0000000000165785
AUTHOR
Elizabeth V. Nunn
Sr/Ca and Mg/Ca ratios of ontogenetically old, long-lived bivalve shells (Arctica islandica) and their function as paleotemperature proxies
International audience; The Sr/Ca and Mg/Ca ratios of many biogenic skeletons provide useful paleotemperature estimates. As yet however, it has remained largely impossible to obtain such information from bivalve shells. In the present study, metal-to-calcium values in the hinge plate (aragonite, outer shell layer) of four ontogenetically old (85 to 374 year-old) specimens of the long-lived bivalve, Arctica islandica, were measured on a LA-ICP-MS. The shells were collected alive in 1868, 1986 and 2003 from three different localities around Iceland. With increasing ontogenetic age and decreasing growth rate, a distinct trend toward increasing Sr/Ca (max. 5.17 mmol/mol) and Mg/Ca values (max. …
Late Jurassic (Kimmeridgian–Tithonian) stable isotopes (δ18O, δ13C) and Mg/Ca ratios: New palaeoclimate data from Helmsdale, northeast Scotland
Abstract The data presented here provide the first detailed stable isotope ( δ 18 O, δ 13 C) and geochemical (Mg/Ca) investigation of Kimmeridgian–Tithonian belemnites from the Helmsdale Coast, Scotland, UK. Oxygen and carbon stable isotope values from well preserved specimens range from − 2.8 to + 0.3‰ and from − 2.3 to + 2.8‰ respectively. The oxygen isotope data are consistent with palaeotemperatures of up to 24 °C in the Early Kimmeridgian cymodoce Zone and down to 11 °C in the Mid Tithonian rotunda–fittoni Zones. These estimates are strongly supported by the Mg/Ca data, which also indicate a cooling episode (and very similar palaeotemperatures, 11–22 °C) at this time. The cooling event…
The Valanginian positive carbon isotope event in Arctic Russia: Evidence from terrestrial and marine isotope records and implications for global carbon cycling
The data presented here comprise Ryazanian–Valanginian carbon isotope ratios analyzed from fossil wood and belemnites from the shallow marine Boyarka River succession in Siberia. Additional belemnite carbon isotope ratios from the Izhma River succession (also Ryazanian–Valanginian) in Russia are also presented. The wood-derived and belemnite-derived isotope ratios are considered to primarily reflect changes in the terrestrial and marine carbon isotope reservoirs respectively. The δ13Ccarb and δ13Cwood records reveal a distinct mid-Valanginian positive carbon isotope excursion, with the initiation occurring near the Boreal Russian michalskii–polyptychus zone boundary, which is broadly time-e…
Isotopic signals from Callovian–Kimmeridgian (Middle–Upper Jurassic) belemnites and bulk organic carbon, Staffin Bay, Isle of Skye, Scotland
Abstract: The stable isotope data presented here significantly extend and expand upon previous isotopic investigations of the Middle to Late Jurassic interval. The belemnite samples collected from the Staffin Bay and Staffin Shale formations from the Isle of Skye, Scotland, yielded oxygen isotope values consistent with Callovian–Kimmeridgian palaeotemperatures of 6.7–20.6 °C. The carbon isotope data comprise one of the first moderately high-resolution investigations of the relationship between terrestrial δ 13 C org (predominantly fossil wood debris) and marine δ 13 C carb (belemnites) as derived from a geologically coeval record. The Staffin Bay data reveal a broad Early to Mid-Oxfordian p…
Valanginian isotope variation in glendonites and belemnites from Arctic Svalbard: Transient glacial temperatures during the Cretaceous greenhouse
Oxygen and carbon isotope data from Cretaceous (Valanginian) glendonites and belemnites from Arctic Svalbard are presented. Oxygen isotope data from well-preserved glendonites, in conjunction with the ikaite to glendonite pseudomorph transition temperature, are used to provide an estimate of the oxygen isotope composition of ambient seawater. Calculation of such a factor is essential for robust paleotemperature estimates. Using this methodology, our paleotemperatures calculated from the oxygen isotope compositions of coexisting belemnites yield cool temperatures (4–7 °C) consistent with transient glacial polar conditions during the Cretaceous greenhouse. Cool polar temperatures during the C…
Stable isotope (δ18O and δ13C) sclerochronology of Callovian (Middle Jurassic) bivalves (Gryphaea (Bilobissa) dilobotes) and belemnites (Cylindroteuthis puzosiana) from the Peterborough Member of the Oxford Clay Formation (Cambridgeshire, England): Evidence of palaeoclimate, water depth and belemnite behaviour
Abstract Incremental δ 18 O and δ 13 C signals were obtained from three well-preserved specimens of Cylindroteuthis puzosiana and from three well-preserved specimens of Gryphaea ( Bilobissa ) dilobotes from the Peterborough Member of the Oxford Clay Formation (Cambridgeshire, England). Through-ontogeny (sclerochronological) δ 18 O data from G. ( B. ) dilobotes appear to faithfully record seasonal temperature variations in benthic Callovian waters of the study area, which range from c . 14 °C to c . 17 °C (arithmetic mean temperature c . 15 °C). Water depth is estimated to have been in the region of c . 50 m, based upon comparisons between these data, previously published non-incremental sea…
Investigation of Li/Ca variations in aragonitic shells of the ocean quahogArctica islandica, northeast Iceland
Interannual and intra-annual variations in lithium-to-calcium ratio were investigated with high temporal resolution in the aragonitic outer shell layer of juvenile Arctica islandica (Mollusca; Bivalvia) collected alive in 2006 off northeast Iceland. Li/Ca shell ranged between 7.00 and 11.12 µmol mol -1 and presented well-marked seasonal cycles with minimum values recorded at the annual growth lines; a general pattern was a progressive increase in Li/Ca shell from March to May, followed by a plateau in June and a decrease down to minimum values in July-August. Li/Ca shell was correlated with d 18 O shell -derived temperature, but the strength of this relationship was weak ( r 2 p shell in A.…
Bioavailable 87Sr/86Sr in different environmental samples — Effects of anthropogenic contamination and implications for isoscapes in past migration studies
(87)Sr/(86)Sr reference maps (isoscapes) are a key tool for investigating past human and animal migrations. However, there is little understanding of which biosphere samples are best proxies for local bioavailable Sr when dealing with movements of past populations. In this study, biological and geological samples (ground vegetation, tree leaves, rock leachates, water, soil extracts, as well as modern and archeological animal teeth and snail shells) were collected in the vicinity of two early medieval cemeteries ("Thuringians", 5-6th century AD) in central Germany, in order to characterize (87)Sr/(86)Sr of the local biosphere. Animal tooth enamel is not appropriate in this specific context t…
Isotopic signals from Callovian–Kimmeridgian (Middle–Upper Jurassic) belemnites and bulk organic carbon, Staffin Bay, Isle of Skye, Scotland
The stable isotope data presented here significantly extend and expand upon previous isotopic investigations of the Middle to Late Jurassic interval. The belemnite samples collected from the Staffin Bay and Staffin Shale formations from the Isle of Skye, Scotland, yielded oxygen isotope values consistent with Callovian–Kimmeridgian palaeotemperatures of 6.7–20.6 °C. The carbon isotope data comprise one of the first moderately high-resolution investigations of the relationship between terrestrial δ13Corg (predominantly fossil wood debris) and marine δ13Ccarb (belemnites) as derived from a geologically coeval record. The Staffin Bay data reveal a broad Early to Mid-Oxfordian positive carbon i…