chemical variations in clay minerals of the Archaean Barberton Greenstone Belt (South Africa)
Abstract Four rock profiles of shales, carbonates and greywacke-type sediments were sampled from the mafic compositional influenced sedimentary Fig Tree Group and from overlying, more felsic related, sedimentary Moodies Group of the Archaean Barberton Greenstone Belt in South Africa. Clay separates of forty sedimentary rocks were examined by XRD and SEM to study the mineralogical, chemical and morphological variations of the constitutive illite and chlorite. The clay minerals showed a significant K-enrichment in the illites and Mg- and Fe-depletions in the chlorites upwards the stratigraphic sequence. Three independent parameters influenced these variations: (1) a change in the origin of th…
Sm–Nd, Rb–Sr and Pb–Pb dating of silicic carbonates from the early Archaean Barberton Greenstone Belt, South Africa
Abstract Two silicic carbonate sequences occurring in the Onverwacht Group (OG) and the overlying Fig Tree Group (FTG) of the early Archaean Barberton Greenstone Belt, South Africa, contain silicified dolomites with primary structures and textures. They occur with volcanic rocks dated by single zircons. The associated Onverwacht felsic volcanics have an age of ∼3440–3416 Ma, whereas the Fig Tree volcanics are ∼3225 Ma old. Therefore, the depositional age of both sequences is between 3440 and 3225 Ma. Pb-isotopic data for different parts of a single OG whole rock sample form a linear array corresponding to a Pb–Pb age of 2632±99 Ma. Sm–Nd and Rb–Sr isotopes were analysed in four whole rock s…
Characterization, provenance, and tectonic setting of Fig Tree greywackes from the Archaean Barberton Greenstone Belt, South Africa
Abstract In this study, mineralogical and geochemical data, as well as Sr and Nd isotopic compositions of early Archaean greywackes from the Fig Tree Group are presented to provide further information about the evolution of the Barberton Greenstone Belt (BGB) of the Kaapvaal Craton, South Africa. The chemical data on the collected greywackes from the BGB suggest limited chemical modification of the source rocks. The Eu/Eu * anomaly is negative with an average value of 0.76 which is slightly higher than that of Eu-depleted crustal rocks (0.65). High Cr and Ni concentrations and a Cr/Ni ratio of about 1.6 indicate derivation from ultramafic sources without fractionation. Although rounded zirc…
Structure-related geochemical (REE) and isotopic (K-Ar, Rb-Sr, δ18O) characteristics of clay minerals from Rotliegend sandstone reservoirs (Permian, northern Germany)
Abstract Euhedral illite cementing the gas-bearing sandstone reservoirs of the Rotliegend in the Niedersachsische rift system (northern Germany) was studied along a horst-to-graben cross-section to examine its chemical and isotopic characteristics. The data show that differentiated illite particles grew during a tectono-thermal event marked by distinct episodic hydrothermal activities along fault drains and in the poral space of sandstones at 210 Ma and at 195 to 190 Ma in horst positions, at 185 to 175 Ma in the nearby graben, and at 170 to 165 Ma in both the horst and graben. Varied REE distribution patterns and initial 87Sr/86Sr ratios (from 0.7124 to 0.7142) relative to illite-particle …
Pb–Pb age, stable isotope and chemical composition of Archaean magnesite, Barberton Greenstone Belt, South Africa
International audience; Trace-element, carbon, oxygen and lead-isotope analyses were carried out to determine the formation mode and crystallization age of magnesite from the Budd ultramafic complex of the Archaean Barberton Greenstone Belt, South Africa. Its significantly high Ti contents probably relate to a soluble Ti-rich accessory mineral, probably dissolved during magnesite precipitation. Primitive mantle-normalized REE patterns of the magnesite show negative Ce and Eu anomalies induced by two events: (1) the Eu anomaly indicates reducing conditions probably induced by the emplacement of the ultramafic source rock; (2) the Ce anomaly implies oxidizing conditions, probably during a hyd…
Strontium and argon isotopic homogenization of pelitic sediments during low-grade regional metamorphism: The pan-African upper Damara sequence of Northern Namibia (South West Africa)
Abstract The fine mineral fractions extracted from pelitic sediments of the Eocambrian upper Damaran Mulden Group were subjected to a detailed isotopic study by the Rb-Sr and K-Ar methods in combination with a mineralogical analysis by X-ray diffractometry. The sediments contain two major parageneses of metamorphic origin which can be related to two separate low-grade regional metamorphic events of anchizonal intensity with temperatures between 250 and 300°C and pressures up to 2 kbar. These events are dated at about 535 m.y. and 455 m.y. respectively (with λ( 87 Rb) = 1.42 × 10 −11 yr −1 ). Anomalously high K-Ar ages on samples from specific stratigraphic horizons can be related to open sy…
A Mineralogical, Chemical and Isotopic Investigation of Shales from the Barberton Greenstone Belt, South Africa, To Constrain Source Materials and Post-Deposition Evolution
Major, trace and rare-earth elements were determined, together with their Rb-Sr, Sm-Nd and Pb-Pb isotopic systems, on shales from the ~3.5 to 3.1 Ga old Barberton Greenstone Belt in South Africa, to constrain their source materials and post-depositional evolution, on the basis of successive potential alteration impacts. A progressive change in the chemical composition has been identified from a dominant ultramafic-mafic (such as a komatiite end-member) source for the Fig Tree Group to a progressively felsic-plutonic (such as a granite end-member) provenance for the Moodies Group. The SiO 2 , K 2 O, U, Rb, Ba, and Sr contents, and the Zr/Y ratio increase upwards the stratigraphy, while the M…
Dissolved silica in the Garonne River waters : changes in the weathering dynamics
The major ion chemistry of the Garonne River is indicative of seasonal variations in the weathering dynamics of the drainage basin. Using the geochemical model MEGA for calculation of the contribution of atmospheric CO2 to the total bicarbonate fluxes exported by the Garonne River allows estimations of the concentrations of the major dissolved elements that originate from silicate- and carbonate-rock weathering. The molecular ratio SiO2/Al2O3 was calculated for the 1989–1992 period to identify the main type of weathering in the Garonne River, and montmorillonite was shown to be the major mineral occurring in the weathering products. The seasonal variations of the SiO2/Al2O3 ratio also showe…
Influence of anthropogenic activity on the lead isotope signature of Thau Lake sediments (southern France): origin and temporal evolution
Lead concentrations and isotopic compositions were determined on both bulk sediments deposited in the Thau lake in southern France during the last 200 years, and leachates derived from a series of sequential leachings of the sediments, making it possible to identify the sources, natural (i.e. indigenous lithologic) or anthropogenic, and to quantify the different inputs of Pb. Two distinct inputs of Pb could be distinguished. One of these corresponds to the terrigenous material entering the basin, representative of the local natural Pb ‘background’. Its supply remained steady most of the time with 206Pb/207Pb ratios of 1.200±0.003, except at the time of heavy storms producing voluminous and …
Tracing the source of gypsum in New Caledonian soils by REE contents and SSr isotopic compositions
Gypsum minerals forming in pedogenic environments in New Caledonia were examined for their S and Sr isotope compositions and REE distributions. Three possible sources were identified: volcanic, soil-derived and marine. However, differentiation based only on the REE contents and normalized patterns was not possible, but, the best preserved volcanic sample yields a negative EuEu∗ anomaly and the lowest GdNYbN ratio due to the high content of organic matter. Mixing calculations of the δ34S values and 87Sr86Sr ratios confirmed that the marine gypsum has a δ34S value close to + 21‰ and an 87Sr86Sr ratio close to 0.70912, and that the volcanic gypsum has a δ34S value of 0‰ and an 87Sr86Sr ratio o…
Sequential leaching of silicified Archaean carbonates: A Rb-Sr, Sm-Nd and Pb-Pb isotopic contribution to their tectonic-thermal history (Kaapvaal Craton, South Africa)
Abstract Sequential leaching was completed by successive interactions of ultra-pure H2O, HAc, HCl and HNO3 with silicified/carbonated Archaean whole rocks from Barberton Greenstone belt of South Africa. The purpose of this experiment was an identification of the minerals interacting with each reagent and, therefore, a detailed succession of isotopically dated tectonic-thermal episodes recorded in these minerals. The contents of the major, trace and rare-earth elemental, together with the Sr, Nd and Pb isotopic compositions of untreated, leachate and residue triplets allowed identification and analysis of various types of carbonates and sulfates mixed with insoluble silicates. The samples yi…
Sm-Nd dating of Fig Tree clay minerals of the Barberton greenstone belt, South Africa.
Sm-Nd isotopic data from carbonate-derived clay minerals of the 3.22-3.25 Ga Fig Tree Group, Barberton greenstone belt, South Africa, form a linear array corresponding to an age of 3102 +/- 64 Ma, making these minerals the oldest dated clays on Earth. The obtained age is 120-160 m.y. younger than the depositional age determined by zircon geochronology. Nd model ages for the clays range from approximately 3.39 to 3.44 Ga and almost cover the age variation of the Barberton greenstone belt rocks, consistent with independent evidence that the clay minerals are derived from material of the belt. The combined isotopic and mineralogical data provide evidence for a cryptic thermal overprint in the …