NMR and $��^{+}$SR detection of unconventional spin dynamics in Er(trensal) and Dy(trensal) molecular magnets

Measurements of proton Nuclear Magnetic Resonance (1H NMR) spectra and relaxation and of Muon Spin Relaxation ($��^{+}$SR) have been performed as a function of temperature and external magnetic field on two isostructural lanthanide complexes, Er(trensal) and Dy(trensal) featuring crystallographically imposed trigonal symmetry. Both the nuclear 1/T1 and muon $��$ longitudinal relaxation rates, LRR, exhibit a peak for temperatures T lower than 30K, associated to the slowing down of the spin dynamics, and the width of the NMR absorption spectra starts to increase significantly at T ca. 50K, a temperature sizably higher than the one of the LRR peaks. The LRR peaks have a field and temperature d…

NMR and μ+SR detection of unconventional spin dynamics in Er(trensal) and Dy(trensal) molecular magnets

CCDC 934656: Experimental Crystal Structure Determination

Related Article: E.Colacio,J.Ruiz,E.Ruiz,E.Cremades,J.Krzystek,S.Carretta,J.Cano,T.Guidi,W.Wernsdorfer,E.K.Brechin|2013|Angew.Chem.,Int.Ed.|52|9130|doi:10.1002/anie.201304386