An authentication case study: Antonio Palomino versus Vicente Guillo paintings in the vaulted ceiling of the Sant Joan del Mercat church (Valencia, Spain)
In 1695, the Valencian artist Vicente Guillo was engaged in painting the vault of the Sant Joan del Mercat church in Valencia, Spain. After preliminary work was carried out, his contract was cancelled. In 1697, Antonio Palomino, renowned for the publication of his technical treatise entitled El Museo Pictorio y Escala Optica, was finally selected as the painter in charge of decorating the vaulted ceiling of Sant Joan del Mercat. This paper reports an analytical study focused on the characterisation and discrimination of the palette and painting procedures used by Palomino and Guillo in the frescoes of Sant Joan del Mercat. For this purpose, Raman spectroscopy combined with light microscopy,…
Electrochemical analysis of the first Polish coins using voltammetry of immobilized particles
[EN] A series of 20 denarii from Boleslaus the Brave (992-1025) and Mieszko II Lambert (1025-1034), corresponding to the beginning of the Polish state were studied using the voltammetry of immobilized particles (VIMP) methodology. VIMP experiments, applied to nanosamples of the corrosion layers of the coins in contact with aqueous acetate buffer, provided well-defined responses mainly corresponding to the corrosion products of copper and lead. Such voltammetric responses, combined with X-ray fluorescence (XRF) spectroscopy experiments performed on the same set of coins, and complemented by focusing ion beam-field emission scanning electron microscope (FIB-FESEM) on silver coins from the 19t…