0000000000137515
AUTHOR
Ceraulo M
THERMOMECHANICAL DEGRADATION OF A POLYPROPYLENE/GRAPHENE NANOCOMPOSITE
In this work the morphology and the rheological and mechanical properties of a nanocomposite made of a polypropylene with graphene nanoplatelets (GNP) have been investigated as a function of the compounding parameters to evaluate the thermomechanical degradation behaviour of this system. The presence of graphene seems to reduce the thermomechanical degradation of the matrix. A better dispersion of the GNP seems the cause of this behaviour.
Chlorides concentration and ph measurement of concrete structure through immersed sensors
The present work develops non-destructive measurements of chemical-physical parameters of concrete, in order to evaluate the degradation condition and to monitor, in time, the aging process. This study in particular focuses on the measurement of parameters such as pH, and therefore the carbonatation level of the concrete, and salt concentration (i.e. chlorides), and the evolution of these quantities with time. The analysis can be extended to other chemical-physical parameter of interests for which is provided a specific microsensor.
PREPARATION AND CHARACTERIZATION OF POLYLACTIC ACID/SILICA AND POLYLACTIC ACID/CLAYS BIONANOCOMPOSITE ELECTROSPUN SYSTEMS
Introduction Electrospinning is a versatile process technology for the production of fibers ranging from nano- to micro-scale. In order to develop high performance electrospun systems, the use of nanofillers is achieving more and more interest. In this context, silica (Si) and clays (Cl) are often used as fillers due to the possibility to combine the advantages of polymeric materials, such as light weight and flexibility, and inorganic materials, such as high mechanical strength, heat stability, and chemical stability. In this work, the morphology of PLA/Si and PLA/Cl were evaluated on two different weight ratios: 99/1 and 95/5 wt/wt. Material and Methods The nanoparticles were added to a s…
Photooxidation behaviour of LDPE/Clay nanocomposite measured through creep curves
The creep response of Polymer systems is typically investigated upon applying different loads, or under different temperature. However, no evidence exist of creep studies under different loads and temperatures and the simultaneos actionof accelerated weathering. In a previous paper La Mantia et al. [1] presented a new equipment that is able to subject polymer samples to creep under different loads, but also monitor the effect of photooxidation due to the temperature, humidity and UV irradiation, thus fully simulating the real operating conditions for polymer-based items. In tihs work a polyethylene/organomodified caly nanocompositehas been subjectedto combined creep-accelerated weathering c…