0000000000154583
AUTHOR
Cynthia Lopes Martins Pereira
Mononuclear lanthanide(III)-oxamate complexes as new photoluminescent field-induced single-molecule magnets: solid-state photophysical and magnetic properties.
Implementing additional optical (luminescent) properties into the well-known class of single-molecule magnets (SMMs) is considered as a promising route toward obtaining the next generation of optomagnetic materials for quantum information storage and computing. Herein, we report a joint optical and magneto-structural study for the two novel series of lanthanide(iii) complexes of general formula Bu4N[LnIII(HL)4(dmso)]·nH2O where H2L = N-(4-Xphenyl)oxamic acid with X = Cl and n = 2 [Ln = Eu (1_Cl), Gd (2_Cl), Dy (3_Cl), and Tb (4_Cl)] and X = F and n = 3 [Ln = Eu (1_F), Gd (2_F), Dy (3_F), and Tb (4_F)]. All these compounds are mononuclear species with each lanthanide(iii) cation in a low-sym…
CCDC 1580311: Experimental Crystal Structure Determination
Related Article: Julia Parreiras de Matos, Érica Neves de Faria, Willian Xerxes Coelho Oliveira, Walace Doti do Pim, Raquel Vieira Mambrini, Emerson Fernandes Pedroso, Miguel Julve, Cynthia Lopes Martins Pereira, Humberto Osório Stumpf|2018|J.Coord.Chem.|71|797|doi:10.1080/00958972.2018.1439162
CCDC 1580310: Experimental Crystal Structure Determination
Related Article: Julia Parreiras de Matos, Érica Neves de Faria, Willian Xerxes Coelho Oliveira, Walace Doti do Pim, Raquel Vieira Mambrini, Emerson Fernandes Pedroso, Miguel Julve, Cynthia Lopes Martins Pereira, Humberto Osório Stumpf|2018|J.Coord.Chem.|71|797|doi:10.1080/00958972.2018.1439162