0000000000173552
AUTHOR
Olga S. Bokareva
Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(ii) complexes
Two closely related FeII complexes with 2,6-bis(1-ethyl-1H-1,2,3-triazol-4yl)pyridine and 2,6-bis(1,2,3-triazol-5-ylidene)pyridine ligands are presented to gain new insights into the photophysics of bis(tridentate) iron(II) complexes. The [Fe(N^N^N)2]2+ pseudoisomer sensitizes singlet oxygen through a MC state with nanosecond lifetime after MLCT excitation, while the bis(tridentate) [Fe(C^N^C)2]2+ pseudoisomer possesses a similar 3MLCT lifetime as the tris(bidentate) [Fe(C^C)2(N^N)]2+ complexes with four mesoionic carbenes. Financial support from the Deutsche Forschungsge-meinschaft [DFG, Priority Program SPP 2102] "Light-controlled reactivity of metal complexes" (BA 4467/7-1, LO 714/11-1, …
Ground- and Excited-State Properties of Iron(II) Complexes Linked to Organic Chromophores
Two new bichromophoric complexes, [Fe(bim-ant)2]2+ and [Fe(bim-pyr)2]2+ ([H2-bim]2+ = 1,1′-(pyridine-2,6-diyl)bis(3-methyl-1H-imidazol-3-ium); ant = 9-anthracenyl; pyr = 1-pyrenyl), are investigate...
CCDC 2050317: Experimental Crystal Structure Determination
Related Article: Philipp Dierks, Ayla Kruse, Olga S. Bokareva, Mohammed J. Al-Marri, Jens Kalmbach, Marc Baltrun, Adam Neuba, Roland Schoch, Stephan Hohloch, Katja Heinze, Michael Seitz, Oliver Kühn, Stefan Lochbrunner, Matthias Bauer|2021|Chem.Commun.|57|6640|doi:10.1039/D1CC01716K
CCDC 2049729: Experimental Crystal Structure Determination
Related Article: Philipp Dierks, Ayla Kruse, Olga S. Bokareva, Mohammed J. Al-Marri, Jens Kalmbach, Marc Baltrun, Adam Neuba, Roland Schoch, Stephan Hohloch, Katja Heinze, Michael Seitz, Oliver Kühn, Stefan Lochbrunner, Matthias Bauer|2021|Chem.Commun.|57|6640|doi:10.1039/D1CC01716K