0000000000172837
AUTHOR
Snehasis Banerjee
showing 6 related works from this author
Magnetic Properties of End-to-End Azide-Bridged Tetranuclear Mixed-Valence Cobalt(III)/Cobalt(II) Complexes with Reduced Schiff Base Blocking Ligands…
2019
Two tetranuclear mixed-valence cobalt(III/II) complexes having the general formula [(μ1,3-N3){CoII(Ln)(μ-O2CC6H4NO2)CoIII(N3)}2]PF6 (where H2L1 and H2L2 are two reduced Schiff base ligands) have been synthesized and characterized. The structures of both complexes show cobalt(II) and cobalt(III) centers with a distorted octahedral geometry with cobalt(III) and cobalt(II) centers located at the inner N2O2 and outer O4 cavities of the reduced Schiff base ligands, respectively. The oxidation states of both cobalt centers have been confirmed by bond valence sum (BVS) calculations. The magnetic properties show that both compounds behave as cobalt(II) dimers connected through an end-to-end azido b…
Field-induced single molecule magnet behavior of a dinuclear cobalt(II) complex: a combined experimental and theoretical study.
2020
Two dinuclear cobalt(ii) complexes, [(dmso)CoIIL1(μ-(m-NO2)C6H4COO)CoII(NCS)] (1) and [(dmso)CoIIL2(μ-(m-NO2)C6H4COO)CoII(NCS)] (2) [dmso = dimethylsulfoxide, H2L1 = (2,2-dimethyl-1,3-propanediyl)bis(iminomethylene)bis(6-methoxyphenol) and H2L2 = (2,2-dimethyl-1,3-propanediyl)bis(iminomethylene)bis(6-ethoxyphenol)] have been synthesized and structurally characterized by single-crystal X-ray diffraction, magnetic-susceptibility measurements and various spectroscopic techniques. Each complex contains a cobalt(ii) center with a slightly distorted octahedral geometry and a second cobalt(ii) center with a distorted trigonal prismatic one. To obtain insight into the physical nature of weak non-co…
CCDC 1976309: Experimental Crystal Structure Determination
2020
Related Article: Abhisek Banerjee, Snehasis Banerjee, Carlos J. Gomez Garcia, Samia Benmansour Souilamas, Shouvik Chattopadhyay|2020|Dalton Trans.|49|16778|doi:10.1039/D0DT02158J
CCDC 1923203: Experimental Crystal Structure Determination
2020
Related Article: Abhisek Banerjee, Snehasis Banerjee, Carlos J. Gómez García, Samia Benmansour, Shouvik Chattopadhyay|2019|ACS Omega|4|20634|doi:10.1021/acsomega.9b02764
CCDC 1923202: Experimental Crystal Structure Determination
2020
Related Article: Abhisek Banerjee, Snehasis Banerjee, Carlos J. Gómez García, Samia Benmansour, Shouvik Chattopadhyay|2019|ACS Omega|4|20634|doi:10.1021/acsomega.9b02764
CCDC 1976308: Experimental Crystal Structure Determination
2020
Related Article: Abhisek Banerjee, Snehasis Banerjee, Carlos J. Gomez Garcia, Samia Benmansour Souilamas, Shouvik Chattopadhyay|2020|Dalton Trans.|49|16778|doi:10.1039/D0DT02158J