0000000000139440
AUTHOR
D. Stuerga
Microwave flash-synthesis of iron oxides nanoparticles
Hematite particles have been synthesized by a one step thermohydrolysis of nitrate iron (III) solutions. The microwave system (RAMO system) designed by the authors is able to induce very fast heating rates within an autoclave. These operating conditions induce precipitation reactions in the entire volume of the reactor. These precipitation conditions lead to instantaneous nucleation of monodisperse particles (separation of the nucleation and growth events). These results indicate that it should be possible to produce very well-crystallized hematite particles which can be used as precursors for production of magnetite or maghemite.
Studies on Instabilities and Patterns in Evaporating Liquids at Reduced Pressure and/or Microwave Irradiation
This paper summarizes our recent experimental and theoretical work on the instabilities in liquids and at interfaces which form during evaporation at reduced pressure and/or microwave irradiation. We have observed a variety of patterns (Benard rolls, Marangoni waves, Hickman interface deformations) which depend on the value of the reduced pressure and the power of the incident beam.
Microwave synthesis of yttria stabilized zirconia (YSZ)
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Microwave heating as a tool for coupling Marangoni and Hickman instabilities
The aim of this paper is the linear stability analysis of an evaporating interface in order to justify hydrodynamic behaviors observed during evaporation of water and ethanol simultaneously under microwave irradiation and reduced pressure. In relation to the local character of the thermal conversion of electromagnetic energy, and of the thermal dependency of the dielectric loss, it seems possible under microwave heating to induce a specific hydrodynamic compared to those induced by conventional heating.
Novel metallic iron/manganese-zinc ferrite nanocomposites prepared by microwave hydrothermal flash synthesis
8 Caillot, T. Pourroy, G. Stuerga, D.; Metallic iron (alpha-Fe)/manganese-zinc ferrite (Fe3-x-yMnxZnyO4) nanocomposites have been successfully synthesized for the first time using microwave hydrothermal treatment of alcoholic solutions of chloride precursors and sodium ethoxide. This new type of nanocomposites, never obtained by conventional synthesis, can now be produced in a short period (e.g. 15s). The powders were characterized by X-ray diffraction, transmission electron microscopy and magnetic properties were measured. In most cases, three classes of crystallites were observed; one of them is composed of grains of about 100 nm in size where the metal is inserted into the oxide. For all…
Densification of MnDoped Tin Oxide Films by Conventional Heating and Microwave Heating Treatment
Mn(II) doped SnO2 thin films used for shielding fluoride glasses against corrosion were investigated by x-ray absorption spectroscopy (EXAFS and XANE)S at the Sn and Mn K-edges. The effect of firing treatment on the densification of the films was studied. It has been evidenced a partial change of Mn valence from 2.3 to 2.6 upon heating which is attributed to a change of ratios of two Mn sites: grafted divalent Mn ions at the surface of SnO2 nanocrystallites and trivalent Mn ions embedded into a substitutional solid solution with Sn.
Microwave hydrothermal flash synthesis of nanocomposites Fe–Co alloy/cobalt ferrite
Abstract The present article presents, for the first time, the last developments reported for an original microwave hydrothermal flash synthesis of Fe–Co alloys (FeyCo1−y)/cobalt ferrite (Fe3−xCoxO4) nanocomposites. Synthesis was performed in alcoholic solutions of ferrous chloride, cobalt chloride and sodium ethoxide (EtONa) using a microwave autoclave (The RAMO system) specially designed by authors. Compared with conventional synthesis, smaller grains (100 nm compared to 1 μm) can be produced in a short period (e.g. 10 s) using a less basic medium. In all the cases, the microstructure and the amount of metal inside the composite particles are very different from the product obtained via a…