0000000000162084
AUTHOR
Elena Gascón
Luminescent iminophosphorane gold, palladium and platinum complexes as potential anticancer agents
A series of coordination gold(III), palladium(II), and platinum(II) complexes with a luminescent iminophosphorane ligand derived from 8-aminoquinoline [Ph3P[double bond, length as m-dash]N–C9H6N] (1) have been synthesized and structurally characterized. The coordination palladium(II) and platinum(II) compounds can evolve further, under appropriate conditions, to give stable cyclometalated endo species [M{κ3-C,N,N-C6H4(PPh2[double bond, length as m-dash]N-8-C9H6N)}Cl] (M = Pd, Pt) by C–H activation of the phenyl group of the PPh3 fragment. Iminophosphorane 1 and the new metallic complexes are luminescent in DMSO or DMSO–H2O (1 : 1 mixture) solutions at RT. The compounds have been evaluated f…
CCDC 977990: Experimental Crystal Structure Determination
Related Article: Malgorzata Frik, Josefina Jiménez, Vadim Vasilevski, Monica Carreira, Andreia de Almeida, Elena Gascón, Farrah Benoit, Mercedes Sanaú, Angela Casini, María Contel|2014|Inorg.Chem.Front.|1|231|doi:10.1039/C4QI00003J
CCDC 977991: Experimental Crystal Structure Determination
Related Article: Malgorzata Frik, Josefina Jiménez, Vadim Vasilevski, Monica Carreira, Andreia de Almeida, Elena Gascón, Farrah Benoit, Mercedes Sanaú, Angela Casini, María Contel|2014|Inorg.Chem.Front.|1|231|doi:10.1039/C4QI00003J